间隔流动分析法测定水中总磷

采用间隔流动分析法(SFA)测定地表水和城镇污水处理厂废水中的总磷,并与现行国标方法作比对,发现悬浮物对SFA法的结果存在一定的干扰,并对此进行了详细讨论且设计了一系列实验。实验结果表明使用均质机对水样均质能够有效消除悬浮物对测定结果的影响。水样经均质处理后两种方法测定结果相对误差小于3.0%。SFA法绘制的校准曲线线性大于0.999 5,标准样品的平行测定RSD≤1.5%,方法检出低限为0.009 mg/L,地表水样品加标回收率为91.4%～97.7%。     

漓江沉积柱重金属垂向分布特征及污染评价

对桂林漓江3个采样点沉积柱状沉积物中主要重金属元素(Cd、Cr、Cu、Zn、Pb、As和Ni)的垂向分布进行了测定。结果表明:7种重金属元素具有相似的垂向变化特征;横向上表现为靠近市区的含量高远离,市区的含量低。地积累指数评价结果显示,远离市区的沉积柱7种金属污染程度较轻,仅有Cd和Ni属于无～中污染程度。临近市区的沉积柱形成污染的元素为Cd、Cu、Zn、Pb和As,主要集中在底层和次表层。     

PM2．5污染危害分析及防控措施研究

本文论述了PM2.5对环境的危害,在剖析PM2.5组成与来源的基础上,提出防控PM2.5的政策与技术方面的建议,以期为今后PM2.5的防控工作提供理论基础。     

试论中国城市公共安全规划与应急管理体系建设

1国内外公共安全形势与城市公共安全的新挑战 　　进入21世纪,国际公共安全形势日趋严峻,城市面临的灾害形势从传统的自然灾害、火灾、瘟疫等为主扩大到传统灾害和生命线系统故障、信息安全、恐怖事件等非传统灾害共同影响的情况,呈现出以下特点:重大自然灾害的发生频率、量级加大,经济损失更严重;随着工业化、现代化和城市化的发展,事故灾难以及复合型事件的影响日益突出;生物和公共卫生危机严重威胁和影响公众健康;恐怖主义威胁呈现出新型化、大规模化和强灾难性的特点;经济危机连锁反应,各种社会危机交相激荡.……     

石羊河流域1959年至2008年风速变化特征分析

利用线性拟合、Mann—Kendall方法、小波分析对石羊河流域五个测站空间平均的近50年来的逐日风速资料进行了倾向、周期、突变等特性分析。研究结果表明：1959年至2008年间,整个石羊河流域风速呈减小趋势,变化率约为-0．004m／（s．a）．而上游风速呈现明显的上升趋势。四个季节中冬季风速降低速度最大,而夏季风速呈现上升趋势。风速的长期变化还具有一定的突变性,年平均风速在1988年出现了由高到低的突变,表明风速开始下降。复值Morlet小波分析的结果显示,风速变化存在6a、13a、19a、25a四个峰值。其中19a的时间尺度为第一主周期。     

Efficient dechlorination of chlorinated solvent pollutants under UV irradiation by using the synthesized TiO2 nano-sheets in aqueous phase

Titanium dioxide(TiO2), which is the widely used photo-catalyst, has been synthesized by simple hydrothermal solution containing tetrabutyl titanate and hydrofluoric acid. The synthesized product has been applied to photo-degradation in aqueous phase of chlorinated solvents, namely tetrachloroethene(PCE), trichloroethene(TCE) and 1,1,1-trichloroethane(TCA). The photo-degradation results revealed that the degradation of these harmful chemicals was better in UV/synthesized TiO2 system compared to UV/commercial P25 system and UV only system. The photo-catalytic efficiency of the synthesized TiO2 was 1.4, 1.8 and 3.0 folds higher compared to the commercial P25 for TCA, TCE and PCE degradation, respectively. Moreover, using nitrobenzene(NB) as a probe of hydroxyl radical(.OH), the degradation rate was better over UV/synthesized TiO2, suggesting the high concentration of.OH generated in UV/synthesized TiO2system. In addition,.OH concentration was confirmed by the strong peak displayed in EPR analysis over UV/synthesized TiO2system. The characterization result using XRD and TEM showed that the synthesized TiO2 was in anatase form and consisted of well-defined sheet-shaped structures having a rectangular outline with a thickness of 4 nm, side length of 50 nm and width of 33 nm and a surface 90.3 m2/g. XPS analysis revealed that ≡Ti-F bond was formed on the surface of the synthesized TiO2. The above results on both photocatalytic activity and the surface analysis demonstrated the good applicability of the synthesized TiO2 nano-sheets for the remediation of chlorinated solvent contaminated groundwater.     

Quantitative method to determine the regional drinking water odorant regulation goals based on odor sensitivity distribution：Illustrated using 2-MIB

Taste and odor （T/O） in drinking water often cause consumer complaints and are thus regulated in many countries. However, people in different regions may exhibit different sensitivities toward WO. This study proposed a method to determine the regional drinking water odorant regulation goals （ORGs） based on the odor sensitivity distribution of the local population. The distribution of odor sensitivity to 2-methylisobomeol （2-MIB） by the local population in Beijing, China was revealed by using a normal distribution function/model to describe the odor complaint response to a 2-MIB episode in 2005, and a 2-MIB concentration of 12.9 ng/L and FPA （flavor profile analysis） intensity of 2.5 was found to be the critical point to cause odor complaints. Thus the Beijing ORG for 2-MIB was determined to be 12.9 ng/L. Based on the assumption that the local FPA panel can represent the local population in terms of sensitivity to odor, and that the critical FPA intensity causing odor complaints was 2.5, this study tried to determine the ORGs for seven other cities of China by performing FPA tests using an FPA panel from the corresponding city. ORG values between 12.9 and 31.6 ng/L were determined, showing that a unified ORG may not be suitable for drinking water odor regulations. This study presents a novel approach for setting drinking water odor regulations.     

应用小型无人值守水站构建苏州市城区河道自动监测系统研究

苏州市城区河道自动监测系统实现了时城区河道环境整治水质变化的实时跟踪监测,系统采用小型、节能、低噪的智能子站、免试剂的监测方法和多重保障的安防措施,集监控评价发布为一体化,体现了绿色监测的理念,且与大型水站同样具有较强的野外适应能力和无人值守智能监测的特点.本文就系统的构架以及系统所具有的4个方面特点进行了阐述,并总结了在系统建设中的站点选址、对监测结果的有效利用、运行过程的质量控制及免试剂监测方法的适用性等几方面应用体会.     

我国安全生产行政执法统计指标体系研究与应用

我国安全生产行政执法统计指标体系自施行以来,一直存在统计指标体系过于繁杂、部分统计指标较笼统,未充分体现安全生产重点工作及其成效等问题,创新改革安全生产行政执法统计制度具有重要的理论意义和实用价值。通过梳理安全生产行政执法统计指标体系演变脉络,在实地调研和现场访谈的基础上,基于PDCA理论提出以执法人员-执法对象-执法行为“三位一体”的安全生产行政执法统计指标体系,明确包含执法力量、执法对象、执法检查和事故查处等方面的综合评价指标,并在实践中得以应用和检验,为全面分析安全生产执法效能拓展空间,统计制度的后续修订和安全生产综合分析工作奠定基础。     

天津市地表水体与沉积物中7种高关注酚类化合物的污染特征与生态风险分析

为探究地表水体与沉积物中酚类化合物的污染分布特征和生态风险,选择天津市3个水源地与6条主要河流,采集了26个地表水样与6个沉积物样品,利用固相萃取与超声萃取、高效液相色谱-串联质谱法(HPLC-MS/MS)测定了水样及沉积物中1-萘酚(1-naphthol)、壬基酚(nonylphenol, NP)、双酚A(bisphenol A, BPA)、2-苯基苯酚(biphenyl-2-ol)、3,4-二氯酚(3,4-dichlorophenol)、四溴双酚A(tetrabromobisphenol A, TBBPA)和对叔丁基苯酚(p-tert-butylphenol, PTBP)等7种高关注酚类化合物的浓度水平,并应用物种敏感性分布(species sensitivity distribution, SSD)法和熵值法(ecological risk quotient, RQ)评估7种酚类化合物水环境和沉积物的生态风险。结果表明,地表水样中7种酚类化合物均全部检出;其中壬基酚的检出浓度最高,其次为四溴双酚A、对叔丁基苯酚、1-萘酚、2-苯基苯酚、3,4-二氯酚和双酚A。沉积物中酚类化合物的污染分布规律与水样相似,除双酚A外的目标物全部检出。其中,壬基酚浓度比其他物质浓度高2个数量级。风险评估结果显示,壬基酚对水环境与沉积物存在不可接受的风险;而四溴双酚A、对叔丁基苯酚、1-萘酚、2-苯基苯酚、3,4-二氯酚和双酚A则对环境具有较低风险或者存在一定的风险。