Functional flax fiber with UV-induced switchable wettability for multipurpose oil-water separation

● A PAA-ZnO-HDTMS flax fiber with UV-induced switchable wettability was developed. ● The property of flax fiber could be switched from hydrophobicity to hydrophilicity. ● The mechanism of the acquired UV-induced switchable wettability was discussed. ● The developed flax fiber was successfully used for multipurpose oil-water separation. The large number of oily wastewater discharges and oil spills are bringing about severe threats to environment and human health. Corresponding to this challenge, a functional PAA-ZnO-HDTMS flax fiber with UV-induced switchable wettability was developed for efficient oil-water separation in this study. The developed flax fiber was obtained through PAA grafted polymerization and then ZnO-HDTMS nanocomposite immobilization. The as-prepared PAA-ZnO-HDTMS flax fiber was hydrophobic initially and could be switched to hydrophilic through UV irradiation. Its hydrophobicity could be easily recovered through being stored in dark environment for several days. To optimize the performance of the PAA-ZnO-HDTMS flax fiber, the effects of ZnO and HDTMS concentrations on its switchable wettability were investigated. The optimized PAA-ZnO-HDTMS flax fiber had a large water contact angle (~130°) in air and an extremely small oil contact angle (~0°) underwater initially. After UV treatment, the water contact angle was decreased to 30°, while the underwater oil contact angle was increased to more than 150°. Based on this UV-induced switchable wettability, the developed PAA-ZnO-HDTMS flax fiber was applied to remove oil from immiscible oil-water mixtures and oil-in-water emulsion with great reusability for multiple cycles. Thus, the developed flax fiber could be further fabricated into oil barrier or oil sorbent for oil-water separation, which could be an environmentally-friendly alternative in oil spill response and oily wastewater treatment.     

Techno-economic characteristics of wastewater treatment plants retrofitted from the conventional activated sludge process to the membrane bioreactor process

• Retrofitting from CAS to MBR increased effluent quality and environmental benefits. • Retrofitting from CAS to MBR increased energy consumption but not operating cost. • Retrofitting from CAS to MBR increased the net profit and cost efficiency. • The advantage of MBR is related to the adopted effluent standard. • The techno-economy of MBR improves with stricter effluent standards. While a growing number of wastewater treatment plants (WWTPs) are being retrofitted from the conventional activated sludge (CAS) process to the membrane bioreactor (MBR) process, the debate on the techno-economy of MBR vs. CAS has continued and calls for a thorough assessment based on techno-economic valuation. In this study, we analyzed the operating data of 20 large-scale WWTPs (capacity≥10000 m³/d) and compared their techno-economy before and after the retrofitting from CAS to MBR. Through cost-benefit analysis, we evaluated the net profit by subtracting the operating cost from the environmental benefit (estimated by the shadow price of pollutant removal and water reclamation). After the retrofitting, the removal rate of pollutants increased (e.g., from 89.0% to 93.3% on average for NH₃-N), the average energy consumption increased from 0.40 to 0.57 kWh/m³, but the operating cost did not increase significantly. The average marginal environmental benefit increased remarkably (from 0.47 to 0.66 CNY/g for NH₃-N removal), leading to an increase in the average net profit from 19.4 to 24.4 CNY/m³. We further scored the technical efficiencies via data envelopment analysis based on non-radial directional distance functions. After the retrofitting, the relative cost efficiency increased from 0.70 to 0.73 (the theoretical maximum is 1), while the relative energy efficiency did not change significantly. The techno-economy is closely related to the effluent standard adopted, particularly when truncating the extra benefit of pollutant removal beyond the standard in economic modeling. The modeling results suggested that MBR is more profitable than CAS given stricter effluent standards.     

New insights into different surfactants’ impacts on sludge fermentation: Focusing on the particular metabolic processes and microbial genetic traits

• The promoting effects for VFA generation follow the order of APG>SDBS>HTAB. • Surfactants improve the WAS solubilization/hydrolysis and acidification processes. • The VFA promotion is associated with surfactants’ distinctive characteristics. • Surfactants induce the enrichment of functional bacteria for VFA biosynthesis. • The vital genes for substrates delivery, metabolism, and VFA yields are upregulated. Surfactants were expected to exhibit positive effects on the waste activated sludge (WAS) disposal. However, the systematic comparison of different categories of surfactants on the WAS fermentation and the functional mechanisms, especially microbial metabolic traits, have not yet been precisely explored. This study revealed the positive effects of different surfactants on the volatile fatty acid (VFA) production, which followed the order of alkyl polysaccharides (APG)>sodium dodecylbenzene sulfonate (SDBS)>hexadecyl trimethyl ammonium bromide (HTAB). Mechanistic exploration found that the presence of different surfactants improved solubilization and hydrolysis steps, and then contributed to the subsequent acidification with different efficiencies. The functional microorganisms associated with VFA generation were enriched in surfactant-conditioned reactors. Metagenomic analysis further indicated that the key genes involved in the particular process of VFA generation were over-expressed. The simultaneous bioavailable substrate improvement, functional bacterial enrichment, and metabolic activity upregulation induced by different surfactants jointly contributed to VFA promotion during WAS fermentation. This study could provide a comprehensive realization of surfactants’ impacts on the WAS fermentation process, and more importantly, it reminded the public to discern the distinct interplaying effects induced by different chemicals in regulating the WAS disposal and resource recovery.     

Spatiotemporal variations of dissolved organic matter in a typical multi-source watershed in northern China: a fluorescent evidence

Environmental Science and Pollution Research - The amount of dissolved organic matter (DOM) in a multi-source watershed is important for complete management and assessing the river basin’s...     

Assessing economic sustainability and ecological efficiency with genuine progress indicator: a case study of the Yangtze River Delta from 2000 to 2018

To achieve urban sustainability, it is critical to enhance the environment, economy, and society simultaneously. This study adopted the revised genuine progress indicator (GPI) and ecological footprint (EF) to evaluate the ecological efficiency and economic sustainability of the Yangtze River Delta from 2000 to 2018. Spatial analysis was utilized to identify spatial autocorrelation. A total of 27 cities were then partitioned through k-means cluster analysis. The results showed that GPI and ecological efficiency improved rapidly, but economic sustainability showed a downward trend. GPI and GDP had a high degree of spatial correlation, especially in Suzhou-Wuxi-Changzhou Metropolitan Area. However, no spatial correlation existed between GPI and EF. The city with high GEE can reach 3000 $/gha, indicating the city consumed 1 global hectare to create $3000 of genuine economic growth. Shanghai, Hangzhou, and Taizhou were cities with the highest level of economic sustainability and ecological efficiency. The spatiotemporal characteristics of economic sustainability and ecological efficiency revealed in this study will provide theoretical guidance for alleviating ecological pressure and promoting economic sustainable development.

     

Prefabrication decisions of the construction supply chain under government subsidies

Environmental Science and Pollution Research - Prefabrication has been generating increasing interest as a cleaner production strategy to promote sustainable development. Alongside this trend,...     

Spatial and seasonal variation and sources of deposition fluxes of polycyclic aromatic hydrocarbons (PAHs) in Shanghai

Environmental Science and Pollution Research - Spatial and temporal variations of polycyclic aromatic hydrocarbons (PAHs) deposition fluxes and sources may significantly facilitate risk evaluation...     

The effects of air pollution on the lung cancer mortality in rural areas of eastern China: a multi-region study

Environmental Science and Pollution Research - Recently, the burden of lung cancer (LC) has attracted global attention. Meanwhile, LC has become the leading cause of death in China. Many studies...     

Inactivation of E. coli and Streptococcus agalactiae by UV/persulfate during marine aquaculture disinfection

Environmental Science and Pollution Research - Sulfate radical (?SO4?)–based advanced oxidation processes have attracted a great deal of attention for use in water disinfection...     

Developing a method for assessing environmental sustainability based on the Google Earth Engine platform

Environmental sustainability is the foundation and of great significance for the sustainable development of urban agglomerations. Taking the Beijing-Tianjin-Hebei urban agglomeration as an example, we developed a method to effectively assess long-term regional environmental sustainability based on the Google Earth Engine (GEE) platform. We used the GEE to obtain 5206 Landsat remote sensing images in the region from 1983 to 2016 and developed the comprehensive environmental index (CEI) to assess regional environmental sustainability based on the theme-oriented framework proposed by the United Nations Commission on Sustainable Development. We found that the environmental sustainability of the urban agglomeration showed a trend of first rising, then falling, and then rising again in the past 30 years. The average CEI increased from 0.621 to 0.631 from 1985 to 1990, dropped to the lowest value of 0.618 in 2000, and then rose to the highest value of 0.672 in 2015. In particular, the extent of areas in which environmental sustainability improved (56% of the region) was greater than the extent of areas in which environmental deterioration occurred. The environmental sustainability of Hengshui, Xingtai, and Cangzhou in the southeast of the region has been significantly improved. The method proposed in this study provides an automatic, rapid, and extensible way to assess regional environmental sustainability and provides a scientific reference for improving the sustainability of the regional environment.