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471.
Clive?BonsallEmail author Adina?Boronean? Andrei?Soficaru Kathleen?McSweeney Tom?Higham Nicolae?Miri?oiu Catriona?Pickard Gordon?Cook 《Die Naturwissenschaften》2012,99(4):321-325
In 1968, excavations in the Climente II cave in the Iron Gates gorge of the River Danube in southwest Romania unearthed the skeleton of an adult male. The burial was assumed to be of Late Pleistocene age because of the presence of Late Upper Palaeolithic (LUP) artefacts in the cave. However, there was no strong supporting stratigraphic evidence, and the body position is reminiscent of Early Neolithic burial practice in the region. Here, we report the results of radiocarbon and stable isotope analyses of the Climente II skeleton, which show that the skeleton dates to the Bølling–Allerød Interstadial ~14,500 cal BP. This is several millennia older than any previously dated human remains from the Iron Gates region and confirms its status as the oldest known burial from Romania. The stable isotope results indicate a diet with an emphasis on aquatic resources, contrary to the commonly held view that the LUP inhabitants of the Iron Gates subsisted mainly by hunting large land mammals. 相似文献
472.
Leif Nelson James Barker Tom Li Neil Thomson Mario Ioannidis John Chatzis 《Journal of contaminant hydrology》2009,109(1-4):82-90
A pilot scale field trial was conducted to evaluate the recovery of volatile, light non-aqueous phase liquids (LNAPLs) using a novel remediation method termed supersaturated water injection (SWI). SWI uses a patented technology to efficiently dissolve high concentrations of CO2 into water at elevated pressures. This water is injected into the subsurface resulting in the nucleation of CO2 bubbles at and away from the injection point. The nucleating bubbles coalesce, rise and volatilize residual LNAPL ganglia. In this study, an LNAPL composed of 103 kg of volatile pentane and hexane, and 30 kg of non-volatile Soltrol was emplaced below the water table at residual saturation. The SWI technology removed 78% of the pentane and 50% of the less volatile hexane. Contaminant mass was still being removed when the system was shut down for practical reasons. The mass removed is comparable to that expected for air sparging but a much smaller volume of gas was injected using the SWI system. 相似文献
473.
Hough RL Whittaker M Fallick AE Preston T Farmer JG Pollard SJ 《Environmental pollution (Barking, Essex : 1987)》2006,143(3):489-498
A preliminary evaluation of compound-specific isotope analysis (CSIA) as a novel, alternative method for identifying source correlation compounds in soils contaminated with residual heavy or weathered petroleum wastes is presented. Oil-contaminated soil microcosms were established using soil (sandy-loam, non-carbonaceous cley) amended with ballast-, crude- or No.6 fuel oil. Microcosms were periodically sampled over 256 days and delta(13)C values (which express the ratio of (13)C to (12)C) determined at each time point for five n-alkanes and the isoprenoid norpristane using gas chromatography-isotope ratio mass spectrometry (GC-IRMS). Although some temporal variation was observed, no significant temporal shifts in the delta(13)C values for the five n-alkanes were measured in all three oils. Isoprenoid isotope ratios (delta(13)C) appeared to be least affected by biotransformation, especially in the No.6 fuel oil. The research suggests that the delta(13)C of isoprenoids such as norpristane, may be of use as source correlation parameters. 相似文献
474.
Passive air sampling for persistent organic pollutants: introductory remarks to the special issue 总被引:1,自引:0,他引:1
Harner T Bartkow M Holoubek I Klanova J Wania F Gioia R Moeckel C Sweetman AJ Jones KC 《Environmental pollution (Barking, Essex : 1987)》2006,144(2):361-364
There have been a number of developments in the need, design and use of passive air samplers (PAS) for persistent organic pollutants (POPs). This article is the first in a Special Issue of the journal to review these developments and some of the data arising from them. We explain the need and benefit of developing PAS for POPs, the different approaches that can be used, and highlight future developments and needs. 相似文献
475.
Pérez-Cadahía B Laffon B Porta M Lafuente A Cabaleiro T López T Caride A Pumarega J Romero A Pásaro E Méndez J 《Chemosphere》2008,71(3):447-455
The sinking of the 'Prestige' oil tanker in front of the Galician coast (NW of Spain) in November 2002 offered a unique opportunity to analyze intermediate cytogenetic and endocrine effects among people exposed to the complex mixture of substances that oil constitutes, including several toxic heavy metals. In this work we evaluated the relationship between exposure to heavy metals (blood concentrations of aluminium, cadmium, nickel, lead and zinc) and genotoxic parameters (sister chromatid exchanges, micronucleus test and comet assay) or endocrine parameters (plasmatic concentrations of prolactin and cortisol) in subjects exposed to 'Prestige' oil during cleaning tasks developed after the spillage. Concentrations of lead were significantly related to the comet assay even after adjusting by age, sex and smoking. Cortisol concentrations were significantly influenced by aluminium, nickel (both, inversely) and cadmium (positively). Women had clearly higher concentrations of prolactin and cortisol, even when adjusting by age, smoking, cadmium, aluminium or nickel. Plasmatic cortisol was jointly influenced by gender, smoking and aluminium or nickel (all p<0.05). In women there was a strong relationship between concentrations of cadmium and prolactin (beta=0.37, p=0.031). When the effects of cadmium, aluminium and nickel on cortisol were simultaneously assessed, only the latter two metals remained statistically significant. Among parameters analysed, cortisol appeared to be the most sensitive to the effects of metal exposure. Plasma levels of cortisol deserve further evaluation as a potentially relevant biomarker to assess the effects of exposure to heavy metals. 相似文献
476.
Copper-ligand complex for the decolorization of synthetic dyes 总被引:1,自引:0,他引:1
The reaction system containing Cu(II), hydrogen peroxide and D-arabinono-1,4-lactone was found to be effective in the decolorization and reduction of toxicity of azo, thiazine-, triphenylmethane- and anthraquinone-based synthetic dyes. More than 85% decolorization was obtained with 100ppm Acridine Orange, Azure B, Chicago Sky Blue 6B, Crystal Violet, Evans Blue, Poly B-411, Reactive Blue 2, Reactive Blue 5, and Remazol Brilliant Blue R incubated for 24h in the presence of 10mM CuSO(4), 20mM D-arabinono-1,4-lactone and 80 mM H(2)O(2). The rate of decolorization was not affected by pH in the range of 3-9. The rapid decolorization was accompanied by a fast decomposition of H(2)O(2) in the reaction mixture and by a fast production of hydroxyl radicals. 相似文献
477.
INTRODUCTION: In this paper a sensitivity analysis is performed to investigate how big the impact would be on the current ranking of crash locations in Flanders (Belgium) when only taking into account the most serious injury per crash instead of all the injured occupants. RESULTS: Results show that this would lead to a different selection of 23.8% of the 800 sites that are currently considered as dangerous. CONCLUSIONS: Considering this impact quantity, the researchers want to sensitize government that giving weight to the severity of the crash can correct for the bias that occurs when the number of occupants of the vehicles are subject to coincidence. Additionally, probability plots are generated to provide policy makers with a scientific instrument with intuitive appeal to select dangerous road locations on a statistically sound basis. Impact on industry Considering the impact quantity of giving weight to the severity of the crash instead of to all the injured occupants of the vehicle on the ranking of crash sites, the authors want to sensitize government to carefully choose the criteria for ranking and selecting crash locations in order to achieve an enduring and successful traffic safety policy. Indeed, giving weight to the severity of the crash can correct for the bias that occurs when the number of occupants of the vehicles are subject to coincidence. However, it is up to the government to decide which priorities should be stressed in the traffic safety policy. Then, the appropriate weighting value combination can be chosen to rank and select the most dangerous crash locations. Additionally, the probability plots proposed in this paper can provide policy makers with a scientific instrument with intuitive appeal to select dangerous road locations on a statistically sound basis. Note that, in practice, one should not only rank the crash locations based on the benefits that can be achieved from tackling these locations. Future research is also needed to incorporate the costs of infrastructure measures and other actions that these crash sites require in order to enhance the safety on these locations. By balancing these costs and benefits against each other, the crash locations can then be ranked according to the order in which they should be prioritized. 相似文献
478.
Jean Hugé Tom Waas Farid Dahdouh-Guebas Nico Koedam Thomas Block 《Sustainability Science》2013,8(2):187-198
Sustainable development is a ubiquitously used concept in public decision-making: it refers to an ideal vision of global society where human development and environmental quality go hand in hand. Logically, any decision-supporting process aiming at facilitating and steering society toward a sustainable future then seems desirable. Assessing the sustainability of policy decisions is, however, influenced by what sustainable development is believed to entail, as different discourses coexist under the umbrella of the sustainable development meta-discourse. This paper proposes a typology of sustainable development discourses, and, subsequently, applies a discourse-analytical lens on two practical cases of sustainability assessment in different institutional and geographical contexts (in Belgium and in Benin). The results indicate that sustainability assessments tend to be influenced mainly by the consensual ‘sustainable development as integration’ discourse, while also providing a forum for dialogue between different discourses. The results shed light on context-specific discursive and institutional dynamics for the development and application of sustainability assessment. Acknowledging these dynamics as well as sustainable development’s inherent interpretational limits can lead to an improved use of sustainable development as a decision-guiding strategy. 相似文献
479.
洞庭湖流域分布式水文模型 总被引:1,自引:0,他引:1
流域出口径流观测序列是水文模型参数率定重要依据,不受水文站控制区域的模型应用是水文研究关注点之一。首先根据水文站观测资料建立洞庭湖流域四水控制站之上基于水文响应单元的分布式水文模型,在此基础上结合实验、同质移植和虚拟水库等方法,将分布式水文模型拓展到包含无径流站控制区域的丘陵区间和平原圩垸区,最终实现了洞庭湖全流域水文过程模拟。结果表明:在较完备土壤、地形、土地利用等空间数据支持下,通过合理的流域划分和水文响应单元定义,建立的流域分布式水文模型可以较好地在水文响应单元尺度反应降水发生后蒸散、地表径流、土壤和地下水的响应特征。而基于观测实验及基流分割等方法获取的关键水文过程特征对模型参数优化的认识,可以提高模型参数率定效率,在较少优化迭代运算后既可使月径流模拟的效率系数NSE和确定性系数R2值高于0.81(日过程高于0.62)。借助参数同质移植和虚拟水库解决了区间和圩垸区无控制站区域水文过程模拟。在全流域水文过程的模拟中,基流指数和蒸散比例与实际过程具有较好的一致性。说明相关参数较好地反映了其物理机制,具备在相似气候及下垫面条件区域进行同质移植的基础,圩垸区径流交换采用虚拟水库的处理方式也合理可行。 相似文献
480.
Jonathan Salerno Karen Bailey Andrea E. Gaughan Forrest R. Stevens Tom Hilton Lin Cassidy Michael D. Drake Narcisa G. Pricope Joel Hartter 《Conservation biology》2020,34(4):891-902
Interactions between humans and wildlife resulting in negative impacts are among the most pressing conservation challenges globally. In regions of smallholder livestock and crop production, interactions with wildlife can compromise human well-being and motivate negative sentiment and retaliation toward wildlife, undermining conservation goals. Although impacts may be unavoidable when human and wildlife land use overlap, scant large-scale human data exist quantifying the direct costs of wildlife to livelihoods. In a landscape of global importance for wildlife conservation in southern Africa, we quantified costs for people living with wildlife through a fundamental measure of human well-being, food security, and we tested whether existing livelihood strategies buffer certain households against crop depredation by wildlife, predominantly elephants. To do this, we estimated Bayesian multilevel statistical models based on multicounty household data (n = 711) and interpreted model results in the context of spatial data from participatory land-use mapping. Reported crop depredation by wildlife was widespread. Over half of the sample households were affected and household food security was reduced significantly (odds ratio 0.37 [0.22, 0.63]). The most food insecure households relied on gathered food sources and welfare programs. In the event of crop depredation by wildlife, these 2 livelihood sources buffered or reduced harmful effects of depredation. The presence of buffering strategies suggests a targeted compensation strategy could benefit the region's most vulnerable people. Such strategies should be combined with dynamic and spatially explicit land-use planning that may reduce the frequency of negative human–wildlife impacts. Quantifying and mitigating the human costs from wildlife are necessary steps in working toward human–wildlife coexistence. 相似文献