Site-specific bioaccumulation of polychlorinated dibenzo-<Emphasis Type="Italic">p</Emphasis>-dioxins and polychlorinated dibenzofurans (PCDD/PCDFs) in mothers and their infants living in vicinity of Bien Hoa airbase,Southern Vietnam

Bien Hoa airbase is located in Dong Nai Province (Southern Vietnam). Several sites within the airbase are highly contaminated by Agent Orange/Dioxin, and thus, they are also commonly named as an Agent Orange/Dioxin hotpot. In the present study, 36 maternal milk samples were collected from primiparas who have lived at least 5 years in four wards, Buu Long, Quang Vinh, Trung Dung and Tan Phong, which are closed to Bien Hoa airbase in order to investigate the level and distribution of Agent Orange/Dioxin exposure in different local communities. The mean concentrations of PCDD/PCDFs in four investigated wards range from 6.4 to 13.6 pgTEQ/g lipid. The highest mean TEQ of PCDD/PCDFs was observed in Buu Long ward (13.6 pgTEQ/g lipid), followed by Tan Phong ward (12.3 pgTEQ/g lipid), and the lowest value was observed in Trung Dung ward (6.4 pgTEQ/g lipid). The mean concentration of 2,3,7,8-TCDD in Buu Long (7.6 pg/g lipid) was approximately 2–6 times higher than those in Tan Phong (3.9 pg/g lipid), Quang Vinh (2.3 pg/g lipid), or Trung Dung (1.2 pg/g lipid). These results imply site-specific exposure to PCDD/PCDFs in different local communities living around Bien Hoa airbase. The mean values of daily intake of dioxin estimated for the breast fed infants living in Buu Long, Quang Vinh, Trung Dung and Tan Phong were about 80, 37.5, 31.7 and 58 pg TEQ/kg bw/day, respectively.     

Current pesticide practices and environmental issues in Vietnam: management challenges for sustainable use of pesticides for tropical crops in (South-East) Asia to avoid environmental pollution

Pesticides are widely used in modern agriculture to minimize financial losses and maintain food supplies. In southeast Asia, where agriculture is the principal economic activity, pesticides are considered essential, particularly in tropical regions seeking to enter the global economy by providing off-season fresh fruits and vegetables. The absence of a strong legal framework for pesticides facilitated a significant increase in the use of low-quality pesticides. Farmers ignore the risks, safety instructions, and protective directives when using pesticides. They are only concerned about the effectiveness of the pesticides for killing pests, without paying attention to the effects on their health and the environment. The improper usage of pesticides and the incorrect disposal of pesticide wastes contributed to the pollution of groundwater, surface water, and soil, and induced health problems in local communities. This paper describes the impact of the exposure of pesticides on human health and water resources in connection with the usage of pesticides and their management. Because of availability, the data are mainly taken for Northern Vietnam, and applied to the water quality in the delta; nevertheless, the problem relates to all countries in the delta, and similar situations may be found in other regions, particularly in Asia.     

Development of nutrient cycle through agricultural activities of a rural area in the North of Vietnam

Material flow analysis (MFA) has been applied to assess the environmental impact of human activities on nutrient flows at the commune scale. This paper reports the assessment of human excreta and animal manure as a nutrient source for paddy fields and fishponds in Hoang Tay commune, Ha Nam province, Vietnam. The quality of MFA model was confirmed through modified uncertainty analysis, then was used to originally quantify and visualize the interlinks of livestock with the environmental sanitation and agricultural system in terms of nutrients. Currently, half of the pig manure was collected to the biogas, and the remainders were freely discharged to the commune’s drainage system (25%) or directly reused in the paddy fields (25%). While wastewater in the drainage system was the biggest source of nitrogen (contributed 46%), paddy field was the biggest source of phosphorous (contributed 55%) discharged to the Nhue River, totaling 57 ± 9 ton N and 29 ± 6 ton P, annually. Consequently, mitigation measures for nutrient resource management were proposed, and reducing half of chemical fertilizers applied and reusing all excreta and manure in the paddy fields were the most effective option.     

Recycling nickel from spent catalyst of Phu My fertilizer plant as a precursor for exhaust gas treatment catalysts preparation

In this study, a very promising way of treating and recycling spent nickel catalysts of fertilizer plants in Vietnam was proposed. Firstly, nickel was recovered from spent catalyst using HNO₃—leaching process. Results show that nickel recovery of over 90% with a purity of over 90% can be achieved with HNO₃ 2.1–2.5 M at 100?°C in 75 min. The residue after leaching is not considered as a hazardous waste according to the Vietnamese regulations. Then, the leachate solution was used as a precursor to prepare a model catalyst for exhaust gas (CO, HC, NO_x) treatment. In comparison with the catalyst prepared from the commercial nickel nitrate solution, the catalyst synthesized from recovered nickel exhibits similar properties and activities. The influence of Ni loading of Ni/alumina catalyst as well as the modification of active phase by some metals addition (Mn, Ba, Ce) was also investigated. It is feasible to modify active phase by transition metals such as Mn, Ba, and Ce for complete oxidation of CO and HC at 270?°C and a reduction of NO_x below 350?°C at high volumetric flow condition (GHSV?=?110.000 h^?1).     

Relationship of urinary arsenic metabolites to intake estimates in residents of the Red River Delta, Vietnam

This study investigated the status of arsenic (As) exposure from groundwater and rice, and its methylation capacity in residents from the Red River Delta, Vietnam. Arsenic levels in groundwater ranged from <1.8 to 486 μg/L. Remarkably, 86% of groundwater samples exceeded WHO drinking water guideline of 10 μg/L. Also, estimated inorganic As intake from groundwater and rice were over Provisional Tolerable Weekly Intake (15 μg/week/kg body wt.) by FAO/WHO for 92% of the residents examined. Inorganic As and its metabolite (monomethylarsonic acid and dimethylarsinic acid) concentrations in human urine were positively correlated with estimated inorganic As intake. These results suggest that residents in these areas are exposed to As through consumption of groundwater and rice, and potential health risk of As is of great concern for these people. Urinary concentration ratios of dimethylarsinic acid to monomethylarsonic acid in children were higher than those in adults, especially among men, indicating greater As methylation capacity in children.     

Inland harmful cyanobacterial bloom prediction in the eutrophic Tri An Reservoir using satellite band ratio and machine learning approaches

Environmental Science and Pollution Research - In recent years, Tri An, a drinking water reservoir for millions of people in southern Vietnam, has been affected by harmful cyanobacterial blooms...     

Radiosynthesis of perfluorooctanesulfonate (PFOS) and perfluorobutanesulfonate (PFBS), including solubility, partition and adhesion studies

Here, we describe for the first time the synthesis of [³⁵S] PFOS and [³⁵S] PFBS with sulfur-35 enriched sulfur dioxide as the radiolabelled reagent, resulting in 2.5 and 2.3 mCi of product, respectively. Basic information concerning the physicochemical properties of perfluorooctanesulfonate (PFOS), perfluorobutanesulfonate (PFBS) and perfluorooctanoic acid (PFOA) are still limited. Hence, we utilized these radiolabelled perfluoroalkanesulfonates (PFSAs), as well as carbon-14 labelled perfluorooctanoic acid ([¹⁴C] PFOA) to determine some basic characteristics of physiological and experimental significance.The solubility of PFOS in buffered aqueous solutions at pH 7.4 was found to be severely reduced in the presence of potassium and sodium ions, which, however, did not reduce the solubility of PFOA or PFBS. PFOS was found to adhere to a small extent to polypropylene and polystyrene, whereas no such adhesion of PFOA or PFBS was detected. The extents of adhesion of PFOS and PFOA to glass were found to be 20% and 10%, respectively. For the first time, the partition coefficients for PFOS, PFBS and PFOA between n-octanol and water were determined experimentally, to be −0.7, −0.3, and 1.4, respectively, reflecting the difference in the amphiphilic natures of these molecules.     

Solid waste management associated with the development of 3R initiatives: case study in major urban areas of Vietnam

The purpose of this article is to describe the application and progress of the Reduce-Reuse-Recycle (3R) initiative and its gradual implementation and development in solid waste management in Vietnam through the study of the municipal solid waste management (MSWM) systems of eight major urban cities and provinces. The resulting survey and studies showed that there are big challenges for MSWM in the study areas due to the absence of an appropriate master plan for MSWM; there is a clear need to set up indicators for waste reduction and greenhouse gas emission reduction from waste generators and enterprises involved in MSWM, especially in terms of using 3R activities in the management of industrial waste. The strength and organic combination of institutional frameworks, support measures, and technologies for 3R promotion need to be applied as soon as possible in order to implement MSWM practices using more effective measures; in particular, a reduction in the amount of hazardous substances discarded and improvements in the handling of hazardous waste are required.     

Dynamic extreme values modeling and monitoring by means of sea shores water quality biomarkers and valvometry

Water quality can be evaluated using biomarkers such as tissular enzymatic activities of endemic species. Measurement of molluscs bivalves activity at high frequency (e.g., valvometry) during a long time period is another way to record the animal behavior and to evaluate perturbations of the water quality in real time. As the pollution affects the activity of oysters, we consider the valves opening and closing velocities to monitor the water quality assessment. We propose to model the huge volume of velocity data collected in the framework of valvometry using a new nonparametric extreme values statistical model. The objective is to estimate the tail probabilities and the extreme quantiles of the distribution of valve closing velocity. The tail of the distribution function of valve closing velocity is modeled by a Pareto distribution with parameter ??_t,τ, beyond a threshold τ according to the time t of the experiment. Our modeling approach reveals the dependence between the specific activity of two enzymatic biomarkers (Glutathione-S-transferase and acetylcholinesterase) and the continuous recording of oyster valve velocity, proving the suitability of this tool for water quality assessment. Thus, valvometry allows in real-time in situ analysis of the bivalves behavior and appears as an effective early warning tool in ecological risk assessment and marine environment monitoring.     

Sampling and analytical methodology development for the determination of primary and secondary low molecular weight amines in ambient air

In this project, a sampling device and an analytical method have been developed to simultaneously analyse the most frequently found low molecular weight amines, including aliphatic, aromatic and alcohol amines. These amines are diethanolamine, ethanolamine, methylamine, isopropylamine, morpholine, dimethylamine, and aniline. A sampling device was developed using a 37 mm cassette with glass fibre filters impregnated with sulfuric acid. Immediately after sampling, the filter was transferred to vials containing a solution of dansyl chloride. Dansyl chloride was used for derivatisation because it forms aromatic sulfonamides that are fluorescent and easy to protonate for MS detection. The effect of using an internal standard made with the dansylated derivative of 1-(2-methoxyphenyl)piperazine (MOPIP) on the uncertainty and efficiency of the method was also evaluated. This internal standard was spiked directly onto filters. The coupling of HPLC/ESI-MS was used for the simultaneous analysis of all the derivatives. This method showed detection limits of about 0.03 microg mL(-1) to 0.3 microg mL(-1) of amine with an average expanded uncertainty of 3% to 6% depending on the amine. The methodology recoveries are close to 100% for all the amines, and the overall estimated expanded uncertainties vary between 10% and 13% depending on the amine. This new strategy will be useful in evaluating workplace air since a unique sampling system will be used, independent of the amine to be quantified.