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991.
Zohra Belala Mejdi Jeguirim Meriem Belhachemi Fatima Addoun Gwena?lle Trouv�� 《Environmental Chemistry Letters》2011,9(1):65-69
The removal of toxic metals from wastewaters by biosorption, based on the metal-binding capacities of various biological materials,
has received much interest. However, the success of this approach depends on economic feasibility, which can be obtained by
optimization of the environmental conditions. This paper evaluates, for the first time, the use of low-cost biosorbent (date
stones (DS) and palm-tree waste (PTW)) to eliminate Cu(II) from aqueous solutions. The effect of some parameters on copper
biosorption has been studied using date stones and palm-tree waste as solid sorbents. Results show that the highest percentage
of copper adsorption was obtained for the smallest size of the sorbent particles. The biosorption process was found to occur
rapidly, i.e. the maximum sorption capacity was reached within 20 min. The process involved pseudo-second-order kinetics with
an activation energy value within the normal range considered for processes, where a physical interaction between the sorbate
and the sorbent solid predominated. The thermodynamic parameters of the copper ions uptake onto the solid sorbents indicated
that, the process was endothermic and proceeds spontaneously from the date stones. However, the thermodynamic studies of the
adsorption of copper on palm-tree waste indicated that the process was exothermic and proceeds spontaneously. 相似文献
992.
Rapid incorporation and short-term distribution of a nonylphenol isomer and the herbicide MCPA in soil-derived organo-clay complexes 总被引:1,自引:0,他引:1
Patrick Riefer Timm Klausmeyer Jan Schwarzbauer Andreas Sch?ffer Burkhard Schmidt Phillipe F. X. Corvini 《Environmental Chemistry Letters》2011,9(3):411-415
Organo-clay complexes in soil are a major sink for xenobiotics and, thus, often enhance their persistence dramatically. However,
the knowledge on environmental processes of non-extractable residue formation on a short time scale is very restricted. Therefore,
this study examined the distribution of 4-(3,5-dimethylhept-3-yl)phenol (NP) and 4-chloro-2-methylphenoxyacetic acid (MCPA)
in soil over a short time period of 48 h and in different soil sub-fractions. The overall proportion of organo-clay-associated
bound residues was not only abundant but also in the same range for both substances (MCPA: 8%; NP: 11% of applied 14C-radioactivity). However, a more detailed view revealed two different distribution patterns: a higher proportion of clay-associated
NP was accompanied by a lower content of bound residues, whereas a smaller fraction of clay-associated MCPA was characterized
by a higher proportion of non-extractable residues. Further on, a selective accumulation of bound residues among clay-associated
humic fractions was observed. NP residues were linked predominantly to humic acids, whereas MCPA residues tended to be incorporated
more into fulvic acids. It was evident that the overall distribution was influenced primarily by the physico-chemical properties
of the contaminants. This study demonstrates in detail a rapid initial incorporation accompanied by a specific distribution
into soil sub-fractions for selected xenobiotics in soil and points to a complex interaction of clay-associated organic matter
with low molecular weight compounds. 相似文献
993.
Pedro Gon?alves Rodrigues Lu��s Moreira Gon?alves Paulo Jorge Magalh?es Jo?o Grosso Pacheco Jos�� Ant��nio Rodrigues Aquiles Ara��jo Barros 《Environmental Chemistry Letters》2011,9(3):405-410
An major research area in environmental chemistry is the development of methods for the analysis of biomarkers. Metallothioneins
are used as biomarkers in studies of heavy metals exposure in water, because metallothioneins are synthesized and accumulated
when organisms are exposed to toxic concentrations of pollutants. In this work, simple and sensitive voltammetric methods
were developed for metallothionein and copper (II) determinations in fish liver Lepomis gibbosus. Both analytical methodologies were optimized and applied to samples extracted from individuals previously submitted to sub-lethal
toxicological trials with copper sulphate (CuSO4) and cadmium chloride (CdCl2). The obtained results showed that both methods are very precise, sensitive, and involve simple sample preparation processes.
Moreover, metallothioneins showed better correlation with the toxic exposure than Cu2+. To the best of our knowledge, this is the first time that hepatic metallothioneins and Cu2+ contents are voltammetrically determined in order to be compared in their function as heavy metal biological indicators. 相似文献
994.
Modified ��-cyclodextrins as prospective agents for improving water solubility of organic pesticides
The drawback of some organic pesticides is their low water solubility. Cyclodextrins are used as agents for improving pesticides
water solubility. However, the stabilization of the crystalline lattice can reduces to a large extent the solubility of cyclodextrins,
especially β-cyclodextrin. Here, searching for the water soluble β-cyclodextrin derivatives, a set of new “host” compounds
were prepared by the reaction of β-cyclodextrin with methyl epoxycinnamate. The reactants ratio was varied in to study the
substitution degree of the obtained derivatives. The structure was determined by the 1H-NMR and FT IR spectra. The average degree of substitution was determined by integration of the corresponding NMR signals
and by elemental analysis. The solubility of four selected pesticides: dimethoate, simazine, linuron and thiram, in water
with and without addition of the new modified β-cyclodextrin was measured by ultraviolet spectrophotometry. Our results showed
that the modified β-cyclodextrins significantly improve solubility of pesticides. 相似文献
995.
996.
da Silveira RP Rodrigues AP Santelli RE Cordeiro RC Bidone ED 《Environmental monitoring and assessment》2011,181(1-4):165-173
This study addressed the identification and monitoring of pollution sources of terrestrial origin in rivers (domestic sewage and industrial effluents) and critical fluvial segments in highly polluted environments under tidal influence (mixing marine and continental sources) from Guanabara Bay Basin, Rio de Janeiro, Brazil. The mass balance of contaminants was determined in conditions of continuous flow (low tide) during dry season (lower dilution capability). The results allowed the evaluation of the potential of contaminant mass generation by the different river segments and the estimation of their natural and anthropogenic components. The water quality of Igua?ú and Sarapuí Rivers were evaluated for metals and biochemical oxygen demand. The method gave an excellent response, including the possibility of sources identification and contaminated river segments ranking. The approach also offers fast execution and data interpretation, being highly efficient. 相似文献
997.
Stähli M Badoux A Ludwig A Steiner K Zappa M Hegg C 《Environmental monitoring and assessment》2011,174(1-4):91-106
Long-term data on precipitation and runoff are essential to draw firm conclusions about the behavior and trends of hydrological catchments that may be influenced by land use and climate change. Here the longest continuous runoff records from small catchments (<1 km(2)) in Switzerland (and possibly worldwide) are reported. The history of the hydrological monitoring in the Sperbel- and Rappengraben (Emmental) is summarized, and inherent uncertainties in the data arising from the operation of the gauges are described. The runoff stations operated safely for more than 90% of the summer months when most of the major flood events occurred. Nevertheless, the absolute values of peak runoff during the largest flood events are subject to considerable uncertainty. The observed differences in average, base, and peak runoff can only partly be attributed to the substantial differences in forest coverage. This treasure trove of data can be used in various ways, exemplified here with an analysis of the generalized extreme value distributions of the two catchments. These distributions, and hence flood return periods, have varied greatly in the course of one century, influenced by the occurrence of single extreme events. The data will be made publicly available for the further analysis of the mechanisms governing the runoff behavior of small catchments, as well as for testing stochastic and deterministic models. 相似文献
998.
B?a?ej Kud?ak Lidia Wolska Jacek Namie?nik 《Environmental monitoring and assessment》2011,174(1-4):509-516
The sensitivity of Heterocypris incongruens to selected heavy metal ions is discussed. Although the Ostracodtoxkit ${\textregistered}$ has been present on the market for a few years, data on its selectivity and sensitivity to toxicants is scarce; such data is indispensable when interpreting the results of sediment toxicity. The LC50 and EC50 results with the Ostracodtoxkit ${\textregistered}$ are compared with those obtained with other commercially available ??direct-contact?? tests (utilizing Hyalella azteca and Chironomus riparius) and microbiotests for assessing the toxicity of aqueous samples (Vibrio fischeri, Daphnia magna, and Selenastrum capricornatum). The sensitivity of H. incongruens to metal ions (Cd2?+?>?>Hg2?+?> Cu2?+?>Cr6?+?>Ni2?+???Mn7?+?>Zn2?+?>Pb2?+?>Li1?+?> Fe3?+?) was found to be similar to that of H. azteca and of C. riparius. The Ostracodtoxkit ${\textregistered}$ has shown itself to be an efficient and reliable element of test batteries for toxicity determination. 相似文献
999.
Mehmet H. Sonmete Can Ertekin Hakan O. Menges Haydar Hac?sefero?ullari Fatih Evrendilek 《Environmental monitoring and assessment》2011,175(1-4):251-277
Solar radiation data are required by solar engineers, architects, agriculturists, and hydrologists for many applications such as solar heating, cooking, drying, and interior illumination of buildings. In order to achieve this, numerous empirical models have been developed all over the world to predict solar radiation. The main objective of this study is to examine and compare 147 solar radiation models available in the literature for the prediction of monthly solar radiation at Ankara (Turkey) based on selected statistical measures such as percentage error, mean percentage error, root mean square error, mean bias error, and correlation coefficient. Our results showed that Ball et al. (Agron J 96:391?C397, 2004) model and Chen et al. (Energy Convers Manag 47:2859?C2866, 2006) model performed best in the estimation of solar radiation on a horizontal surface for Ankara. 相似文献
1000.
Edgar Hiller Lenka Zemanov?? Maro? Sirotiak L??ubom??r Jurkovi? 《Environmental monitoring and assessment》2011,173(1-4):883-897
Dredging water reservoirs is necessary to maintain accumulation capacity and to prevent floodings. As a first step, the quality of the bed sediments in water reservoirs must be determined before dredging operations. In this study, sediment samples from 34 stations of three selected water reservoirs (Zemplinska Sirava, Velke Kozmalovce, and Ruzin) were collected to investigate concentrations, distributions, and hazards of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) and to predict their possible sources. Total PCB concentrations were in the range of 20.4 to 2,325?ng/g. The maximum concentrations of PCBs were found in sediments from Zemplinska Sirava, which is in the vicinity of a former manufacturer of PCBs. The composition of PCBs was characterized by tri- and hexa-CB congeners, indicating the influence of contamination from the use of specific Delor mixtures, formerly produced and massively used on the territory of Slovakia. The data showed that the highest total PAH concentrations were associated with the sediments from the Velke Kozmalovce, ranging from 7,910 to 29,538?ng/g. On the other hand, the lowest total PAH concentrations (84?C631?ng/g of dry weight) were found in the sediments of Zemplinska Sirava, an important recreational area in eastern Slovakia. The distribution of individual PAHs was similar among the three water reservoirs, and this, together with principal component analysis and diagnostic PAH ratios, suggests mainly pyrolytic contamination of the sediments. However, petrogenic inputs appear to be important in the Zemplinska Sirava sediments. 相似文献