Adsorption of arsenic using high surface area magnetites

Magnetites (MEBWx) were prepared by precipitation in 1-butanol/water mixtures of various mole ratios of 1-butanol to water. It was found that the magnetites prepared in the mixture with high mole ratio of 1-butanol to water have high specific surface area. The adsorption isotherms of As(III) and As(V) with the magnetites at 303 K fitted the Langmuir model well. The adsorption capacities of the magnetite prepared in the mixtures were higher than those of the magnetite prepared without 1-butanol. Their adsorption capacities increased with increasing specific surface area.     

Adjustment of web-building initiation to high humidity: a constraint by humidity-dependent thread stickiness in the spider Cyrtarachne

Cyrtarachne is an orb-weaving spider belonging to the subfamily Cyrtarachninae (Araneidae) which includes triangular-web-building Pasilobus and bolas spiders. The Cyrtarachninae is a group of spiders specialized in catching moths, which is thought to have evolved from ordinary orb-weaving araneids. Although the web-building time of nocturnal spiders is in general related to the time of sunset, anecdotal evidence has suggested variability of web-building time in Cyrtarachne and its closely related genera. This study has examined the effects of temperature, humidity, moonlight intensity, and prey (moths) availability on web-building time of Cyrtarachne bufo, Cyrtarachne akirai, and Cyrtarachne nagasakiensis. Generalized linear mixed model (GLMM) have revealed that humidity, and not prey availability, was the essential variable that explained the daily variability of web-building time. Experiments measuring thread stickiness under different humidities showed that, although the thread of Cyrtarachne was found to have strong stickiness under high humidity, low humidity caused a marked decrease of thread stickiness. By contrast, no obvious change in stickiness was seen in an ordinary orb-weaving spider, Larinia argiopiformis. These findings suggest that Cyrtarachne adjusts its web-building time to favorable conditions of high humidity maintaining strong stickiness, which enables the threads to work efficiently for capturing prey.     

Temporal Trends of Non-sea Salt Sulfate and Nitrate in Wet Deposition in Japan

Temporal trends of non-sea salt (nss-) sulfate and nitrate were analyzed from nationwide precipitation chemistry measurements provided by the Ministry of the Environment (MOE) for the 1988–2002 fiscal years (April–March). The concentrations and deposition of nss-sulfate were found to be decreasing, and those of nitrate were stable or slightly increasing at most sites. These deposition trends were discussed from the viewpoint of emissions of SO₂ and NO_X during the period of interest. Because monitoring techniques have changed in the number of active sites, samplers, and analytical methods during the operation period, the median of all annual depositions measured in Japan in a specific year was selected as the annual representative. The contribution of specific emission sources was also calculated for 1990 on the basis of the nss-sulfate and nitrate deposition in Japan obtained with a model simulation in which the model did not include volcanic emissions from Mt. Oyama, Miyakejima Island, which began to erupt suddenly and violently in 2000. For nss-sulfate, the calculated deposition agrees well with the intensity and trends of the median up to 1999. After 2000, a higher deposition than calculated in the preceding years was evident, which is attributable to the volcanic SO₂ from Mt. Oyama. For nitrate, both the calculated and observed depositions were slightly increasing; however, the calculation was found to exceed the observation.     

Occurrence and detrimental effects of the bivalve-inhabiting hydroid <Emphasis Type="Italic">Eutima japonica</Emphasis> on juveniles of the Japanese scallop <Emphasis Type="Italic">Mizuhopecten yessoensis </Emphasis>in Funka Bay,Japan: relationship to juvenile massive mortality in 2003

In November 2003, we first observed prevalent occurrence of a hydroid, Eutima japonica, on soft body tissues of age zero Japanese scallop (Mizuhopecten yessoensis) juveniles cultured in large areas of Funka Bay, Hokkaido. The occurrence coincided with massive death of juvenile scallops. A major objective was to clarify ecological relationships between the symbionts, and to infer the relationship between symbiosis and the massive mortality. To do this, we investigated distributions of association rates of hydroids with juvenile scallops at 15–34 sites over 3 years (2003–2005), with age one adult scallops at 24 sites in 2003, and with mussels at 13 sites in 2004. We studied seasonal changes in association rates with juvenile scallops, and numbers of polyps per juvenile scallop at three sites from November 2003 to June 2004. We also quantified the hydroid impacts on juvenile scallop shell length growth and triglyceride accumulation in the digestive gland. The association rate of E. japonica polyps with juvenile scallops was high in large areas of Funka Bay in 2003, and overlapped the distribution of mussels bearing polyps. Association rates with age one adult scallops were very low in November 2003, even at the sites where polyps were very common on juvenile scallops. Levels of hydroid occurrence in juvenile scallops varies by year. We found that hydroids presence in juvenile scallops declined drastically in 2004 and 2005. The association rates with juvenile scallops, and numbers of polyps per juvenile scallop declined during winter, until they disappeared completely in the following June. Since polyps were rare in adult scallops, we believe that infection of juvenile scallops was probably initiated from the planulae produced by medusae released from polyps growing on Mytilus spp., especially M. galloprovincialis. Subsequently, the inhabitation spread intraspecifically and interspecifically. In juvenile scallops, inhabitation of polyps reduced shell length growth by 43%, and triglyceride accumulation in digestive glands by 24–47%. Inhabitation of E. japonica on juvenile scallop is best regarded as parasitism, rather than inquilinism or commensalism. Occurrence of polyps was probably not a direct lethal factor for juvenile scallops, because there were some sites where association rates were high, but mortalities were low. Massive mortalities in 2003 may have resulted from simultaneous impacts of heavy polyp load and stresses caused by the way in which the animals were handled (transferred from cages for pre-intermediate culture to cages for intermediate culture), because the massive mortality occurred within a month of the transfer. The presence of polyps in juvenile scallops does not affect the quality of the product in Funka Bay, because market size scallops are hydroid-free.     

High performance liquid chromatographic determination of pesticides in soluble phase and suspended phase in river water

A high performance liquid chromatographic method has been developed to determine pesticides in river water as both dissolved phase and suspended phase. The target pesticides were eight herbicides, asulam, diuron, flazasulfuron, linuron, MCPB, mecoprop, pyrazosulfuron‐ethyl and siduron, and two fungicides, oxine‐copper and thiram. The pesticides in filtered river water were extracted with styrene‐divinylbenzene copolymer and were eluted with acetonitrile. The pesticides on suspended solids were extracted ultrasonically with acetonitrile. Each eluate was concentrated and analyzed by HPLC with multiwavelength detector. Recoveries of the pesticides in the overall procedure of this method were 78–114% for filtered river water and 75–107% for suspended solids. The limits of detection in water and suspended solids ranged from 0.1 to 0.9 μg/L and 1 to 7 μg/g, respectively. Pesticide distribution between soluble phase and suspended phase in river water was measured by this method.     

Estimation and validation of biomass of a mountainous agroecosystem by means of sampling,spectral data and QuickBird satellite image

Biomass estimation in agroecosystems (AESs) is important to understand their role in carbon exchange for a sustainable environment. We used field spectra and sampled biomass of an AES including cultivated and abandoned croplands to develop a simple biomass estimation model. The digital number (DN) of a QuickBird (QB) satellite image was converted to a reflectance factor using the dark object subtraction method and the spectral reflectance of asphalt. The relationship between the reflectance factor of field-based spectra and the QB image obtained in early July 2007 was insignificant in the blue (R ² = 0.15) and green (R ² = 0.18) bands but was significant (p < 0.05) in the red (R ² = 0.57) and near-infrared (NIR, R ² = 0.45) bands in the AES. Better correlations were obtained between field-based and QB-based vegetation indices (VIs). The best correlations were obtained with the normalized difference vegetation index (NDVI) (R ² = 0.97, p < 0.001) and the ratio vegetation index (RVI) (R ² = 0.99, p < 0.001). Biomass was significantly correlated with both field-based NDVI and RVI (R ² = 0.79 and 0.72, respectively, p < 0.001). Although RVI saturated at higher biomass densities (>600 g m^?2), NDVI showed a linear relationship. Other field-based VIs showed poorer correlations with biomass. The model was evaluated by incorporating it into high-resolution QB images to obtain the observed biomass. The relationship between field-estimated and QB-observed biomass appeared to be a one-to-one linear relationship (R ² = 0.79). Thus, models using field spectra and sampled biomass can be applied to QB images for remote estimation of biomass in an AES.     

Leaching characteristics of solid wastes from thermal power plants of western Turkey and comparison of toxicity methodologies

Use of lignite in power generation has led to increasing environmental problems associated not only with gaseous emissions, but also with the disposal of ash residues. In particular, use of low quality coals with high ash content results in huge quantities of both fly and bottom ashes to be disposed of. A main problem related to coal ash disposal is the heavy metal content of the residue. In this regard, experimental results of numerous studies indicate that toxic trace metals may leach when fly and bottom ashes are in contact with water. In this study, fly and bottom ash samples obtained from thermal power plants, namely Yenikoy, Kemerkoy and Yatagan, located at the southwestern coast of Turkey, were subjected to toxicity tests such as the extraction (EP) and toxicity characteristic leaching (TCLP) procedures of the US Environmental Protection Agency (USEPA) and the so-called 'Method A' extraction procedure of the American Society of Testing and Material (ASTM). The geochemical composition of ash samples showed variations depending on the coal burned in the plants. Furthermore, the EP, TCLP and ASTM toxicity tests showed variations such that the ash samples were classified as 'toxic waste' based on EP and TCLP results whereas they were classified as 'non-toxic' based on ASTM results, indicating test results are pH dependent. When the extraction results were compared with the chemical composition of water samples obtained in the vicinity of the thermal power plants, it was found that the results obtained using the ASTM procedure cannot be used to predict subsurface contamination whereas the EP and TCLP procedures can be used.     

Investigation of unsaturated water flow in a deep vadose zone by applying quasi-partition law to 222Rn

This paper describes an application of the quasi-partition law of radon-222 (222Rn) to a deep unsaturated vadose zone in a field. 222Rn is a very useful tracer to investigate not only saturated but also unsaturated water flows in vadose zones. Concentrations of 222Rn in water in unsaturated soils are, based on the quasi-partition law, lower than those in saturated soils. However, no study has previously applied quasi-partition law of 222Rn to analyze saturated and unsaturated water flows in vadose zones. In this study, we observed the applicability of existing theoretical equations of quasi-partition law of 222Rn experimentally. After confirming the validity of the theoretical equation, we applied this equation to estimate the unsaturated water flow in an actual vadose zone. By comparing the estimated degree of saturation from 222Rn measurement with that from a neutron moisture meter measurement, we obtained a beautiful agreement between them.     

Eco-friendly recovery process of lithium from reduction roasting residue powder based on hydrothermal extraction

Journal of Material Cycles and Waste Management - To cater to the increasing demand for secondary lithium-ion batteries, the recovery of valuable metal species in spent batteries is increasingly...