Evaluation of a fast wastewater odour characterisation procedure using a chemical sensor array

Sewage treatment works are one of the major sources that cause atmospheric odour pollution. The increase in the number of complaints about odour nuisance is due to the increase in environmental concerns. Unfortunately, the legislation on odour nuisance from sewage treatment works is very limited. In order to determine suitable thresholds on which to base legal standards, reliable and efficient odour measurement methods need to be defined. A chemical sensor array was developed for the purpose of measuring wastewater odour. This paper describes the development of the chemical sensor system which is specifically tuned to odours of wastewater origin and which can give an electronic measure of the wastewater odours. Odour emissions from a wastewater treatment facility were detected by using a quartz crystal microbalance (QCM) sensor array. The array consists of nine sensor elements, which were coated with different materials. In this paper, the usage of these novel instruments in the water industry was shown.     

Mineral contents of seed and seed oils of Capparis species growing wild in Turkey

The mineral contents of seed and seed oils of Capparis species growing wild in Turkey were established by inductively coupled plasma–atomic emission spectrometry. Capparis spinosa var. spinosa (2010) and Capparis ovata var. canescens variety (2009) were determined to be rich in terms of mineral matter as 19,514.60 and 16,995.92 ppm as a total, respectively. C. spinosa var. spinosa collected from Mu?la-Milas region (2009) had the highest amount of Ca with 1,010.67 ppm in C. spinosa species and in C. ovata species. C. ovata var. canescens collected from Ankara-Beypazar? (2010) region had the highest amount of Ca with 833.92 ppm Ca amount in C. spinosa var. spinosa, inermis, herbaceae seeds decreased in 2010. C. spinosa var. inermis collected from Antalya-Serik (2010) in C. spinosa species had rich amount of Ca with 123.78 ppm and C. ovata var. palaestina seed oils collected from Mardin-Savur region (2009) had rich amount of Ca with 253.71 ppm in C. ovata species. The oil of C. spinosa var. herbaceae variety collected from Mardin-Midyat region (2010) was determined to have the highest major mineral matter (Ca, K, Mg, Na, and P) with 1,424.37 ppm in C. spinosa species. It was also determined that as a result, caper seed and oils were found to be important sources of nutrients and essential elements.     

Quality of water used during cage cultivation of rainbow trout (Oncorhynchus mykiss) in Bereket HES IV Dam Lake (Muğla,Turkey)

A thorough investigation of the impact of rainbow trout (Oncorhynchus mykiss) cultivation on surface water quality in the area known as Bereket HES IV Dam Lake was conducted. Water samples were collected from October 2009 to June 2010 from four stations in the Dam Lake and analyzed for water temperature, pH, dissolved oxygen, electrical conductivity, nitrite nitrogen, nitrate nitrogen, and orthophosphate. Surface water quality was then evaluated based on the comparison of samples collected from three stations located near fish cages to those collected from a reference station outside the cultivation area as well as by the comparison with standards specified in the Water Pollution Registration Act. According to the Water Pollution Registration Act, the surface water quality of the Dam Lake was class I. Additionally, there were no significant differences in water quality within the Dam Lake among any of the sampling stations, including the reference station. Overall, these findings indicate that cage cultivation of rainbow trout may have a negative impact on the entire Dam Lake.     

Grading of Parameters for Urban Tree Inventories by City Officials, Arborists, and Academics Using the Delphi Method

Tree inventories are expensive to conduct and update, so every inventory carried out must be maximized. However, increasing the number of constituent parameters increases the cost of performing and updating the inventory, illustrating the need for careful parameter selection. This article reports the results of a systematic expert rating of tree inventories aiming to quantify the relative importance of each parameter. Using the Delphi method, panels comprising city officials, arborists, and academics rated a total of 148 parameters. The total mean score, the top ranking parameters, which can serve as a guide for decision-making at practical level and for standardization of tree inventories, were: Scientific name of the tree species and genera, Vitality, Coordinates, Hazard class, and Identification number. The study also examined whether the different responsibilities and usage of urban tree databases among organizations and people engaged in urban tree inventories affected their prioritization. The results revealed noticeable dissimilarities in the ranking of parameters between the panels, underlining the need for collaboration between the research community and those commissioning, administrating, and conducting inventories. Only by applying such a transdisciplinary approach to parameter selection can urban tree inventories be strengthened and made more relevant.     

Aerobic in situ stabilization of Landfill Konstanz Dorfweiher: Leachate quality after 1 year of operation

Modern landfill understanding points out controlled operation of landfills. Emissions from landfills are caused mainly by anaerobic biodegradation processes which continue for very long time periods after landfill closure. In situ landfill stabilization aims controlled reduction of emissions towards reduced expenditures as well as aftercare measures. Since April 2010, a new in situ stabilization technique is being applied at a pilot scale landfill (BAIV) within Landfill Konstanz Dorfweiher. This new method utilizes intermittent aeration and leachate recirculation for waste stabilization. In this study, influence of this technique on leachate quality is investigated. Among many other parameters, leachate analyses were conducted for COD, BOD₅, NH₄–N, NO₂–N, NO₃–N, TKN and chloride besides continuously on site recorded pH, electrical conductivity and oxidation–reduction potential (ORP). Results from leachate quality analyses showed that biological activity in the landfill was accelerated resulting in initial higher leachate strength and reduced emission potential of landfill. During full scale in situ aeration, ambient conditions differ from optimized laboratory scale conditions which mainly concern temperature increase and deficient aeration of some landfill parts (Ritzkowski and Stegmann, 2005). Thus, as a field application results of this study have major importance on further process optimization and application.     

Investigation of Nanoparticle Additives to Biodiesel for Improvement of the Performance and Exhaust Emissions in a Compression Ignition Engine

Worldwide energy demand has been growing steadily during the past five decades and most experts believe that this trend will continue to rise. The amount of emitted harmful emission gases increases in parallel with increasing energy consumption. This increase has forced many countries to take various precautions, and various restrictions on emitted emissions have been carried. In this study, effects of addition of oxygen containing nanoparticle additives to biodiesel on fuel properties and effects on diesel engine performance and exhaust emissions were investigated. Two different nanoparticle additives, namely MgO and SiO₂, were added to biodiesel at the addition dosage of 25 and 50 ppm. Fuel properties, engine performance, and exhaust emission characteristics of obtained modified fuels were examined. As a result of this study, engine emission values NO_x and CO were decreased and engine performance values slightly increased with the addition of nanoparticle additives.     

Interactions between metals accumulated in the narrow-clawed crayfish Astacus leptodactylus (Eschscholtz, 1823) in Dikilitaş Lake,Turkey

The accumulations of Al, Cd, Cr, Cu, Fe, Ni, Pb and Zn in the exoskeleton, gills, hepatopancreas and abdominal muscles of crayfish Astacus leptodactylus (Eschscholtz, 1823) were determined. The strongest correlation observed was between Cr and Ni in the gills (r?=?0.904); moderate to strong correlations between Al, Cr, Fe, Ni and Cu were also observed in gill tissue. Disregarding the gills, the strongest correlation was found between Cu and Zn in the hepatopancreas (r?=?0.808); the correlation between these two metals might have been a result of metallothionein activity. The accumulation of Pb was found to correlate with that of Cd in the exoskeleton, Cd and Zn in the gills, Zn and Cu in the hepatopancreas and Cu in the abdominal muscle. None of these correlations were present in lakewater and sediment samples, suggesting that the crayfish metabolism may be responsible for the co-accumulation of metal–metal pairs. As all correlations in non-gill tissues are observed between divalent metals, a shared transporter such as divalent metal transporter 1 might be involved in the accumulation of these metals.     

Composite of Natural Polymers and Their Adsorbent Properties on the Dyes and Heavy Metal Ions

Journal of Polymers and the Environment - Natural polymers such as chitosan, chitin, cellulose, alginate, pectin, and lignin produced by renewable organic resources are regarded as greener,...