Unravelling the molecular mechanism of mutagenic factors impacting human health

Environmental Science and Pollution Research - Environmental mutagens are chemical and physical substances in the environment that has a potential to induce a wide range of mutations and generate...     

Seasonal variability of ambient NH3, NO, NO2 and SO2 over Delhi

We present the diurnal and seasonal variability of ambient NH3, NO, NO2 and SO2 over Delhi, India. Ambient NH3, NO and NO2 were measured continuously during winter, summer and autumn seasons using NH3- and NOx-analyzer, which operates by chemiluminescence method with a higher estimation e ciency (> 90%) than the chemical trap method (reproducibility 4.7%). Prominent diurnal, day-to-day and seasonal variations of ambient mixing ratio of NH3, NO, NO2 and SO2 were observed during the study period. Seasonal variation with higher mixing ratio in winter was observed for all measured trace gases except NO. Day-night variation of all measured trace gases observed was higher in winter in comparison with summer. Late morning increase in NO2 mixing ratio might be attributed to conversion of NO to NO2 with the interaction of O3.     

Modeling studies of ammonia dispersion and dry deposition at some hog farms in North Carolina

A modeling study was conducted on dispersion and dry deposition of ammonia taking one hog farm as a unit. The ammonia emissions used in this study were measured under our OPEN (Odor, Pathogens, and Emissions of Nitrogen) project over a waste lagoon and from hog barns. Meteorological data were also collected at the farm site. The actual layout of barns and lagoons on the farms was used to simulate dry deposition downwind of the farm. Dry deposition velocity, dispersion, and dry deposition of ammonia were studied over different seasons and under different stability conditions using the short-range dispersion/air quality model, AERMOD. Dry deposition velocities were highest under near-neutral conditions and lowest under stable conditions. The highest deposition at short range occurred under nighttime stable conditions and the lowest occurred during daytime unstable conditions. Significant differences in deposition over crop and grass surfaces were observed under stable conditions.     

Are consumers willing to pay for conservation agriculture? The case of white maize in the Democratic Republic of the Congo

Throughout the low-income world, agricultural producers have a motivation to slash-and-burn rainforests as they cannot afford inorganic fertilizers. Farmers in the Democratic Republic of the Congo (DRC), who are predominantly women, are often forced to walk long distances to cultivate more productive lands, when fertility near their villages is reduced. On their way and while working away from home, women become targets for rape. Adopting conservation agriculture (CA) could help mitigate deforestation and potentially create a safer environment for women. Limited knowledge about the benefits of CA across countries in Sub-Saharan Africa (SSA) has hindered its adoption. Taking these impediments into account, we estimate if consumers in the DRC are willing to pay (WTP) a premium for CA, using maize flour as the medium. By means of a double-bounded dichotomous choice valuation method, 600 consumers in Bukavu, DRC, were surveyed about their willingness-to-pay for CA-produced maize. Our study finds that only those consumers who identify themselves as farmers are WTP a premium. This study indicates that if CA adoption is to spread in the DRC, it will likely need to happen via increased yields or reduced costs before the farm gate and not premiums after the farm gate.     

Selective sensing of mercury(II) using PVC-based membranes incorporating recently synthesized 1,3-alternate thiacalix[4]crown ionophore

The construction and electrodes characteristics of poly(vinylchloride) (PVC)-based polymeric membrane electrode (PME) and coated graphite electrode (CGE), incorporating 1,3-alternate thiacalix[4]crown as ionophore for estimation of Hg(II) ions, are reported here. The best potential response was observed for PME-1 having membrane composition of: ionophore (6.2 mg), PVC (100.0 mg), 2-nitrophenyl octyl ether (2-NPOE; 200.0 mg), and sodium tetraphenyl borate (NaTPB; 2.0 mg); for CGE-1 with the membrane composition: ionophore (3.5 mg), PVC (40.0 mg), 2-NPOE (80.0 mg), and NaTPB (2.0 mg). The electrodes exhibits Nernstian slope of 29.16 mV/decade with PME-1 and 30.39 mV/decade with CGE-1 for Hg(II) ions over wide concentration range, i.e., 1.0?×?10^?1 to 5.0?×?10^?6?M with PME-1 and 1.0?×?10^?1 to 5.0?×?10^?7?M with CGE-1. Lower detection limits were found to be 9.77?×?10^?6?M for PME-1 and 7.76?×?10^?7?M for CGE-1 with response time varying from 10 to 20 s. Also, these electrodes work within pH range of 2.0–6.0 for PME-1 and 1.5–6.5 for CGE-1. Overall, CGE-1 has been found to be better than PME-1. CGE-1 has been used as indicator electrode for the potentiometric titration of Hg(II) ions with EDTA as well as successfully applied for determination of Hg(II) content in wastewater, insecticide, dental amalgam, and ayurvedic medicines samples with very good performance (0.9974 correlation coefficient in the comparison against volumetric method).     

Identification and Classification of Key Variables and their Role in Environmental Impact Assessment: Methodology and Software Package Intra

There is, as yet, no proven methodology to enable, objectively,the identification of key parameters out of a large number one normally encounters during any EIA. As EIA is a costly and time-consuming exercise, it is necessary to separate the man from the boys – so to speak – in order to optimize costs andefforts.In this paper a methodology for distinguishing the moreimportant parameters from the less important ones, developed byus, is described. The methodology aims at identifying andshortlisting the key parameters which ought to be studied in agiven EIA situation, thereby helping in reducing time, effort,and cost of EIA. With this methodology a system structure is developed whichgives hierarchical pattern of inter-parameter interaction, andreveals several distinguishing features of each parameter. Asoftware package INTRA (INTer-parameter Relationship Analysis)based on this methodology, has been developed. The paper alsodescribes a case study in which INTRA has been used to study theenvironmental impacts of urbanization of a typical third worldtown (Roorkee).