Simulation and life cycle assessment of process design alternatives for biodiesel production from waste vegetable oils

This study uses the process simulator ASPEN Plus^® and Life Cycle Assessment (LCA) to compare three process design alternatives for biodiesel production from waste vegetable oils that are: the conventional alkali-catalyzed process including a free fatty acids (FFAs) pre-treatment, the acid-catalyzed process, and the supercritical methanol process using propane as co-solvent. Results show that the supercritical methanol process using propane as co-solvent is the most environmentally favorable alternative. Its smaller steam consumption in comparison with the other process design alternatives leads to a lower contribution to the potential environmental impacts (PEI’s). The acid-catalyzed process generally shows the highest PEI’s, in particular due to the high energy requirements associated with methanol recovery operations.     

The effect of copper sulphate on some biochemical parameters of rainbow trout

Copper sulphate has an adverse effect on some biochemical parameters of trout Salmo gairdneri. The main targets of damage are: (a)Tissue necrosis as demonstrated by increased ASAT and ALAT levels in blood plasma. (b)Inhibition of acetylcholinesterase activity. There is also a general stress effect as reflected by an elevated blood glucose level.     

Natural radiation exposure in the Campo Arañuelo region in the surroundings of Almaraz nuclear power station (Spain)

During 1998 regional surveys were conducted to evaluate natural radiation exposure of people in the vicinity of the six Spanish nuclear power stations. Indoor radon, external gamma dose rates outdoors and indoors and radioactivity in soil were measured in these surveys. The highest mean annual effective dose to the population was found in the surroundings of the Almaraz nuclear power plant in the province of Cáceres and was mainly due to the presence of high radon concentrations in homes. In order to make a more accurate assessment of the dose coming from the radon in this area, a new and more extensive surgery on indoor radon with a total of 380 measurements was carried out in 2000 in the Campo Ara?uelo region around the Almaraz nuclear power station. From the results obtained in this survey, a population-weighted mean annual effective dose from radon exposure of 1.7 mSv y(-1), 44% lower than that previously reported in 1998, was estimated for the whole Campo Ara?uelo region. The maximum dose value due to radon exposure, about 4 mSv y(-1), was reached in the so-called La Vera area located in the north of this region. The relationship between the indoor radon concentrates experimentally measured, the geological characteristics of this geographic area and the information provided by the radiation map of the Spanish MARNA Project is also analyzed, confirming that La Vera area should be considered as a high radon level area.     

Factors controlling measurements of radon mass exhalation rate

Radon mass exhalation rate of soil samples was measured using an exhalation chamber of 10 dm(3) volume and a Lucas cell. The results show that mass of sample, grain size and water content influence the radon mass exhalation rate. For soil of (226)Ra activity concentration about 2500 Bq kg(-1) and samples within the range from 0.20 kg to 0.50 kg, the radon mass exhalation rate values are higher than those for samples of other masses. The observed radon exhalation rate is an inverse function of the average grain size. At the water content about 6% by weight, the radon mass exhalation rate reaches maximum, then it decreases with both increasing and decreasing of the water content in the sample.     

Utilization of magnetic and electrostatic separation in the recycling of printed circuit boards scrap

The progress of the technology is directly related to the growth of production and consumption of electrical/electronics equipment, especially of personal computers. This type of equipment has a relatively short average lifetime, 2-3 years. The amount of defective or obsolete equipment has been increasing substantially; consequently its disposition and/or recycling should be studied. In this work, printed circuit boards, which are used in personal computers, were studied in order to recover the metals in the circuit boards through mechanical processing, such as crushing, screening, as well as magnetic and electrostatic separation. The results obtained demonstrate the feasibility of using these processes to separate metal fractions from polymers and ceramics, and that it is possible to obtain a fraction concentrated in metals containing more than 50% on average of copper, 24% of tin and 8% of lead.     

Avoidance behaviour of Enchytraeus albidus: effects of benomyl, carbendazim, phenmedipham and different soil types

Enchytraeids are typical inhabitants of many soils, contributing to vital processes of this environmental compartment. Indirectly they are involved in regulating the degradation of organic matter, as well as improving the pore structure of the soil. Due to their behaviour, they are able to avoid unfavourable environmental conditions. Avoidance tests with enchytraeids, initially developed with earthworms by several authors, are quick and easy to perform. With these tests a first assessment of the toxicity of a (contaminated or spiked) soil is possible in just 48 h by using the reaction of the enchytraeids as measurement endpoint. In this period of time the organisms can choose between the control soil and the other soil (a contaminated or spiked or another soil with different physico-chemical properties). In the tests reported here, the enchytraeids were exposed to control soils spiked with the fungicides Benomyl and Carbendazim and the herbicide Phenmedipham. Several chemical concentrations were tested in order to evaluate the avoidance behaviour to toxic substances. In fact, often these short-term screening tests gave results showing avoidance at concentrations in a range similar to the acute test results but, higher than in chronic tests. Further tests are needed to decide whether the results gained in this study can be extrapolated to other chemicals. It is proposed to standardize the Enchytraeid Avoidance Test as it is currently done for the Earthworm Avoidance Test by the International Standard Organization (ISO).     

Genuine modern analogues of Precambrian stromatolites from caldera lakes of Niuafoʻou Island, Tonga

Calcareous or dolomitic, often secondarily silicified, laminated microbial structures known as stromatolites are important keys to reconstruct the chemical and biotic evolution of the early ocean. Most authors assume that cyanobacteria-associated microbialitic structures described from Shark Bay, Western Australia, and Exuma Sound, Bahamas, represent modern marine analogues for Precambrian stromatolites. Although they resemble the Precambrian forms macroscopically, their microstructure and mineralogical composition differ from those characterizing their purported ancient counterparts. Most Precambrian stromatolites are composed of presumably in situ precipitated carbonates, while their assumed modern marine analogues are predominantly products of accretion of grains trapped and bound by microbial, predominantly cyanobacterial, benthic mats and biofilms and only occasionally by their physicochemical activity. It has therefore been suggested that the carbonate chemistry of early Precambrian seawater differed significantly from modern seawater, and that some present-day quasi-marine or non-marine environments supporting growth of calcareous microbialites reflect the hydrochemical conditions controlling the calcification potential of Precambrian microbes better than modern seawater. Here we report the discovery of a non-marine environment sustaining growth of calcareous cyanobacterial microbialites showing macroscopic and microscopic features resembling closely those described from many Precambrian stromatolites.