Spatial Patterns of Land Use Changes Across a Mediterranean Metropolitan Landscape: Implications for Biodiversity Management

Land use and land cover change (LUCC) is an acknowledged cause of the current biodiversity crisis, but the link between LUCC and biodiversity conservation remains largely unknown at the regional scale, especially due to the traditional lack of consistent biodiversity data. We provide a methodological approach for assessing this link through defining a set of major pressures on biodiversity from LUCC and evaluating their extent, distribution, and association with a set of physical factors. The study was performed in the Metropolitan Region of Barcelona (MRB, NE of Spain) between 1956 and 2000. We generated a LUCC map for the time period, which was reclassified into a set of pressures on biodiversity (forestation, deforestation, crop abandonment, and urbanization). We then explored the association of these pressures with a set of physical factors using redundancy analysis (RDA). Pressures encompassed 38.8 % of the MRB area. Urbanization and forestation were the dominating pressures, followed by crop abandonment and deforestation. RDA showed a significant distribution gradient of these pressures in relation to the studied physical factors: while forestation and deforestation are concentrated in remote mountain areas, urbanization mainly occurs in lowlands and especially on the coast, and close to previous urban centers and roads. Unchanged areas are concentrated in rainy and relatively remote mountain areas. Results also showed a dramatic loss of open habitats and of the traditional land use gradient, both featuring Mediterranean landscapes and extremely important for their biodiversity conservation. Implications of these results for biodiversity management are finally discussed.     

The marine macroalga Cystoseira baccata as biosorbent for cadmium(II) and lead(II) removal: kinetic and equilibrium studies

This work reports kinetic and equilibrium studies of cadmium(II) and lead(II) adsorption by the brown seaweed Cystoseira baccata. Kinetic experiments demonstrated rapid metal uptake. Kinetic data were satisfactorily described by a pseudo-second order chemical sorption process. Temperature change from 15 to 45 degrees C showed small variation on kinetic parameters. Langmuir-Freundlich equation was selected to describe the metal isotherms and the proton binding in acid-base titrations. The maximum metal uptake values were around 0.9 mmol g(-1) (101 and 186 mg g(-1) for cadmium(II) and lead(II), respectively) at pH 4.5 (raw biomass), while the number of weak acid groups were 2.2 mmol g(-1) and their proton binding constant, K(H), 10(3.67) (protonated biomass). FTIR analysis confirmed the participation of carboxyl groups in metal uptake. The metal sorption was found to increase with the solution pH reaching a plateau above pH 4. Calcium and sodium nitrate salts in solution were found to affect considerably the metal biosorption.     

Hydrocarbons in particulate samples from wildfire events in central Portugal in summer 2010

In summer 2010, twenty eight(14 PM_(2.5)samples plus 14 samples PM_(2.5–10)) smoke samples were collected during wildfires that occurred in central Portugal. A portable high-volume sampler was used to perform the sampling, on quartz fibre filters of coarse(PM_(2.5–10)) and fine(PM_(2.5)) smoke samples. The carbonaceous content(elemental and organic carbon) of particulate matter was analysed by a thermal–optical technique. Subsequently, the particulate samples were solvent extracted and fractionated by vacuum flash chromatography into three different classes of organic compounds(aliphatics, polycyclic aromatic hydrocarbons(PAHs) and carbonyl compounds). The organic speciation was performed by gas chromatography–mass spectrometry(GC–MS). Emissions were dominated by the fine particles, which represented around 92% of the PM_(10). A clear predominance of carbonaceous constituents was observed, with organic to elemental carbon(OC/EC)ratios ranging between 1.69 and 245 in both size fractions. The isoprenoid ketone6,10,14-trimethyl-2-pentadecanone, a tracer for secondary organic aerosol formation, was one of the dominant constituents in both fine and coarse particles. Retene was the most abundant compound in all samples. Good correlations were obtained between OC and both aliphatic and PAH compounds. Pyrogenic processes, thermal release of biogenic compounds and secondary processing accounted for 97% of the apportioned PM_(2.5)levels.     

Life cycle assessment of solar photo-Fenton and solar photoelectro-Fenton processes used for the degradation of aqueous α-methylphenylglycine

A comparative Life Cycle Assessment (LCA) of solar photo-Fenton and solar photoelectro-Fenton, two solar-driven advanced oxidation processes (AOPs) devoted to the removal of non-biodegradable pollutants in water, is performed. The study is based on the removal, at laboratory scale, of the amino acid α-methylphenylglycine, a good example of soluble and non-biodegradable target pollutant. The system under study includes chemicals, electricity, transport of all raw materials to the plant site, and the generation of emissions, but it does not take into account the impact of the infrastructure needed to build a hypothetical solar plant. Nine environmental impact categories are included in the LCA: global warming potential, ozone depletion potential, aquatic eutrophication potential, acidification potential, human toxicity potential, photochemical ozone formation potential, fresh water aquatic ecotoxicity potential, marine aquatic ecotoxicity potential, and terrestrial ecotoxicity potential and abiotic resource depletion potential. Although previous experimental results show that both AOPs are able to efficiently degrade the pollutant, the LCA indicates that solar-driven photo-Fenton is the most environmentally friendly alternative, mainly because the use of electricity in solar photoelectro-Fenton experiments involves high environmental impacts.     

A Classification Procedure for Mapping Topo-climatic Conditions for Strategic Vegetation Planning

Environmental classification addresses issues involving the representation and analysis of continuous and variable ecological data. This study creates a methodology to define topo-climatic landscapes (TCL) in the north-west of Catalonia, which is situated in the north-east of the Iberian Peninsula. TCL provide data regarding the ecological behavior of a landscape in terms of its topography, physiognomy, and climate, which are the main drivers of an ecosystem. The variables selected are derived from a variety of different sources, such as remote sensing and climatic atlases. The methodology employed combines unsupervised iterative cluster classification with supervised fuzzy classification. Twenty eight TCL, which can be differentiated in terms of their vegetation physiognomy and vegetation altitudinal range type, were selected for the study area. Furthermore, a hierarchy among the TCL is established which permits the merging of clusters and allows for changes in thematic resolution. By using the topo-climatic landscape map, managers can identify patches with similar environmental conditions and at the same time assess the uncertainty involved in classification.     

Influence of sewage sludge,as a substrate,in the plasticity of functional characteristics of plants

This work aimed to evaluate the effect of sewage sludge application as fertilizer on the plasticity of functional characteristics of species commonly found in the Caatinga. The research was developed in the nursery of the Federal Institute of Education, Science and Technology of Ceará (IFCE), Quixadá campus, located in northeastern Brazil. Three treatments were applied: raw sludge, sanitized sludge, and no manipulation. In each treatment, five species were planted, each with five individuals, totaling 75 individuals, which were tagged, and 4 months after germination, they were destroyed to obtain dry matter content (TMSF) from leaf, stem (TMSC), fine root (TMSRF), and thick root (TMSRG); leaf area; height and diameter of the seedling; and length above and below the ground. The sanitized sludge was responsible for giving higher values for leaf area, height of the seedlings, and diameter and length of stem and root. However, the dry matter content of the fine roots was higher in the treatment without manipulation. At the community level, as TMSRG increased, TMSC also increased, the same occurred between TMSRG and TMSRF, TMSC and TMSRF, and stem length and leaf area. In the treatment without manipulation, there was a positive correlation between leaf area, height and plant diameter, and negative correlation between root length and plant diameter. Thus, it can be concluded that the use of sanitized sludge is a good tool to increase the availability of soil resources, conferring to individuals’ greater dry matter content, greater leaf area, and higher height and diameter above the ground.     

Energy consumption analysis of ABS plastic parts injected in a hybrid injection moulding machine

The energy analysis of injection moulding processes is influenced by complex interactions amongst the moulded part, its material, the injection machine, the process parameters and the environmental conditions. The availability of energy usage analyses that comprehend information on specific materials and machine kind is limited. This paper reports a study that estimates and analyses the power usage profile (PUP), the specific energy consumption (SEC), and the energy distribution at an operation level of two different injected parts made of acrylonitrile-butadiene-styrene and produced in a hybrid injection moulding machine. The methodology followed by the authors incorporates an experiment carried out in an industrial facility. A large sample size, and data-acquisition and data post-processing processes to obtain an accurate PUP and SEC are used. A breakdown of the energy consumed by the injection moulding process of the parts studied at an operation level using Sankey diagrams is discussed. The study results are used to identify strategies to reduce the energy consumed by the processes. The methodology employed, and the strategies reported could be used with other plastic parts regardless of the material and machine used. The results reported are new experimental data useful input for theoretical models.     

Toxicity evaluation of cypermethrin,glyphosate, and malathion,on two indigenous zooplanktonic species

In Aguascalientes, Mexico, there is a special concern about pesticides because of their intensive use on guava production areas, which are located in the vicinity of water reservoirs; thus, non-target organisms could be exposed. Thereafter, the aim of this work was to assess the effect of cypermethrin, Faena® (glyphosate), and malathion, which are the most used pesticides in Aguascalientes’ guava production, on the indigenous freshwater species Alona guttata (cladoceran) and Lecane papuana (rotifer). Acute 48-h toxicity tests were carried out, and LC₅₀ values were calculated. Then, five sublethal concentrations (1/80, 1/40, 1/20, 1/10, and 1/5 of the respective LC₅₀) were selected for the chronic assays: (a) intrinsic growth rate analysis in the rotifer and (b) partial life table analysis in the cladoceran. The results of the acute toxicity tests showed that A. guttata was more sensitive to malathion (LC₅₀ = 5.26 × 10^?3 mg/L) at concentrations found in natural environments with continuous application on guava fields, whereas L. papuana was more sensitive to Faena® (LC₅₀ = 19.89 mg/L). The somatic growth of A. guttata was inhibited for the chronic exposure to cypermethrin. In addition, cypermethrin and Faena® seemed to exert endocrine disruptive effects on A. guttata. Moreover, malathion chronic exposure significantly decreased the survival of A. guttata. Moreover, L. papuana was affected chronically for the three pesticides.     

Evaluation of municipal wastewater treatment plants with different technologies at Las Rozas, Madrid (Spain)

Eight small-scale municipal wastewater treatment plants were evaluated over a period of 19 months in the suburb of Las Rozas in Madrid (Spain). Four plants used compact extended aeration, two used conventional activated sludge, two used conventional extended aeration, one used a rotary biodisc reactor and the other used a peat bed reactor. The best results were obtained from the plants that used conventional technologies and the biodisc. Conventional activated sludge and extended aeration had higher removal efficiencies for ammonia, TSS, COD and BOD(5) and produced good quality final effluents for final disposal in accordance with the discharge standard. Empirical equations that correlated the concentration of dissolved oxygen in the effluents with the efficiencies of TSS, ammonia, COD and BOD(5) removals for all plants evaluated were obtained. The performance of the plants using compact extended aeration was affected more than those using conventional technologies or rotary biodisc when the capacity exceeded that of its initial design.     

Evaluating the urban climate of a typically tropical city of northeastern Brazil

This study attempted to assess a bioclimate index and the occurrence of an urban heat island in the city of Campina Grande, northeastern Brazil, using data taken from mobile measurements and Automatic Weather Stations (AWS). The climate data were obtained during two representative months, one for the dry season (November 2005) and one for the rainy season (June 2006) at seven points in an urban area. Ten-minute air temperatures recorded by an AWS installed in urban areas were compared to those from a similar station located in a suburban area to assess the urban heat island (UHI). The data were collected using a 23X data logger (Campbell Scientific, Inc.) programmed for collecting data every second. The thermal discomfort level was analyzed by Thom’s discomfort index (DI), and an analysis of variance was applied for assessing if there was any statistically significant difference at the 1% and 5% significance level of thermal comfort among points. Mann–Kendall statistical test was used for identifying possibly significant trends in a time series for air temperature, relative humidity, and class A pan evaporation for the city of Campina Grande. The present study found UHI intensities of 1.48°C and ??0.7°C for the months taken as representative of the dry and rainy seasons, respectively. Summer in the city has partially comfortable conditions while the winter is fully comfortable. There are significant changes in DI hourly values between seasons. Only during the rainy season did all points of the city have a comfortable condition until 8:19 h, at which time they become partially comfortable for the rest of the day. Results indicated that there was a 1.5°C increase in air temperature and a 7.2% reduction in relative humidity throughout the analyzed time series. The DI also showed a statistically significant increasing trend (Mann–Kendall test, p?<?0.01) for the dry and rainy seasons and annual period of approximately 1°C in the last 41 years in the city of Campina Grande.