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排序方式: 共有459条查询结果,搜索用时 15 毫秒
161.
Kim K Steuerwald AJ Parsons PJ Fujimoto VY Browne RW Bloom MS 《Journal of environmental monitoring : JEM》2011,13(9):2413-2419
Humans are exposed to concentrations of multiple trace elements through a variety of background sources; many are suspected reproductive toxicants. Prior to investigating associations between trace elements and human reproductive health, potential biomarkers of exposure should be characterized by sources of variability in the population at risk. Factors influencing elemental exposure should also be identified to ensure their consideration as potential confounding variables. The principal aim of this study is to characterize sources of variability for 19 trace elements measured in urine specimens collected from 55 women and 36 male partners completing a 1st cycle of in vitro fertilization (IVF). Urine specimens were analyzed using a biomonitoring method based on inductively coupled plasma-mass spectrometry (ICP-MS). Randomly selected urine specimens (~6%) were analyzed in duplicate, and these data were used to characterize sources of variability. Nine trace elements including As, Ba, Cd, Cs, Co, Cu, Mn, Mo, and Zn, were quantified in most specimens, indicating their utility in future epidemiologic studies of trace elements exposure and IVF outcomes. With few exceptions, normalizing urine using the traditional creatinine-correction procedure, or an alternative approach based on a linear regression model, increased residual variability only slightly. Sex and race appear to be important factors to consider in epidemiologic studies conducted in this population. Urine concentrations for most elements are similar to those reported in the 2005-2006 National Health and Nutrition Examination Survey (NHANES); however, differences in others may indicate regional trends or a unique exposure history for this infertile study population. 相似文献
162.
Peter Bröde Kalev Kuklane Victor Candas Emiel A. Den Hartog Barbara Griefahn Ingvar Holmér 《International journal of occupational safety and ergonomics》2013,19(2):231-244
The heat transferred through protective clothing under long wave radiation compared to a reference condition without radiant stress was determined in thermal manikin experiments. The influence of clothing insulation and reflectivity, and the interaction with wind and wet underclothing were considered. Garments with different outer materials and colours and additionally an aluminised reflective suit were combined with different number and types of dry and pre-wetted underwear layers. Under radiant stress, whole body heat loss decreased, i.e., heat gain occurred compared to the reference. This heat gain increased with radiation intensity, and decreased with air velocity and clothing insulation. Except for the reflective outer layer that showed only minimal heat gain over the whole range of radiation intensities, the influence of the outer garments’ material and colour was small with dry clothing. Wetting the underclothing for simulating sweat accumulation, however, caused differing effects with higher heat gain in less permeable garments. 相似文献
163.
Victor Moutinho Mara Madaleno Joo Paulo Bento 《Environmental and Ecological Statistics》2020,27(2):363-413
Few studies have attempted to study the environmental Kuznets curve (EKC) hypothesis at the individual sector level using more than one sector at once. This paper investigates the existence of the EKC hypothesis in the Iberian countries (Portugal and Spain) using thirteen economic activity sectors for each, analyzing each individual sector’s cointegration and causality relationships considering carbon dioxide (CO2) emissions, sector gross value added and energy consumption. The findings of this paper using the autoregressive distributed lag (ARDL) approach only validate cointegration in six Portuguese sectors and in five of the Spanish sectors. Results confirm both short- and long-run bi-directional and unidirectional causality between economic growth, energy consumption and CO2 emissions, using the error correction model (ECM) and Toda and Yamamoto’s causality approaches. Moreover, results for Portuguese and Spanish sectors indicate an inverted U-shaped relationship only for one sector each. In some sectors there was evidence of a U-shaped relationship and in others the EKC hypothesis could be verified but no statistical significance was obtained. The study has significant contributions for sector policy, including implications to curtail energy pollutants by implementing environmental friendly regulations to sustain economic development at the sector level in the Iberian market. It also allows inferences to be made about the existence of different behaviors in comparative terms for the same economic activity sectors of the individual countries. 相似文献
164.
Mohamad Sleiman Hugo Destaillats Jared D. Smith Chen-Lin Liu Musahid Ahmed Kevin R. Wilson Lara A. Gundel 《Atmospheric environment (Oxford, England : 1994)》2010,44(34):4191-4198
We used controlled laboratory experiments to evaluate the aerosol-forming potential of ozone reactions with nicotine and secondhand smoke. Special attention was devoted to real-time monitoring of the particle size distribution and chemical composition of SOA as they are believed to be key factors determining the toxicity of SOA. The experimental approach was based on using a vacuum ultraviolet photon ionization time-of-flight aerosol mass spectrometer (VUV-AMS), a scanning mobility particle sizer (SMPS) and off-line thermal desorption coupled to mass spectrometry (TD-GC-MS) for gas-phase byproducts analysis. Results showed that exposure of SHS to ozone induced the formation of ultrafine particles (<100 nm) that contained high molecular weight nitrogenated species (m/z 400–500), which can be due to accretion/acid–base reactions and formation of oligomers. In addition, nicotine was found to contribute significantly (with yields 4–9%) to the formation of secondary organic aerosol through reaction with ozone. The main constituents of the resulting SOA were tentatively identified and a reaction mechanism was proposed to elucidate their formation. These findings identify a new component of thirdhand smoke that is associated with the formation of ultrafine particles (UFP) through oxidative aging of secondhand smoke. The significance of this chemistry for indoor exposure and health effects is highlighted. 相似文献
165.
Victor Vilarrasa Diogo Bolster Sebastia Olivella Jesus Carrera 《International Journal of Greenhouse Gas Control》2010,4(6):910-919
Sequestration of carbon dioxide (CO2) in deep saline aquifers has emerged as an option for reducing greenhouse gas emissions to the atmosphere. The large amounts of supercritical CO2 that need to be injected into deep saline aquifers may cause large fluid pressure increases. The resulting overpressure may promote reactivation of sealed fractures or the creation of new ones in the caprock seal. This could lead to escape routes for CO2. In order to assess the probability of such an event, we model an axisymmetric horizontal aquifer–caprock system, including hydromechanical coupling. We study the failure mechanisms, using a viscoplastic approach. Simulations illustrate that, depending on boundary conditions, the least favorable moment takes place at the beginning of injection. Initially, fluid pressure rises sharply because of a reduction in permeability due to desaturation. Once CO2 fills the pores in the vicinity of the injection well and a capillary fringe is fully developed, the less viscous CO2 displaces the brine and the capillary fringe laterally. The overpressure caused by the permeability reduction within the capillary fringe due to desaturation decreases with distance from the injection well. This results in a drop in fluid pressure buildup with time, which leads to a safer situation. Nevertheless, in the presence of low-permeability boundaries, fluid pressure continues to rise in the whole aquifer. This occurs when the radius of influence of the injection reaches the outer boundary. Thus, caprock integrity might be compromised in the long term. 相似文献
166.
In this study, an analytical method was optimized for the determination of bisphenol-A (BPA), triclosan (TCS) and 4-n-nonylphenol (4n-NP), environmental contaminants with potential endocrine disruptive activities, in human tissues. The method consisted of a liquid extraction step, derivatization with pentafluorobenzoylchloride followed by a clean-up on acidified silica and detection with gas chromatography coupled with mass spectrometry (GC-ECNI/MS). Recoveries ranged between 92% and 102% with a precision below 5%. Limits of quantification ranged between 0.3-0.4 ng g−1, 0.045-0.06 ng g−1 and 0.003-0.004 ng g−1 for BPA, TCS and 4n-NP in different tissues, respectively. The method was applied for the determination of BPA, TCS and 4n-NP in paired adipose tissue, liver and brain samples from 11 individuals. BPA could be detected in almost all tissues, with the highest concentrations found in adipose tissue (mean 3.78 ng g−1), followed by liver (1.48 ng g−1) and brain (0.91 ng g−1). TCS showed the highest concentrations in liver (3.14 ng g−1), followed by adipose tissue (0.61 ng g−1), while it could be detected in only one brain sample. Levels of 4n-NP were much lower, mostly undetected, and therefore 4n-NP is considered of minor importance for human exposure. Despite the measurable concentrations in adipose tissue, these compounds seem to have a low bioaccumulation potential. The reported concentrations of free BPA in the various tissues are slight disagreement with pharmacokinetic models in humans and rats and therefore the possibility of external contamination with BPA during sample collection/storage cannot be ruled out. 相似文献
167.
Between 2000 and 2007 pooled muscle tissue samples of the European eel (Anguilla anguilla) from 48 sites in Flanders (Belgium) were analysed for 30 polychlorinated biphenyl (PCB) congeners. There was a large variation between individual sites (range 11-7752 ng/g wet weight (ww) for the sum of the ICES 7 PCBs), eels from the River Meuse basin (mean 1545 ng/g ww) being considerably more polluted than those from the River Scheldt (615) and IJzer (61) basins. Overall, PCB 153, PCB 138 and PCB 180 were the most prominent congeners, however PCB patterns varied between the monitored locations. Analysis of the weight percentage of congeners demonstrates obvious differences in PCB composition between sites, indicating differential sources of pollution. Due to the variation in patterns, atmospheric fallout does not seem to be the main source of the PCB spread, but instead both local and upstream sources linked to industrial activities seem to be the main cause for PCB presence in Flanders. Considering the levels of the Sum 7 PCBs, eels are not compliant with the Belgian legal limits for consumption (75 ng/g ww) in 71% of the sites. Regular consumption of eels from polluted sites leads to a considerable excess of the WHO Acceptable Daily Intake value. Consumption of wild eels should by all means be prevented, as it presents risks for human health, especially for local anglers consuming their catch. 相似文献
168.
Yadav Uprety Ram C. Poudel Hugo Asselin Emmanuel Boon 《Environment, Development and Sustainability》2011,13(3):463-492
A survey of plant biodiversity and ethnobotany was conducted along the Seti river banks in the Tanahun district of Western
Nepal. This area, home of the Magar ethnic group, will be impacted by a major hydropower project, currently under feasibility study. The objective of the study
was to document plant biodiversity and ethnobotany in order to suggest appropriate conservation and management strategies.
Botanical sampling was conducted inside quadrats and along transects. A total of 221 plant species were recorded in the study
area, distributed as herbs (80 species), trees (68), shrubs (28), climbers (19), pteridophytes (18), lianas (5), and epiphytes
(3). Twelve of the inventoried species figure in one or more conservation categories identified by various national or international
agencies. Group discussions and personal interviews allowed to find out that 43% of the species were ethnobotanically important
for the local people and that most were used as medicine, food, or timber. We propose specific species for sustainable use
programs based on certain criteria. The area is very important in terms of plant biodiversity and ethnobotany, and hence,
immediate implementation of conservation measures is recommended to maintain the high social, ecological and economic values
of the area. 相似文献
169.
Spatial and temporal drivers of zoonotic pathogen contamination of an agricultural watershed 总被引:1,自引:0,他引:1
Jokinen CC Edge TA Koning W Laing CR Lapen DR Miller J Mutschall S Scott A Taboada EN Thomas JE Topp E Wilkes G Gannon VP 《Journal of environmental quality》2012,41(1):242-252
In regions where animal agriculture is prominent, such as southern Alberta, higher rates of gastrointestinal illness have been reported when compared with nonagricultural regions. This difference in the rate of illness is thought to be a result of increased zoonotic pathogen exposure through environmental sources such as water. In this study, temporal and spatial factors associated with bacterial pathogen contamination of the Oldman River, which transverses this region, were analyzed using classification and regression tree analysis. Significantly higher levels of fecal indicators; more frequent isolations of Campylobacter spp., Escherichia coli O157:H7, and Salmonella enterica spp.; and higher rates of detection of pig-specific Bacteroides markers occurred at downstream sites than at upstream sites, suggesting additive stream inputs. Fecal indicator densities were also significantly higher when any one of these three bacterial pathogens was present and where there were higher total animal manure units; however, occasionally pathogens were present when fecal indicator levels were low or undetectable. Overall, Salmonella spp., Campylobacter spp., and E. coli O157:H7 presence was associated with season, animal manure units, and total rainfall on the day of sampling and 3 d in advance of sampling. Several of the environmental variables analyzed in this study appear to influence pathogen prevalence and therefore may be useful in predicting water quality and safety and in the improvement of watershed management practices in this and other agricultural regions. 相似文献
170.
Victor C. Searle 《Journal of the Air & Waste Management Association (1995)》2013,63(3):137-141
In common with other technical fields and disciplines, the air pollution area has “information explosion” problems, compounded by the interdisciplinary nature of the field and the current increased emphasis on air pollution and its control. The development of technical information programs to meet these needs is traced, with emphasis on the Air Pollution Technical Infor-mation Center established by the National Air Pollution Control Administration of the Department of Health, Education, and Welfare. The Center is based on a delegation of responsibility by the Office of Science and Technology, Executive Office of the President, and now contains over 12,000 current references, with an acquisition rate of approximately 200 per month. In addition to the U. S. journal literature, particular emphasis is placed on the foreign literature and on U. S. Government research reports. Other programs discussed include the Air Pollution Control Association, Bay Area Air Pollution Control District, Center for Air Environment Studies at Penn State, and centers serving particular industries. Services available from each are described. 相似文献