Beach vulnerability assessment of a protected area of the Northern Campania coast (Southern Italy)

A detailed and multidisciplinary study of physical and biotic factors of a coastal sector of southern Italy, the Pineta della foce del Garigliano SCI (Site of Community Importance) area, has been carried out in the frame of the European research project LIFE + Nature & Biodiversity PROVIDUNE. We evaluated the degree of dunes vulnerability (Dune Vulnerability Index, DVI) and sustainable anthropogenic load (carrying capacity) of the emerged beach of the study area, which is largely affected by shoreline retreat and degradation of dune habitat. The values of about 0.6 of the DVI in the two key sectors of the study area suggest a high level of vulnerability of beach/dune system due to both natural and human factors. The partial vulnerability index related to the geomorphological condition exhibits the highest values, as a consequence of a coastal system largely affected by recent and present-day beach erosion and severe hydrodynamics processes. Several inadequate human practises have been recognized in the study area whose impact appears to be an important factor in controlling the reduction of the beach-dune system resilience. Integrated analysis of DVI and carrying capacity suggests that the northern and central sectors of the study area have a high level of dune vulnerability due to hydrodynamic and geomorphological factors whereas the human impact can be considered relatively less important. The southern sector of the study area is featured by a well-developed infrastructure system, which is able to assure a sustainable beach occupation. Nevertheless, significant interventions such as dune replacement by permanent or ephemeral infrastructures, uncontrolled pedestrian or vehicular access and inappropriate use of mechanical beach cleaning have been recognized in this sector of the beach. These long-lasting impacts have promoted the dismantling of large sector of the dune habitats. Obtained results allowed identifying the critical area where appropriate actions can be performed for the mitigation of impacts, the conservation of dune habitats and their sustainable use.     

Fungitoxicity of lyophilized and spray-dried garlic extracts

Among the compounds discussed for anti-microbial and anti-fungal use allicin (allylthiosulfinate, diallyl disulfide-S-monoxide), an active ingredient of garlic, has attracted considerable attention. The objective of this study is to determine the antifungal activity of a local garlic ecotype (Voghiera) extracts against different pathogens. Primary screening was carried out by the agar plates technique using ethanol garlic extract at four final concentrations against the following organisms: Alternaria alternata, Aspergillus spp., Colletotrichum acutatum, Didymella bryoniae, Fusarium culmorum, Fusarium avenaceum, Fusarium gramineareum, Gliocladium roseum 47, Pythium splendens, Rhizoctonia solani, Sclerotium rolfsii, Stemphylium vesicarium, Trichoderma longibranchiatum, and Botrytis cinerea. Secondary screening was carried out using a lyophilized and a spray-dried preparation at different concentrations against the organisms selected for the high inhibition garlic effect in the primary screening and compared with the commercial fungicides mancozeb and iprodione. The best results were observed for the spray-dried garlic compound that showed a good fungicidal activity at the concentration of 1.5 g/10 mL while lyophilized garlic at the same concentration exhibited less inhibition activity against the four fungi analyzed in the second screening.     

Organochlorine pesticides and polychlorinated biphenyls in common buzzard (<Emphasis Type="Italic">Buteo buteo</Emphasis>) from Sicily (Italy)

In the present study, we investigated the concentrations and distribution of organochlorine pesticides (OCs) and polychlorinated biphenyls (PCBs) in intestine, liver, and muscle samples of 11 common buzzards (Buteo buteo) from Sicily used as bioindicator for monitoring pollution in environment. All samples of common buzzards were collected at the “Recovery Center of Wild Fauna” of Palermo, through the Zooprophilactic Institute. Quantitative determination of OCs and PCBs in the samples examined has been carried out using HRGC-ECD and GC-MS. The results obtained show the presence of concentrations of ∑DDT and ∑PCB in almost all samples. Regarding ∑DDT (4,4^′-DDE, 2,4^′-DDD, 4,4^′-DDD, 2,4^′-DDT, and 4,4^′-DDT), the highest concentrations were found in intestine (0.411 ± 0.050 μg/g) followed by muscle (0.130 ± 0.017 μg/g) and liver samples (0.109 ± 0.014 μg/g). As regards the ∑PCB congeners (PCB-28, PCB-52, PCB-95, PCB-99, PCB-101, PCB-110, PCB-138, PCB-146, PCB-149, PCB-151, PCB-153, PCB-170, PCB-177, PCB-180, PCB-183, and PCB-187), the highest concentrations were found in intestine (1.686 ± 0.144 μg/g) followed by liver (1.064 ± 0.162 μg/g) and muscle samples (0.797 ± 0.078 μg/g). Our data deserve particular attention not only for their significance but especially because they were recorded in Sicily, a region with a very low risk of environmental pollution due to the shortage of industries.     

Numerical simulation of water mixing and renewals in the Barcelona harbour area: the winter season

In the present paper, we use numerical simulation to investigate currents, mixing and water renewal in Barcelona harbour under typical conditions of wind forcing for the winter season. This site is of particular importance due to the interplay between touristic and commercial activities, requiring detailed and high-definition studies of water quality within the harbour. We use Large Eddy Simulation (LES) which directly resolves the anisotropic and energetic large scales of motion and parametrizes the small, dissipative, ones. Small-scale turbulence is modelled by the anisotropic Smagorinsky model (ASM) to be employed in presence of large cell anisotropy. The complexity of the harbour is modelled using a combination of curvilinear, structured, non-staggered grid and the immersed boundary method. Boundary conditions for wind and currents at the inlets of the port are obtained from in-situ measurements. Analysis of the numerical results is carried out based on both instantaneous and time-averaged velocity fields. First- and second-order statistics, such as turbulent kinetic energy and horizontal and vertical eddy viscosities, are calculated and their spatial distribution is discussed. The study shows the presence of intense current in the narrow and elongated part of the harbour together with sub-surface along-shore elongated rolling structures (with a time scale of a few hours), and they contribute to the vertical water mixing. Time-averaged velocity field reveals intense upwelling and downwelling zones along the walls of the harbour. The analysis of second-order statistics shows strong inhomogeneity of turbulent kinetic energy and horizontal and vertical eddy viscosities in the horizontal plane, with larger values in the regions characterized by stronger currents. The water renewal within the port is quantified for particular sub-domain regions, showing that the complexity of the harbour is such that certain in-harbour basins have a water renewal of over five days, including the yacht marina area. The LES solution compares favourably with available current-meter data. The LES solution is also compared with a RANS solution obtained in literature for the same site under the same forcing conditions, the comparison demonstrating a large sensitivity of properties to model resolution and frictional parametrization.     

Air quality biomonitoring through pollen viability of Fabaceae

In this study, pollen viability and germination of three plant species, Cercis siliquastrum L., Robinia pseudoacacia L., and Spartium junceum L., belonging to the Fabaceae family, was evaluated in sites with different intensity of road traffic, constantly monitored with continuous analysers for air pollutants (carbon monoxide (CO), sulphur dioxide (SO₂), and nitrogen dioxide (NO₂)) by the Municipality of Catania. Two sites, in which road traffic was absent, were selected, too. The percentages of viable pollen by 2,3,5-trypheniltetrazolium chloride (TTC) test ranged from 59.0 to 90.2 % in C. siliquastrum, from 61.5 to 83.5 % in S. junceum and from 67.5 to 84.3 % in R. pseudoacacia. The percentages of germination varied from 41.0 to 72.7 % in C. siliquastrum, from 42.0 to 64.7 % in S. junceum and from 38.3 to 66.3 % in R. pseudoacacia. The highest percentages of viable pollens were found in no-road traffic stations by either TTC or germination tests, while the lowest values were detected in a site characterised by heavy road traffic. In the monitored period (2007–2009), pollen viability, germinability and tube length of C. siliquastrum resulted in a significant negative correlation to CO, SO₂ and NO₂, whereas data from TTC and germination tests on S. junceum and R. pseudoacacia pollens were not well correlated to air pollutants. The results showed that pollen viability, germination and tube growth in C. siliquastrum were affected by air pollution. S. junceum and R. pseudoacacia were not very influenced by air pollutants, suggesting a different pollen sensitivity of these species.     

Voltammetric and Spectroscopic Determination of Toxic Metals in Sediments and Sea Water of Salerno Gulf

In this present work the distribution of heavy metals in sea water and sediments of the Salerno Gulf is measured. The elements determined were Cu, Pb, Cd, Zn and Hg, employing, as instrumental techniques, either differential pulse anodic stripping voltammetry (DPASV) or graphite furnace atomic absorption spectroscopy (GFAAS). A comparison of the results of the two analytical techniques is also made. Mercury determination was carried out employing the cold vapour atomic absorption spectroscopy (CVAAS) technique, with SnCl₂ as the reducing agent. The sample digestion was performed by a new procedure using concentrated suprapure H₂SO₄–K₂Cr₂O₇ mixture. The accuracy and precision of the analytical procedure were evaluated employing Sea Water BCR-CRM 403 and Estuarine Sediment BCR-CRM 277 as reference materials. Accuracy, expressed as relative error e and precision, expressed as relative standard deviation s_r, were in order of 2 to 5%. For both matrices, the detection limits, for all the elements, were in the range g g_-1 to ng g_-1.