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991.
Caio F. Gromboni George L. Donati Wladiana O. Matos Eduardo F. A. Neves Ana Rita A. Nogueira Joaquim A. Nóbrega 《Environmental Chemistry Letters》2010,8(1):73-77
Efficiency of metabisulfite and a commercial steel wool as reducing agents in the removal of Cr(VI) from wastewaters was evaluated.
Chromium(VI) was converted to Cr(III), precipitated with NaOH, and removed by filtration. A reduction of more than 1.0 × 105 and 4.0 × 105 fold in total Cr and the Cr(VI) concentrations, respectively, was observed by employing steel wool masses as low as 0.4420 g
to 30-mL solutions of wastewater. Chromium(III) hydroxide obtained after the treatment was recycled and used as marker in
cattle nutrition studies. The liquid residue obtained after the treatment was reused as precipitation agent replacing NaOH. 相似文献
992.
A surfactant mediated cloud point extraction (CPE) procedure has been developed to remove color from wastewater containing
malachite green using Triton X-100 as non-ionic surfactant. The effects of the concentration of the surfactant, temperature
and salt concentration on the different concentrations of dye have been studied and optimum conditions were obtained for the
removal of malachite green. The concentration of malachite green in the dilute phase was measured using UV–Vis spectrophotometer.
It was found that the separation of phases was complete and the recovery of malachite green was very effective in the presence
of NaCl as an electrolyte. The results showed that up to 500 ppm of malachite green can quantitatively be removed (>95%) by
CPE procedure in a single extraction using optimum conditions. 相似文献
993.
Davide Vione Daniele Bagnus Valter Maurino Claudio Minero 《Environmental Chemistry Letters》2010,8(2):193-198
We measured the formation rate and the steady-state concentration of hydroxyl radicals and of singlet oxygen upon irradiation
of lake water. There is controversy about the importance of singlet oxygen in the environmental photochemistry, but here we
show that the steady-state concentration of 1O2 under irradiation can be higher by about two orders of magnitude compared to the hydroxyl radical. The higher occurrence
of singlet oxygen in surface waters is mainly due to a higher rate of formation, because the transformation rate constants
of 1O2 (collision with the solvent) and of ·OH (reaction with dissolved compounds) are comparable. 相似文献
994.
We studied the removal mechanism and affecting factors of Fe2+-based replacement–precipitation process for treating CuEDTA-containing wastewaters. Since Fe2+ was easily oxidized to Fe3+ in the presence of oxygen, the chelated copper was removed by the synergetic effect of Fe3+ replacement and NaOH precipitation. Our experiments showed that the copper removal efficiency was considerably dependant
on pH conditions of the solution and molar ratio of Fe2+/Cu2+. 相似文献
995.
Alžbeta Jarošová Jiří Harazim Lenka Krátká Doubravka Kolenčíková 《Environmental Chemistry Letters》2010,8(4):387-391
Phthalates are animal carcinogens and may cause death or tissue deformities. Samples of feedstuffs collected in 2005 and 2006
from industrial feed manufacturers in the Czech Republic were analysed for contamination with phthalic acid esters (PAEs),
specifically di-2-ethylhexyl phthalate (DEHP) and di-n-butyl phthalate (DBP). Samples of feed additives, premixes and raw materials were collected (year 2005, n = 26). For soybean oil, the total volume of phthalates measured (DBP + DEHP) reached a level of 131.42 mg kg−1; for rapeseed oil, fish meal and animal fats, the levels measured were 15.00, 7.96 and 58.87 mg kg−1, respectively. The lowest level of DBP + DEHP was found in corn (2.03 mg kg−1). Since phthalates were detected, samples of feed additives (n = 28) and raw materials (n = 28) were collected again in 2006. The highest levels of DBP + DEHP were found in raw materials containing fat. Phthalate
levels in rapeseed oil samples ranged from 1.38 to 32.40 mg kg−1 DBP + DEHP. For feed additives, contamination levels in vitamins and amino acids ranged from 0.06 to 3.15 and 1.76 to 4.52 mg kg−1 DBP + DEHP, respectively. Here, we show that the levels of PAEs found in cereals such as wheat, barley and corn may be regarded
as being alarmingly high, because cereals make up the largest proportion of compound feed of farm animals. 相似文献
996.
Marco Ghisalberti 《Environmental Fluid Mechanics》2010,10(3):329-343
Obstructed shear flows (i.e. those over permeable media) are common in the environment. An archetypal example, flow over a
submerged vegetation canopy, is investigated here. Like any flow through complex geometry, canopy flows are characterised
by strong spatial gradients. The focus of this experimental study is the three-dimensionality of aquatic canopy flow, in particular
that of the coherent interfacial vortices that govern mixing into and out of the canopy. It is shown here that the vortices
have a finite lateral scale that is comparable to their vertical scale; both are of the order of the drag length scale of
the canopy, (C
D
a)−1, where a is the frontal area density and C
D
is a bulk drag coefficient. The finite lateral extent of the vortices generates strong lateral hydrodynamic gradients, both
instantaneously and in the long-term. The instantaneous gradients, which can contribute greatly to the dispersion of dissolved
and particulate species, are far more pronounced. Finally, the potential for canopies to generate differential roughness secondary
circulation is examined. In the consideration of vertical scalar transport, this circulation can be of the same order as turbulent
diffusion. 相似文献
997.
Suspended particulate matter dynamics in a particle framework 总被引:1,自引:0,他引:1
Suspended particulate matter (SPM) dynamics in ocean models are usually treated with an advection–diffusion equation for one or more sediment size classes coupled to the hydrodynamical part of the model. Numerical solution of these additional partial differential equations unavoidably introduces numerical diffusion, i.e. in the case of sharp gradients the possible occurrence of artificial oscillations and non-positivity. A Lagrangian particle-tracking model has been developed to simulate short-term SPM dynamics. Modelling individual sediment particles allows a straightforward physical interpretation of the processes. The tracking of large numbers of individual and independent particles (up to 25 million in total in a single sediment class) can be achieved on high performance computer clusters, due to efficient parallelisation of particle tracking. The movement of the particles is described by a stochastic differential equation, which is consistent with the advection–diffusion equation. Here, the concentration profile is represented by a set of independent moving particles, which are advected according to the 3D velocity field, while the diffusive displacements of the particles are sampled from a random distribution, which is related to the eddy diffusivity field. To account for erosion a new parameterisation is proposed. Three numerical particle tracking schemes (EULER, MILSTEIN and HEUN) are presented and validated in idealised test cases. Finally, the particle tracking algorithms are applied to a realistic scenario, a severe winter storm in the East Frisian Wadden Sea (southern North Sea). The comparison with observations and an Eulerian SPM transport model seems to indicate a somewhat better fidelity of the Lagrangian approach. 相似文献
998.
Photo-polymerization of triclosan in aqueous solution induced by ultraviolet radiation 总被引:1,自引:0,他引:1
The formation of 2,8-dichlorodibenzo-p-dioxin and other harmful degradation products in the photo-degradation process of triclosan is of increasing concern. Here we worked on the identification of polymerized products at high triclosan concentration and on the mechanism of photoreaction. Five dimmers and two trimers of triclosan were detected by liquid chromatography-mass spectrum analysis. 2,8-dichlorodibenzo-p-dioxin was also identified by comparing with an authentic standard. Relatively low pH and high concentration favored the polymerization of triclosan. Three main routes of photoreaction were postulated, namely dechlorination, ring closure and polymerization. 相似文献
999.
This study is to develop a carbon-based adsorbent containing multiple functional ligands for effective removal of lead ions
from aqueous media. Activated carbon was oxidized by nitric acid, followed by chlorination with thionyl chloride and reaction
with ethylenediamine. Modified activated carbon (MAC) was characterized using scanning electron microscopy in conjunction
of energy dispersive spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FT-IR), and potentiometric titration.
Surface characterizations confirmed that carboxyl, amine, and chlorine functional groups were effectively introduced onto
the carbon surface by the treatments. The modifications lowered the pH at the point of zero charge (pHpzc) from 9.6 to 2.55 and resulted in more negatively charged surfaces. Adsorptive experiments showed that aqueous Pb removal
by MAC was faster, with a 62% higher capacity than the original activated carbon (60.2 vs. 37.2 mg g−1). 相似文献
1000.
Jun Bi Yongliang Zhang Bing Zhang 《Frontiers of Environmental Science & Engineering》2010,4(3):361-372
In developing countries, there is controversy over the correct perception regarding environmental and developmental issues. Few studies have examined the perception of low-income nationals in regards to social and environmental issues. This paper looks at the relationship between socio-demographic factors and the groups’ perceived priority regarding environmental and social issues in Wujin County. The results indicated that most residents, specifically the young, government employed and the urban community consider environmental issues to be serious, especially in relation to air pollution and water pollution. Furthermore, many residents feel it is important to rank environmental problems that are related to other social and economic issues, and that environmental protection must be set as a priority in Wujin County. Compared to social issues, environmental concern was greater among the young, government employed, and the urban community, because of their higher education and affluence. In addition, 66.2% of residents consider environmental protection to be more important than economic development. Thus, environmental protection must be set as a high priority in Wujin County, in order to face the many social and environmental challenges inherent in development. 相似文献