农业灌溉水的污染控制——一种跨学科的方法

为控制农业灌溉水的污染而采用统一水质标准问题已受到国家水质管理机构的重视,到目前为止,大量测试的结果启示人们要使用水质标准和监测方法,当然重点仍然放在选择和使用适于在特定地区、特定气候、土壤、地形和耕作方法等具体条件下的“最佳管理方法”上。     

金伯利岩及有关岩石放射性测定年龄方法总结

金伯利岩及有关岩石组成的多样性,排除了应用单一年龄测定方法来确定所有岩石年龄的可能性。此外,许多这类岩石的蚀变性质(尤其是出露地表的部分)缩小了某些测年方法的可用性。由于具有特征同住素组成的污染物的存在,火山道相(与浅成相相对)金伯利岩年龄很难确定,甚至不可能测定。尽管存在这些问题,但多种放射性年龄测量方法,包括云母Rb-Sr法、全岩和云母的K-Ar法和Ar-Ar分步加热法、U-Pb锆石和钙钛矿法以及裂变径迹法,都证明是有效的。其他方法,如Rb-Sr、U-Pb或Pb-Pb全岩法或Rb-Sr单斜辉石法没有这么有效,但对某些经过仔细选择过的样品也能产生合理的结果。利用离子探针分析对单个锆石、钙钛矿,可能还有磷灰石颗粒进行U-Pb年龄测定有可能是极端有效的。 应用各种放射性测量方法,测定南部非洲金伯利岩及有关岩石的年龄,表明其就位的地质年代跨度范围很大,已知地质事件的年龄为50—1700Ma。测过年龄的大多数产地的金伯利岩及有关岩石为侏罗纪和白垩纪,不过有几次金伯利岩岩浆作用也发生在约500、1200和1600Ma。     

Land Use/Cover Changes, the Environment and Water Resources in Northeast China

Land use/cover in Northeast China went through extensive changes during the 1990s. This report explores the interaction between these changes and the environment, and the implication of these changes for rational allocation of water resources. Two maps of land use/cover produced from 1990 and 2000 Landsat TM satellite images were overlaid in ArcInfo to reveal changes in land cover. Results indicate that farmland and grassland decreased by 386,195 and 140,075 ha, respectively, while water, built-up areas, and woodland increased by 238,596, 194,231, and 192,682 ha, respectively. These changes bore a mutual relationship with the environmental change. On the one hand, climate warming made some of these changes (e.g., conversion of woodland and grassland to farmland) possible. On the other hand, the changed surface cover modified the local climate. These changes, in turn, caused severe environmental degradation and increased flooding. The change between dry field and rice paddy, in particular, raised severe implications for the proper allocation of limited water resources in the Northeast. Efforts are needed to coordinate their rational allocation to reap maximum and sustainable return over the entire area, not just in some localities. Results obtained in this study should be of interest to the international audience of Environmental Management in that they highlight the interactive nature of human activities and the environment and the off-site impact of these activities on the environment.     

The European Water Framework Directive: Water Quality Classification and Implications to Engineering Planning

The European Water framework directive (WFD) is probably the most important environmental management directive that has been enacted over the last decade in the European Union. The directive aims at achieving an overall good ecological status in all European water bodies. In this article, we discuss the implementation steps of the WFD and their implications for environmental engineering practice while focusing on rivers as the main receiving waters. Arising challenges for engineers and scientists are seen in the quantitative assessment of water quality, where standardized systems are needed to estimate the biological status. This is equally of concern in engineering planning, where the prediction of ecological impacts is required. Studies dealing with both classification and prediction of the ecological water quality are reviewed. Further, the combined emission–water quality approach is discussed. Common understanding of this combined approach is to apply the most stringent of either water quality or emission standard to a certain case. In contrast, for example, the Austrian water act enables the application of only the water quality based approach - at least on a temporary basis.     

Development of a New Approach to Cumulative Effects Assessment: A Northern River Ecosystem Example

If sustainable development of Canadian waters is to be achieved, a realistic and manageable framework is required for assessing cumulative effects. The objective of this paper is to describe an approach for aquatic cumulative effects assessment that was developed under the Northern Rivers Ecosystem Initiative. The approach is based on a review of existing monitoring practices in Canada and the presence of existing thresholds for aquatic ecosystem health assessments. It suggests that a sustainable framework is possible for cumulative effects assessment of Canadian waters that would result in integration of national indicators of aquatic health, integration of national initiatives (e.g., water quality index, environmental effects monitoring), and provide an avenue where long-term monitoring programs could be integrated with baseline and follow-up monitoring conducted under the environmental assessment process.     

An ultra-clean firn core from the Devon Island Ice Cap, Nunavut, Canada, retrieved using a titanium drill specially designed for trace element studies

An electromechanical drill with titanium barrels was used to recover a 63.7 m long firn core from Devon Island Ice Cap, Nunavut, Canada, representing 155 years of precipitation. The core was processed and analysed at the Geological Survey of Canada by following strict clean procedures for measurements of Pb and Cd at concentrations at or below the pg g(-1) level. This paper describes the effectiveness of the titanium drill with respect to contamination during ice core retrieval and evaluates sample-processing procedures in laboratories. The results demonstrate that: (1) ice cores retrieved with this titanium drill are of excellent quality with metal contamination one to four orders of magnitude less than those retrieved with conventional drills; (2) the core cleaning and sampling protocols used were effective, contamination-free, and adequate for analysis of the metals (Pb and Cd) at low pg g(-1) levels; and (3) results from 489 firn core samples analysed in this study are comparable with published data from other sites in the Arctic, Greenland and the Antarctic.     

Potential Use of the Plant Antioxidant Network For Environmental Exposure Assessment of Heavy Metals in Soils

In recent years, awareness has risen that the total soil content of pollutants by itself does not suffice to fully assess the potential ecotoxicological risks involved. Chemical analysis will require to be complemented with biological assays in a multidisciplinary approach towards site specific ecological risk assessment (SS-ERA). This paper evaluates the potential use of the plants' antioxidant response to metal-induced oxidative stress to provide a sensitive biological assay in SS-ERA. To this end, plants of Phaseolus vulgaris were grown for two weeks on 15 soils varying in contamination level. Morphological parameters and enzymatic plant responses were measured upon harvest. Foliar concentrations of the (heavy) metals Al, Cu, Cd, Cr, Fe, Mn, Ni, Pb, Zn were also determined. Metal mobility in the soil was further assessed by determining soil solution and NH₄OAc extractable levels. In general more significant correlations were observed between plant responses and foliar metal concentrations or exchangeable/soluble levels than between plant responses and the total soil content. The study demonstrates the potential use of the plants' antioxidant defence mechanisms to assess substrate phytotoxicity for application in SS-ERA protocols. However, the system, based on calculation of a soil Phytotoxicity Index (PI), will require adaptation and fine-tuning to meet the specific needs for this type of environmental monitoring. Large variation was observed in phytotoxicity classification based on the various test parameters. The thresholds for classification of the various morphological and enzymatic response parameters may require adaptation according to parameter stress sensitivity in order to decrease the observed variation. The use of partial PI's (leaves and roots separately) may in addition increase the sensitivity of the system since some metals show specific effects in one of both organs only. Loss of biological functionality of enzymes, as was observed for ICDH in one of the more strongly contaminated soils, may also be recognized as an additional stress symptom when assigning phytotoxicity classification, whereas the current system only considers increasing enzymatic capacities. Other easily distinguishable parameters, which could be added to the current indexation are: failure to germinate and the incapacity to develop roots in the toxic substrate.Additional research will be required to determine the possible application range of soil properties for this biological assay and to further improve its performance in SS-ERA.     

Polycyclic aromatic hydrocarbon (PAH) contamination of surface sediments and oysters from the inter-tidal areas of Dar es Salaam, Tanzania

Surface sediment and oyster samples from the inter-tidal areas of Dar es Salaam were analyzed for 23 polycyclic aromatic hydrocarbons (PAHs) including the 16 compounds prioritized by US-EPA using GC/MS. The total concentration of PAHs in the sediment ranged from 78 to 25,000 ng/g dry weight, while oyster concentrations ranged from 170 to 650 ng/g dry weight. Hazards due to sediment contamination were assessed using Equilibrium Partitioning Sediment Benchmarks and Threshold Effect Levels. Diagnostic indices and principle component analysis were used to identify possible sources. Interestingly, no correlation between sediment and oyster concentrations at the same sites was found. This is supported by completely different contamination patterns, suggesting different sources for both matrices. Hazard assessment revealed possible effects at six out of eight sites on the benthic communities and oyster populations. The contribution of PAH intake via oyster consumption to carcinogenic risks in humans seems to be low.     

The relation between the estimated dietary intake of PCDD/Fs and levels in blood in a Flemish population (50-65 years)

Dioxin-like activity was measured in the serum of 1425 Flemish men and women via the CALUX assay. The adults, aged between 50 and 65 years, participated in a large biomonitoring program, executed by the Flemish Center of Expertise for Environment and Health between 2002 and 2006. Within the context of this biomonitoring program also dietary intake of dioxin-like contaminants was assessed through a food frequency questionnaire. The relation between the estimated dietary intake and the dioxin-like activity in serum was evaluated using multivariate analyses: a logistic model was performed on the total population, while a linear regression analysis was done on the subsample with quantifiable dioxin activity levels in serum. Region, gender, age, BMI, smoking status, as well as dietary habits were entered in the model, with dioxin level as an outcome estimate. Both the logistic and linear model confirmed the contribution of dietary intake to the dioxin activity measured in serum. Also BMI and region were found to be associated with dioxin activity levels.