Chemical Changes in Sediment Pore-Waters of an Acidic Mining Lake After Addition of Organic Substrate and Lime for Stimulating Lake Remediation

In the past five years, enclosures have beeninstalled in an acidic mining lake in Lusatia to investigate insitu remediation processes. They were treated with straw, withstraw and Carbokalk, or with Carbokalk alone, where Carbokalkis a by-product of the sugar industry (solid precipitate ofnon-sugars after lime clarification of extracted sugar beetjuice). Sediment samples were taken as cores to get informationabout the behaviour of organic and inorganic components insediment pore-water with depth. Vertical distributions of pH,soluble reactive phosphate, nitrate, ammonium, silica,aluminium, iron, manganese, calcium, magnesium, sodium,potassium, sulphate, and DOC were measured. The resultingprofiles, each consisting of 15 data points at differentdepths, were compared by cluster analysis. The similarities ofsediment cores from different treated enclosures relating toprofiles of chemical components were discussed. Increasedconcentrations of potassium and sulphate were found in pore-water after substrate treatment. The data imply dissolution ofpotassium iron sulphate hydroxide minerals (jarosite) after anincrease of pH caused by dissolution of lime and by sulphatereducing processes which were stimulated by organic substrateaddition.     

Biological Pollutants: Alien Fishes in Mountain Lakes

Many lakes in the national parks of the Canadian Rockies were stocked with alien fish species in the early to mid 20th century. Changes to Parks Canada's mandate require the original communities of these lakes to be restored. We document the changes to invertebrate communities caused by the stocking of alien fishes into three fishless alpine lakes, and describe the results of two restoration experiments, one the reintroduction of Hesperodiaptomus arcticus, a planktonic predator that had been eliminated from Snowflake Lake by stocked fish, and the other the removal of brook trout (Salvelinus fontinalis) from Bighorn Lake. In both cases, there were great changes to the zooplankton communities, which required several years to complete, probably because of the cold water and unproductive nature of the lakes. Many of the invertebrate species extirpated by stocked alien fishes co-exist with native fish species in nearby lakes. Possible reasons are discussed.     

Development of Stream Water Chemistry during Spring Melt in a Northern Hardwood Forest

The role of snowmelt and subsurface hydrology in determiningthe chemistry of a small headwater stream in the TurkeyLakes Watershed (TLW) was evaluated for the spring meltperiods 1992 to 1996. Spring runoff is the dominanthydrological event at the TLW each year. Processesoccurring within the snowpack during snowmelt wereprincipally responsible for the above-ground changes inchemical fluxes relative to bulk deposition (the effect ofwinter throughfall was minimal). Large changes in chemicalfluxes occurred below ground. Organic matter decomposition,weathering, nitrification, and element cycling are some ofthe more important below-ground processes that operateduring the snow accumulation and ablation season and controlthe composition of the water ultimately appearing in thestream. Maximum stream discharge was accompanied byelevated concentrations of H⁺, NO₃ ^-, K⁺,NH₄ ⁺, DOC, Al and Mn, but reduced levels ofCa²⁺, Mg²⁺, SO₄ ^2- and SiO₂. Theconcentration-discharge relationships were consistent withwater movement through and above the forest floor duringpeak discharge, a flowpath facilitated by rapid infiltrationof meltwater and the existence of a relatively impermeablelayer in the mineral soil creating a perched water table. Averaged over the five periods of snow accumulation andablation, it was estimated that pre-melt stream flow, andwater routed through the forest floor and through the uppermineral soil contributed 9, 28 and 63%, respectively, ofthe discharge measured at the outlet of the catchment. Theforest floor contribution would be greater at peak dischargeand at higher elevations. An end-member mixing modelestimated concentrations of SO₄ ^2-, NO₃ ^-,Cl^-, Ca²⁺, Mg²⁺, Na⁺ and Al that werecomparable to average values measured in the stream. Othervariables (NH₄ ⁺, H⁺, K⁺ and DOC) wereover-estimated implying retention mechanisms operatingoutside the model assumptions.     

APPLICATION OF AN ENVIRONMENTAL AND ECONOMIC MODELING SYSTEM FOR WATERSHED ASSESSMENTS1

ABSTRACT: A National Pilot Project (NPP) on Livestock and the Environment was initiated in 1992 to help provide solutions to environmental problems associated with livestock production. A major development of the NPP was the Comprehensive Economic and Environmental Optimization Tool‐Livestock and Poultry (CEEOT‐LP), an integrated modeling system designed to produce economic and environmental indicators for alternative policy scenarios applied to intensive livestock production watersheds. The system consists of a farm‐level economic model (FEM) and two environmental models: the field‐scale APEX model and the watershed‐level SWAT model. To date, CEEOT‐LP has been applied to two watersheds in Texas and one in Iowa. Predicted reductions in P losses for two P‐based manure application rate scenarios, relative to baseline conditions, ranged from ?4 to ?54 percent across the three watersheds; however, N loss impacts ranged from a decrease of 34 percent to an increase of 79 percent. For five other alternative scenarios that were simulated for only one watershed, N and P loss impacts ranged between a reduction of 78 percent to an increase of 20 percent. Aggregate watershed‐level economic impacts of the seven scenarios spanned a spectrum of a 27 percent decrease to a 25 percent increase in profit, relative to the baseline.     

Investigation of the ozonolysis of ethylenebisdithiocarbamate-fungicides in model solutions

A study of the effectiveness of ozonation for the removal of nabam (disodium ethylenebisdithiocarbamate) from aqueous solutions was carried out. Nabam is the parent compound of a commonly used group of fungicides. The process of nabam degradation was followed in terms of several parameters such as nabam concentration, chemical oxygen demand (COD), sulphate ion concentration as a measure of the relative degree of mineralization of nabam, and the pH value of the solution. Ozonation accelerates the decomposition of nabam with the formation of sulphates and nitrates as final products. The intermediate decomposition products of nabam are more resistant to degradation by ozone than the parent compound. The amounts of ozone which are used in wastewater treatment plants for disinfection may be sufficient to remove both nabam and its decomposition products, at a low level of contamination, but if the concentration of nabam is too high the intermediate decomposition products can still be present. Lowering the pH of the medium favours the oxidation of nabam.     

Recovery of temperate-stream fish communities from disturbance: A review of case studies and synthesis of theory

To evaluate the relative effect of autecologic factors, site-specific factors, disturbance characteristics, and community structure on the recovery of temperate-stream fish communities, we reviewed case histories for 49 sites and recorded data on 411 recovery end points. Most data were derived from studies of low-gradient third- or fourth-order temperate streams located in forested or agricultural watersheds. Species composition, species richness, and total density all recovered within one year for over 70% of systems studied. Lotic fish communities were not resilient to press disturbances (e.g., mining, logging, channelization) in the absence of mitigation efforts (recovery time >5 to >52 yr) and in these cases recovery was limited by habitat quality. Following pulse disturbances, autecological factors, site-specific factors, and disturbance-specific factors all affected rates of recovery. Centrarchids and minnows were most resilient to disturbance, while salmonid populations were least resilient of all families considered. Species within rock-substrate/nest-spawning guilds required significantly longer time periods to either recolonize or reestablish predisturbance population densities than did species within other reproductive guilds. Recovery was enhanced by the presence of refugia but was delayed by barriers to migration, especially when source populations for recolonization were relatively distant. Median population recovery times for systems in which disturbances occurred during or immediately prior to spawning were significantly less than median recovery times for systems in which disturbances occurred immediately after spawning. There was little evidence for the influence of biotic interactions on recovery rates.     

Mine-drainage treatment wetland as habitat for herptofaunal wildlife

Land reclamation techniques that incorporate habitat features for herptofaunal wildlife have received little attention. We assessed the suitability of a wetland, constructed for the treatment of mine-water drainage, for supporting herptofaunal wildlife from 1988 through 1990 using diurnal and nocturnal surveys. Natural wetlands within the surrounding watershed were also monitored for comparison. The treatment wetland supported the greatest abundance and species richness of herptofauna among the sites surveyed. Abundance was a function of the frog density, particularly green frogs (Rana clamitans) and pickerel frogs (R. palustris), while species richness was due to the number of snake species found. The rich mix of snake species present at the treatment wetland was believed due to a combination of an abundant frog prey base and an amply supply of den sites in rock debris left behind from earlier surface-mining activities. Nocturnal surveys of breeding male frogs demonstrated highest breeding activity at the treatment wetland, particularly for spring peepers (Hyla crucifer). Whole-body assays of green frog and bullfrog (R. catesbeiana) tissues showed no differences among sites in uptake of iron, aluminum, and zinc; managanese levels in samples from the treatment wetland were significantly lower than those from natural wetlands. These results suggest that wetlands established for water quality improvement can provide habitat for reptiles and amphibians, with the species composition dependent on the construction design, the proximity to source populations, and the degree of acidity and heavy-metal concentrations in drainage waters.