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61.
The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric
reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO
initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10−3 and 1.94 × 10−5 min−1respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H2O2 and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed. 相似文献
62.
汽油清净剂的研究应用及进展 总被引:8,自引:0,他引:8
随着环保要求的日趋严格及汽车工业的发展创新,开展汽油清净剂的研究和应用工作已势在必行。本文介绍了国内外汽油清净剂的发展过程、应用现状,同时还介绍了将清净分散剂、抗氧防腐剂、减磨剂、防锈剂等添加剂复合而成的汽油清净剂的研制情况。实验结果表明:该剂具有抑制和清除发动机燃燃油系统沉积物的性能,达到国外第三代同类产品的水平。 相似文献
63.
Muhammad Akram Xing Xu Baoyu Gao Qinyan Yue Shang Yanan Rizwan Khan Muhammad Ali Inam 《环境科学学报(英文版)》2020,32(5):189-198
This study aimed to fabricate new and effective material for the efficiency of phosphate adsorption. Two types of adsorbent materials, the zirconium hydroxides embedded in pomegranate peel (Zr/Peel) and zirconium-lanthanum hydroxides embedded in pomegranate peel (Zr–La/Peel) were developed. Scanning electronic microscopy (SEM), x-ray photoelectron spectroscopy (XPS) and x-ray diffraction (XRD) were evaluated to give insight into the physicochemical properties of these adsorbents. Zr–La/Peel exceeded the adsorption efficiency of Zr/Peel adsorbents in batch adsorption experiments at the same pH level. The peel as a host can strive to have a strong “shielding effect” to increase the steadiness of the entrenched Zr and La elements. La and Zr are hydroxide metals that emit many hydrogen ions during the hydrolysis reaction, which contribute to protonation and electrostatic attraction. The highest adsorption capacity of La–Zr/Peel for phosphate was calculated to be 40.21 mg/g, and pseudo second-order equation is very well fitted for kinetic adsorption. Phosphate adsorption efficiency was reduced by an increase of pH. With the background of coexisting Cl?, little effect on adsorption efficiency was observed, while adsorption capacities were reduced by almost 20–30% with the coexistence of , and humic acid (HA). 相似文献
64.
介绍了葫芦岛市生态环境现状及主要问题,分析了各种生态问题产生的原因,阐述了保护和建设生态环境的主要对策。 相似文献
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简要的回顾水流横向扩散系统的研究现状,介绍了三种用实验求算横向扩散系统的方法,并就嘉陵江的示踪剂扩散试验以及利用现有的扩散系数资源,推求非试验江段的扩散系数的计算式作了详细的叙述。 相似文献
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用自来水和去离子水配制不同的pH溶液,测定涡虫生存及再生的情况,以及涡虫可承受的pH变化幅度,确定日本三角涡虫对不同酸碱环境的耐受性。结果表明涡虫对酸碱环境的耐受力较强。 相似文献
70.
介绍了钢结构件生产加工项目环境影响评价中工程分析、污染防治措施以及清洁生产等方面的环境影响评价要点,以期为同类项目的环境影响评价、污染治理和环境管理提供参考。 相似文献