危化品事故应急辅助决策支持系统的研究

该文提出了以一个事故工程文件处置、管理一次事故的思想。根据危险化学品事故发生的一般特点和事故处置的一般程序,建立了危险化学平事故应急辅助决策支持软件平台。该软件平台利用GIS技术实现了事故的基本情况、事故初始处置、事故事态发展、现场监测预警等功能,在软件平台的基础上搭配相应的硬件设备组成一套完整的应急辅助决策系统。     

一种基于事故后果的重大危险源安全规划方法

介绍了一种基于事故后果的重大危险源安全规划方法。该方法详细阐述了“最坏”事故情景选择、事故后果阈值确定及后果伤害范围划分的方法,以危险源周边人群作为主要脆弱性目标,通过分析事故后果伤害范围和目标的脆弱性级别确定危险源与周边环境的兼容性。另外,以危险品仓储区为例,利用该方法对仓储区可能发生的事故后果影响范围进行计算,对仓储区选址的可行性进行分析。本文提出的重大危险源安全规划方法可为城市土地使用及危险源的安全规划提供参考。     

化工园区接警处警与应急值守系统的研究

本文分析了目前常用的接警处警系统,针对化工园区安全管理的工作需要,研究化工园区综合接警中心接警处警工作的特点和要求,分析化工园区接警中心工作体系和功能要求,设计开发了化工园区接警处警与应急值守系统。文中对系统体系架构、系统建设关键问题和所需的支持系统进行了详细介绍。该系统集成了地理信息系统的功能,提供化工园区事故接警、通知和处置功能,应用重大危险源监管信息系统、应急预案综合管理系统、综合监控系统等业务系统作为数据支持,为化工园区接警中心管理园区突发事件、实现事故快速反应和及时应对提供技术支持。     

Immunotoxicity of bisphenol a to Carassius auratus Lymphocytes and macrophages following in vitro exposure

Bisphenol A （BPA） is the monomer component of polycarbonate plastics and classified as an endocrine disrupting chemical （EDC）. The reproductive toxicity of BPA has been extensively studied in mammals; however, relatively little information is available on the immunotoxic responses of fish to BPA. In this study, we investigated the effects of BPA on the immune functions of lymphocytes and macrophages in Carassius auratus. The effects of BPA were compared with those of two natural steroid hormones, estradiol and hydrocortisone. Proliferation of the two types of cells in response to PHA was measured using colorimetric MTT assay. Macrophage respiratory burst stimulated by Con A was measured using chemiluminescence assay. Results showed that BPA （0.054-5.4 mg/L）, estradiol （0.0002-2.0 mg/L） and hydrocortisone （5-50 mg/L） significantly induced Carassius auratus lymphocyte proliferation while higher doses of hydrocortisone （500-5000 mg/L） appeared to be inhibitory. BPA （0.005-50 mg/L）, estradiol （0.005-800 mg/L） and hydrocortisone （0.005-500 mg/L） markedly enhanced macrophage proliferation, whereas higher doses of BPA （500-1000 mg/L） appeared to inhibit cell proliferation. Furthermore, higher dosage of BPA （50 mg/L） and hydrocortisone （50 and 500 mg/L） suppressed the macrophages respiratory burst while estradiol is stimulative all the doses tested （0.05-500 mg/L）. In conclusion, BPA could have immunotoxicity to Carassius auratus and functional changes of lymphocyte and macrophage in Carassius auratus may be different between low and high dosages.     

Transformations of particles, metal elements and natural organic matter in different water treatment processes

Characterizing natural organic matter （NOM）, particles and elements in different water treatment processes can give a useful information to optimize water treatment operations. In this article, transformations of particles, metal elements and NOM in a pilot-scale water treatment plant were investigated by laser light granularity system, particle counter, glass-fiber membrane filtration, inductively coupled plasma-optical emission spectroscopy, ultra filtration and resin absorbents fractionation. The results showed that particles, NOM and trihalomethane formation precursors were removed synergistically by sequential treatment of different processes. Preozonation markedly changed the polarity and molecular weight of NOM, and it could be conducive to the following coagulation process through destabilizing particles and colloids; mid-ozonation enhanced the subsequent granular activated carbon （GAC） filtration process by decreasing molecular weight of organic matters. Coagulation-flotation and GAC were more efficient in removing fixed suspended solids and larger particles; while sand-filtration was more efficient in removing volatile suspended solids and smaller particles. Flotation performed better than sedimentation in terms of particle and NOM removal. The type of coagulant could greatly affect the performance of coagulation-flotation. Pre-hydrolyzed composite coagulant （HPAC） was superior to FeCl3 concerning the removals of hydrophobic dissolved organic carbon and volatile suspended solids. The leakages of flocs from sand-filtration and microorganisms from GAC should be mitigated to ensure the reliability of the whole treatment system.     

Imazaquin degradation and metabolism in a sandy loam soil amended with farm litters

Irnazaquin applied in legume crops has a long residual time in soil, which often impacts safety of the susceptible crops. To increase safety of imazaquin application, two composted litters, bovine manure （BM） and chicken manure （CM）, were used to determine their effects on imazaquin environmental behavior by incorporating each kind of manure into the tested sandy loam soil at 10% （w/w）. The degradation of imazaquin in BM- and CM-amended soil was about 2.4 and 1.5 times, respectively, faster than that in unamended soil. The half-lives of imazaquin in BM-amended soil varied between 6.7 and 15.4 d over the temperature range of 20 to 40℃, and the degradation rate constant （k） increased by a factor of about 1.5 for every 10℃ change. Higher mix ratio did not significantly increase the degradation, and the optimal active degradation of imazaquin was observed approximately at the mix ratio of 10：1 of soil to BM. The different moisture levels had negligible effect on imazaquin degradation. In both unamended and BM-amended treatments, two metabolites were observed at 5, 10 and 30 d after treatment. One metabolite at retention time （RT） of 8.4 rain was identified as 2-（4- hydroxyl-5-oxo-2-imidazolin-2-yl） quinoline acid, originating from the loss of isopropyl group and hydroxylation at the 4-position of imidazolinone ring. The other at RT of 12.9 rain was identified as quinoline-2,3-dicarboxylic anhydride, resulting from detachment of imidazolinone ring and the forming of dicarboxylic anhydride. This finding suggested that the addition of farm litters into soil might be a good management option since it can not only increase soil fertility but also contribute to increase safety of imazaquin application to the following susceptible crops.     

液液萃取-气相色谱/串联质谱法测定水中五氯酚及其钠盐

采用液液萃取处理水样,用气相色谱-串联质谱法测定样品中五氯酚及其钠盐,通过优化测定条件,使方法在1.00μg/L～500μg/L范围内线性良好.检出限和定量限分别为1.00μg/L和5.00μg/L,空白水样五氯酚钠3个质量浓度水平的加标回收率为89.8％～98.4％,5次平行试验测定结果的RSD为5.5％～10.7％...     

湖泊型水源地管理研究——以苏州市太湖水源地为例

饮用水安全是最大的民生工程,也是自然资源管理研究的热点。基于实地调研、部门访谈和制度条文的梳理与分析,以苏州市太湖水源地为例研究湖泊型水源地管理体制。研究表明：我国水源地管理由国家、省、市、县的法律法规、规章和规范性文件构成相对完善的制度体系,具有水资源和水环境分割管理、流域管理和行政区管理交错的制度特征,初步具备了综合管理的架构;水源保护缺乏流域管治的思维,农村面源污染治理制度支撑不足;在管理手段上以命令控制型手段为主,经济激励与公众参与不足。建立水源地综合管理协调机制,完善经济激励手段,推进公众参与,实施水源地管理共同责任机制将有利于提高水源地管理效率     

中国企业社会责任财务绩效评价模型研究

2003年,英国政府出台了<我们能源的未来-创建低碳经济>能源白皮书,其中首次引入了"低碳经济"的概念,随后越来越多的学者开始探讨这种经济发展模式及其技术和政策的可行性,并展开了一系列实证研究.而在这种新的经济发展趋势下,作为经济主体的企业所要承担的社会责任也就被赋予了新的内窖.那么在向低碳经济转型的过程中,如何对企业的社会责任进行客观、有效的评价将对于企业更好履行其社会责任起到重要作用.基于我国国情,本文通过对低碳经济发展模式下中国企业社会责任财务绩效进行模型研究,提出了在传统指标分析模型基础上进行数据包络分析(DEA)和可持续计量的双重模型修正,以期弥补传统财务绩效模型在企业有效投入分析和动态性评价方面的缺陷和不足.     

西安市大气和水污染对人群健康损害的经济价值损失研究

环境污染对人群健康造成损害的经济价值评价一直是学术界讨论的热点．采用不同的价值评估方法-VPLL潜在寿命损失年法、VSL统计生命价值法、WTP支付意愿法对西安市1996—2003年的大气和水污染对人群健康造成的经济损失进行评价。结果表明：1996—2003年。西安市大气和水污染健康损失年平均为228792万-434237万元，占GDP的3．69％-7％。对居民健康有显着影响。