提高重大工业事故预防控制能力研究

从系统宏观安全及事故预防的微观要素两方面,深入剖析我国在事故预防法规标准、重大危险源监控、隐患治理、安全设备设施、安全科研、人员素质等方面存在的问题,提出"五个转变"的理念,并从健全事故预防法规标准、严格安全设备及人员准入、构建多级事故风险预警机制、创新安全管理模式、加强重大事故预防控制新技术研究和应用、推进重大危险源监管实用技术开发与推广等方面提出相应的措施方法,突出强调了风险预控和依靠安全科技,建议加强对重大危险源和重大事故隐患预防控制工作的系统思考和统筹规划。     

大城市边缘区土地利用时空格局模拟--以武汉市洪山区为例

大城市边缘区的土地利用变化复杂而迅速,采用定量模型对此地域的时空格局进行模拟,在土地规划领域有重大意义。以武汉市洪山区为例,首先采用DPSIR模型对大城市边缘区的工业用地、居住用地、服务设施用地、绿地等进行驱动力机制的定性分析,得出每种用地相应的驱动力、压力和状态;进而采用CLUE S模型,通过用地变化驱动力因子作用权重系数的求解,模拟时段内各类用地的需求分析与用地变化的动态分配过程,对边缘区的用地演变进行模拟;最后通过用地现状图对模拟用地进行验证,模拟结果基本拟合。在模拟的基础之上,设定了两种大城市边缘区空间发展的情景模式,即不作任何空间约束的用地演变和进行可持续发展约束的用地演变,有针对性地提出该区域的发展需要重点保护水体和自然风景区。其方法及成果可为大城市边缘区制定发展管理政策提供科学参考。     

UV/Fe3+/H2O2体系降解活性艳橙X-GN废水的研究

采用UV/Fe3 /H2O2体系光解活性艳橙X-GN模拟废水,考察了X-GN,Fe3 和H2O2的初始浓度、初始pH值及温度对光解的影响,探讨了X-GN的降解途径和机理.结果表明,在8W低压汞灯(λ＝254nm)照射下,UV/Fe3 /H2O2能够有效地降解X-GN,在pH=3.0,T=50 ℃,时间为120 min,Fe3 和H2O2的初始浓度分别为2.5×10-5 mol·l-1和1.5×10-4 mol·l-1时,对含200 mg·l-1 X-GN模拟废水的色度去除率和矿化率分别达到100%和90.15%.用IC和GC/MS对X-GN降解的中间产物和最终产物进行分析,推导出UV/Fe3 /H2O2体系中X-GN降解的途径和机理.     

节约土地资源的沉沙淤泥新型墙体材料的研制

引黄济青工程创造了惊人的经济效益和社会效益,但大量的黄河淤泥沉积,却危害了当地生态环境,造成土地资源浪费.通过分析黄河淤泥的化学成分、颗粒组成、塑性指数,对沉淀池堆场的淤泥和黄河河床的淤泥进行比较和筛选,最后进行了成型和煅烧,试验结果表明:2号堆场的黄河淤泥完全可以替代粘土作原料生产新型墙体材料,其技术指标完全符合国家产品质量要求,每年可节约土地约13.3公顷.     

稳定化技术在铅砷复合污染土壤修复中的应用

以铅砷复合污染土壤为研究对象,采用硫酸亚铁和氧化钙作为稳定剂,通过正交实验得出各因素对土壤中铅的稳定率影响程度的大小顺序为:氧化钙添加量>硫酸亚铁添加量=养护周期>两种稳定剂的交互作用.最佳实验条件为硫酸亚铁添加量2 g/kg,氧化钙添加量10 g/kg,养护时间2 d.添加硫酸亚铁后,土壤pH对砷的稳定化效果影响不大...     

Adsorption removal of thiocyanate from aqueous solution by calcined hydrotalcite

A hydrotalcite with Mg/AI molar ratio 2 was prepared by co-precipitation method and was characterized by XRD, TG/DTA, Zeta potential and BET surface area. The hydrotalcite was calcined at 500℃, with the dehydration from interlayer, the dehydroxilation from the brucite-like layer and the decomposition of carbonate successively, transformed into the mixed oxide type. The removal of thiocyanate from aqueous solution by using the original hydrotalcite and calcined hydrotalcite （HTC-500） was investigated. The results showed that the thiocyanate adsorption capacity of calcined hydrotalcite was much higher than that of the original form. Calcined hydrotalcite was particularly effective at removing thiocyanate, and that the effective range of pH for the thiocyanate removal are between 5.5-10.0. The experimental data of thiocyanate removal fit nicely with Langmuir isotherm, and the saturated adsorption uptake was 96.2 mg SCN-/g HTC-500. The adsorption of thiocyanate by calcined hydrotalcite follows first-order kinetics. And the intercalation to the structure recovery for calcined hydrotalcite. But the presence of additional anions could affect the adsorption behavior of thiocyanate.     

Supercritical gasification for the treatment of o-cresol wastewater

The supercritical water gasification of phenolic wastewater without oxidant was performed to degrade pollutants and produce hydrogen-enriched gases. The simulated o-cresol wastewater was gasified at 440-650℃ and 27.6 MPa in a continuous Inconel 625 reactor with the residence time of 0.42-1.25 min. The influence of the reaction temperature, residence time, pressure, catalyst, oxidant and the pollutant concentration on the gasification efficiency was investigated. Higher temperature and longer residence time enhanced the o-cresol gasification. The TOC removal rate and hydrogen gasification rate were 90.6% and 194.6%, respectively, at the temperature of 650℃ and the residence time of 0.83 min. The product gas was mainly composed of H2, CO2, CFL and CO, among which the total molar percentage of H2 and CFL was higher than 50%. The gasification efficiency decreased with the pollutant concentration increasing. Both the catalyst and oxidant could accelerate the hydrocarbon gasification at a lower reaction temperature, in which the catalyst promoted H2 production and the oxidant enhanced CO2 generation. The intermediates of liquid effluents were analyzed and phenol was found to be the main composition. The results indicate that the supercritical gasification is a promising way for the treatment of hazardous organic wastewater.     

公路建设中边坡水毁模式与处治对策

文章在总结了国道105线边坡的水毁破坏模式基础上,分析了地下水在边坡破坏中所起的作用,提出了相应的处治对策。     

白洋淀两种生境中芦苇地上生物量及其影响因子分析

文章在野外调查的基础上,在白洋淀台田和沼泽中各选择6个样区,统计分析了2种生境芦苇地上生物量;运用冗余分析方法(RDA),分析了芦苇生长季(4～9月)平均水深、土壤/底泥有机质、全氮和全磷等对两类生境中芦苇地上生物量的影响.结果表明,台田、沼泽中芦苇地上生物量分别为1 408.2±527.5 gDW/m2、723.2±...     

低C/N城市污水亚硝酸型硝化试验研究

对低C/N城市污水进行亚硝酸型硝化的可行性、稳定性进行了研究,具体研究了系统的启动培养、稳定亚硝化、污泥毒害、短暂亚硝化、污泥适应等5个阶段及污泥的适应性问题。低C/N城市污水可实现稳定的亚硝酸型硝化,其亚硝化率最高可达90%。试验中合理确定反应周期的首要因素是系统出水NH4+-N的浓度至少达到50%降解率,其次是出水中NOx-NN应主要以NO2-N为主。根据泥龄维持所能维持的MLSS浓度确定系统泥龄在合理范围。系统不排泥和较长泥龄将不能通过排泥,将系统中硝化菌"洗出",硝化菌也会最终适应亚硝酸型硝化的环境因素,从而导致亚硝酸型硝化现象的不可逆消失。杆状污泥絮体为亚硝酸型硝化现象的特征污泥相。