环境空气中VOC s 的监测技术新进展

大气中的挥发性有机物(VOCs)严重威胁着人类的健康,目前对它的监测技术的研究越来越多.文章综述了近年来国内外在VOCs的采样及测试技术上的进展,重点介绍了固相微萃取、罐取样、吸附法等采样技术以及以气相色谱法为主的分析方法,并对一些非色谱法的分析技术进行了简单介绍.     

A vulnerability analysis in the Fei-tsui reservoir watershed in Taiwan

The vulnerability analysis method has been widely used in many environmental fields. In recent years, the tool has succeeded in comprehensive assessment of environmental problems. This study applied the vulnerability and resilience analysis method on watershed conservation and grasped the environmental change capacity that watershed could bear. The Fei-tsui reservoir watershed in Northern Taiwan provided the setting for the case study reported herein. This study considered both internal and external effect factors, including watershed vulnerability, rainfall energy and the distances between the outlet and subbasins, and developed a new index, WP, for the priority restraints strategies on the land-use activities. The land-use restraint index can be a significant criterion for watershed protection and management strategies.     

Optimal Expansion Strategy for a Sewer System under Uncertainty

Because of fast urban sprawl, land use competition, and the gap in available funds and needed funds, municipal decision makers and planners are looking for more cost-effective and sustainable ways to improve their sewer infrastructure systems. The dominant approaches have turned to planning the sanitary sewer systems within a regional context, while the decentralized and on-site/cluster wastewater systems have not overcome the application barriers. But regionalization policy confers uncertainties and risks upon cities while planning for future events. Following the philosophy of smart growth, this paper presents several optimal expansion schemes for a fast-growing city in the US/Mexico borderlands—the city of Pharr in Texas under uncertainty. The waste stream generated in Pharr is divided into three distinct sewer sheds within the city limit, including south region, central region, and north region. The options available include routing the wastewater to a neighboring municipality (i.e., McAllen) for treatment and reuse, expanding the existing wastewater treatment plant (WWTP) in the south sewer shed, and constructing a new WWTP in the north sewer shed. Traditional deterministic least-cost optimization applied in the first stage can provide a cost-effective and technology-based decision without respect to associated uncertainties system wide. As the model is primarily driven by the fees charged for wastewater transfer, sensitivity analysis was emphasized by the inclusion of varying flat-rate fees for adjustable transfer schemes before contracting process that may support the assessment of fiscal benefits to all parties involved. Yet uncertainties might arise from wastewater generation, wastewater reuse, and cost increase in constructing and operating the new wastewater treatment plant simultaneously. When dealing with multiple sources of uncertainty, the grey mixed integer programming (GIP) model, formulated in the second stage, can further allow all sources of uncertainties to propagate throughout the optimization context, simultaneously leading to determine a wealth of optimal decisions within a reasonable range. Both models ran for three 5-year periods beginning in 2005 and ending in 2020. The dynamic outputs of this analysis reflect the systematic concerns about integrative uncertainties within this decision analysis, which enable decision makers and stakeholders to make all-inclusive decisions for sanitary sewer system expansion in an economically growing region.     

Disinfection by-product formation and mutagenic assay caused by preozonation of groundwater containing bromide

Brominated organic and inorganic by-products are generated during ozonation of groundwater containing high bromide concentrations. This study measured concentrations of bromate, bromoform, bromoacetic acids, bromoacetonitriles, bromoacetone, 2,4-dibromophenol and aldehyde generated by ozonation. The potential mutagenicity of ozonated waters was assessed using the Ames and Microtox tests. Test results for the 18 ozonated groundwater samples demonstrate that bromate formation is associated with high pH, bromide and alkalinity content, low levels of dissolved organic carbon (DOC) and ammonia, and low alkalinity. Brominated organic by-products were correlated with high bromide ion and natural organic matter content, and low ammonia concentrations. The Ames test results demonstrate that all extracts from ozonated water have mutagenic activity; however, the 18 raw groundwater samples had no mutagenicity. The Microtox test results also show that the ozonated water samples were highly toxic. Generally, both bromide and DOC content promoted the formation of ozonation by-products and mutagenicity. Controlling of bromide and DOC concentrations is an effective method of reducing potential by-product formation and eliminating mutagenicity problems associated with groundwater ozonation.     

Joint Impact of Scaling and Hysteresis on NAPL Flow Simulation

The hysteresis of capillary pressure versus saturation (P–S) relation is an important constitutive relation in multiphase flow, since the P–S relation is widely used to predict P–S relations in the simulation of the non-aqueous phase liquids (NAPLs). This work examined the performance of the scaling rule on predicting the P–S relationship and then studied the joint impact of the scaling and hysteresis on the multiphase NAPL flow simulation. Various experimental P–S values of distinct fluid pairs were compared with the scaled P–S curves using the scaling rule. The comparison indicated that the prediction of P–S is more accurate when the water–air P–S curve is used to scale other P–S curves. The joint impact of the scaling and hysteresis on the NAPLs flow simulation was then investigated by numerical simulation studies. The NAPL simulator was used to simulate the outcome of several scenarios based on a system with water–NAPL–air in a hypothetical sand tank. For both gasoline and trichloroethylene, the difference of the injected NAPL volume between no hysteretic and hysteretic simulations over a given time period was the smallest when the water–air P–S curve was used to scale other P–S curves. Simulation results of this study are valuable references for predicting the distribution of NAPLs.     

Minimax regret optimization analysis for a regional solid waste management system

Solid waste management (SWM) facilities are crucial for environmental management and public health in urban regions. Due to the waste management hierarchy, one of the greatest challenges that organizations face today is to figure out how to diversify the treatment options, increase the reliability of infrastructure systems, and leverage the redistribution of waste streams among incineration, compost, recycling, and other facilities to their competitive advantage region wide. Systems analysis plays an important role for regionalization assessment of integrated SWM systems, leading to provide decision makers with break-through insights and risk-informed strategies. This paper aims to apply a minimax regret optimization analysis for improving SWM strategies in the Lower Rio Grande Valley (LRGV), an economically fast growing region in the US. Based on different environmental, economic, legal, and social conditions, event-based simulation in the first stage links estimated waste streams in major cities in LRGV with possible solid waste management alternatives. The optimization analysis in the second stage emphasizes the trade-offs and associated regret evaluation with respect to predetermined scenarios. Such optimization analyses with multiple criteria have featured notable successes, either by public or private efforts, in diverting recyclables, green waste, yard waste, and biosolids from the municipal solid waste streams to upcoming waste-to-energy, composting, and recycling facilities. Model outputs may link prescribed regret scenarios in decision making with various scales of regionalization policies. The insights drawn from the system-oriented, forward-looking, and preventative study can eventually help decision-makers and stakeholders gain a scientific understanding of the consequences of short-term and long-term decisions relating to sustainable SWM in the fast-growing US-Mexico borderland.     

Influence of start-up on PCDD/F emission of incinerators

This study aims to evaluate the influence of start-up on polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) concentration in the stack flue gas of incinerators and its contributing PCDD/F emission. The PCDD/F emission of the first sample among three consecutive stack flue gas samples of five intermittent incinerators, which sampled at a stable combustion condition after start-up, is 2-3 times higher than the mean of the others. For verifying the PCDD/F characteristics of incinerators during start-up, one continuous MSWI was investigated for two years. The elevated PCDD/F emissions of the MSWI during start-up could reach 96.9 ng I-TEQN m(-3) and still maintained a high PCDD/F emission (40 times higher than the Taiwan emission limit) even 18 h after the injection of activated carbon, indicating the memory effect. Taking the MSWI for example, which consists of four incinerators, the estimated annual PCDD/F emission from normal operational conditions was 0.112 g I-TEQ. However, one start-up procedure can generate approximately 60% of the PCDD/F emissions for one whole year of normal operations. And the PCDD/F emission, which is the result of the start-ups of four incinerators, was at least two times larger than that of a whole year's normal operations, without consideration for the PCDD/F emission contributed by the long lasting memory effect.     

Aerobic degradation of bisphenol A by Achromobacter xylosoxidans strain B-16 isolated from compost leachate of municipal solid waste

A novel bacterium designated strain B-16 was isolated from the compost leachate of the municipal solid waste (MSW) in a laboratory reactor. This strain was identified as a gram-negative bacterium, Achromobacter xylosoxidans that could grow on bisphenol A (BPA, a representative endocrine disruptor) as a sole carbon source under aerobic condition. BPA-degrading characteristics of strain B-16 were investigated in liquid cultures. The results show that BPA degradation was influenced by several factors (e.g. inoculum size, substrate concentration, temperature and pH, etc). The half-lives, optimum temperature and pH were found to be 0.58-3.1d, 35 degrees C and 7.0, respectively. BPA-degrading activity and cell growth were inhibited at high substrate concentration. Metabolic intermediates detected during the degradation process were identified as p-hydroxybenzaldehyde, p-hydroxybenzoic acid and p-hydroquinone, respectively. Metabolic pathway of BPA degradation was proposed in this study.     

Anaerobic degradation of nonylphenol in soil

This study investigated the effects of various factors on the anaerobic degradation of nonylphenol (NP) in soil. The results show that the optimal pH for NP degradation was 7.0 and that the degradation rate was enhanced when the temperature was increased. The addition of compost enhanced NP degradation. The individual addition of the electron donors lactate, acetate, and pyruvate inhibited NP degradation. The high-to-low order of NP degradation rates under three anaerobic conditions was sulfate-reducing conditions > methanogenic conditions > nitrate-reducing conditions. The results show that sulfate-reducing bacteria, methanogen, and eubacteria are involved in the anaerobic degradation of NP, with sulfate-reducing bacteria being a major component of the soil. Of the anaerobic strains isolated from the soil samples, strain AT3 expressed the best ability to biodegrade NP.     

Remediation of soil contaminated with pyrene using ground nanoscale zero-valent iron

The sites contaminated with recalcitrant polycyclic aromatic hydrocarbons (PAHs) are serious environmental problems ubiquitously. Some PAHs have proven to be carcinogenic and hazardous. Therefore, the innovative PAH in situ remediation technologies have to be developed instantaneously. Recently, the nanoscale zero-valent iron (ZVI) particles have been successfully applied for dechlorination of organic pollutants in water, yet little research has investigated for the soil remediation so far. The objective in this work was to take advantage of nanoscale ZVI particles to remove PAHs in soil. The experimental factors such as reaction time, particle diameter and iron dosage and surface area were considered and optimized. From the results, both microscale and nanoscale ZVI were capable to remove the target compound. The higher removal efficiencies of nanoscale ZVI particles were obtained because the specific surface areas were about several dozens larger than that of commercially microscale ZVI particles. The optimal parameters were observed as 0.2 g iron/2 mL water in 60 min and 150 rpm by nanoscale ZVI. Additionally, the results proved that nanoscale ZVI particles are a promising technology for soil remediation and are encouraged in the near future environmental applications. Additionally, the empirical equation developed for pyrene removal efficiency provided the good explanation of reaction behavior. Ultimately, the calculated values by this equation were in a good agreement with the experimental data.