Arsenic speciation in plants growing in arsenic-contaminated sites

Concentrations of total arsenic and of arsenic species were determined by ICPMS and HPLC-ICPMS in terrestrial plant samples. The arsenic concentration in plant samples from the contaminated sites ranged from 1.14 to 98.5 mg kg(-1) (dry mass). However, a very high value, exceeding largely this range was found in a moss sample growing in the contaminated area (1750 mg kg(-1)). Plants growing in a non-contaminated area with similar geological characteristics contained 0.06-0.58 mg As kg(-1). Plant samples from different species were selected and extracted with water, water/methanol (9+1, v/v), and water/methanol (1+1, v/v). Water/methanol (9+1, v/v) was selected as extractant for the speciation analysis for all the plant samples. The extraction efficiencies ranged from 3.0% to 41.4%, with good agreement between samples from the same plant species. Arsenite and/or arsenate were found in all the plant samples. Additionally, methylarsonate (MA), dimethylarsinate (DMA), trimethylarsine oxide (TMAO) and tetramethylarsonium ion (TETRA) were also identified in several plants, and in some cases MA and DMA were the main species found. TMAO, which is usually found as a trace constituent in organisms, was also a significant arsenical in one of the studied samples, where it constituted 24% of the extracted arsenic. In the present study, the patterns of arsenic species varied with the plant species and much higher proportion of organoarsenicals was found in plants from the more contaminated sites.     

Environmental risks of farmed and barren alkaline coal ash landfills in Tuzla, Bosnia and Herzegovina

The disposal of coal combustion residues (CCR) has led to a significant consumption of land in the West Balkan region. In Tuzla (Bosnia and Herzegovina) we studied previously soil-covered (farmed) and barren CCR landfills including management practises, field ageing of CCR and the transfer of trace elements into crops, wild plants and wastewaters. Soil tillage resulted in mixing of cover soil with CCR. Medicago sativa showed very low Cu:Mo ratios (1.25) which may cause hypocuprosis in ruminants. Total loads of inorganic pollutants in the CCR transport water, but not pH ( approximately 12), were below regulatory limits of most EU countries. Arsenic concentrations in CCR transport water were <2microgl(-1) whereas reductive conditions in an abandoned landfill significantly enhanced concentrations in leachates (44microgl(-1)). The opposite pattern was found for Cr likely due to large initial leaching of CrVI. Public use of landfills, including farming, should be based on a prior risk assessment due to the heterogeneity of CCR.     

Safety metaphors and theories,a review of the occupational safety literature of the US,UK and The Netherlands,till the first part of the 20th century

The 19th century and first half of the 20th century is one of those periods in history of rapid economical, technical and social changes. There is an ongoing mechanization, followed by a movement to rationalize production and to make it cost effective. This has created a heavy burden of occupational deaths amongst workers. In this period occupational safety is developing into a professional field. Engineers are enclosing hazards and fencing heights, shaping up safety technique, and writing very practical publications on occupational safety. These publications, predominantly published in the United States, are leading to quite some safety related metaphors, with the iceberg and the domino’s as the most famous ones. Sociologists, psychologists, and physicians are more concerned with questions related to accident causation, and these specialists are conducting research leading to two different safety theories. Causes of occupational accident are found either in the workers’ capacity to handle hazardous situations, or in external causes, like very long working hours, dangerous machines and the increased pressures of work and speed of production. The Pittsburgh survey, the first extended analysis of occupational accidents in a steel district, strongly advocated the environmental hypothesis, while the so-called ‘individual hypothesis’ is favored by the American Safety First Movement, starting as a private initiative in 1906 by US Steel, and later spreading out over Western European countries. The British Industrial Fatigue Board has given the individual hypothesis its scientific justification. Despite scientific criticism just after World War II on the concept of accident proneness and ‘unsafe acts’, its popularity is not fading. Even nowadays the famous metaphors are still part of the vocational training of safety experts, also in The Netherlands. Apparently professional and scientific developments in occupational safety are belonging to two separate worlds. Before World War II, The Netherlands is not a leading country in occupational safety but a follower, first of France and the German speaking countries. After World War I its focus is directed towards the Anglo-Saxon countries.     

The jamming avoidance response in the weakly electric fishEigenmannia

This study analyzes the algorithm by which the animal's nervous system evaluates spatially distributed temporal patterns of electroreceptive information. The outcome of this evaluation controls the jamming avoidance response, which is a shift in the animal's electric organ discharge frequency away from similar foreign frequencies. The encoding of “behaviorally relevant” stimulus variables by electroreceptors and the central computation of their messages are investigated by combined behavioral and neurophysiological strategies.     

Intragroup dynamics of a cooperative breeder: An anlysis of reproductive roles in the acorn woodpecker

Summary The acorn woodpecker is a cooperative breeder generally thought to breed promiscuously within groups, but alternative patterns of reproductive investment can be expected and remain to be examined. With this feature of mating system in mind, we studied the reproductive roles of individuals in a single group of this species in central coastal California over a three-year period. Particularly detailed observations were made in 1979, when the group consisted of two potentially breeding sibling males and a single breeding female. One male (298) contributed significantly more than 297 in virtually all aspects of nest and fledgling care. These include (1) feeding nestlings, (2) nest sanitation, (3) nocturnal incubation and brooding, (4) feeding fledglings, and (5) escorting fledglings. In the few observed and rarely occurring dominance interactions, 298 prevailed. These results suggest that 298 had a higher probability of fathering the group's two 1979 offspring than did his brother. Thus, the two males differed substantially in their parental roles within the group, and very likely in reproductive roles, also. At present stage of knowledge, monogamy in groups with one female and more than one potential reproductive male is no less likely than promiscuity. These findings are discussed with respect to the evolution of cooperative breeding in this species.     

Translation of user requirements into house designs: A multi-dimensional scaling analysis

An experiment was conducted to determine how user requirements for single-storey houses are translated into actual design layouts. Architectural students were asked to provide floorplans of houses for four quite different hypothetical users. The briefs contained information either about spatial requirements or about life-style characteristics. Another group of architectural students later evaluated the appropriateness of the designs for the intended user. An INDSCAL analysis of the data (inter-room distances) produced a 4-dimensional solution that accounted for 65% of the variance between house designs. The salience of the dimensions seemed to be more a function of the designer than of the requirements of the user.It was found that when users' requirements are expressed in spatial terms only, the designs produced are clearly a function of the user, not the designer. The more information supplied about the user, the greater the tendency for congruence in the designs. When the brief consisted of life-style characteristics only, the results remained equivocal. There appeared to be little consensus on what designs were appropriate for the hypothetical users.The experiment strongly suggested that (a) architecture students handle information about spatial requirements with ease and with a good deal of consensus on what they consider to be the appropriate design solution for each user; (b) information about life-style characteristics and activity profiles, on the other hand, is handled quite differently by different students. In the latter case, the house designs produced probably follow implicit design-behaviour theories that are quite idiosyncratic. A number of theoretical and methodological issues that require further investigation are raised in the discussion.