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651.
Kenneth M. Doll Erin L. Walter Rex E. Murray Hong-Sik Hwang 《Journal of Polymers and the Environment》2018,26(9):3670-3676
Organogels are used in a variety of high value applications including the removal of toxic solvents from aqueous environments and the time-controlled release of compounds. One of the most promising gelators is a polyvinyl polymer containing medium chain length carboxylic acids. The existing production of this product requires synthesis of vinyl esters containing medium length carboxylic chains. This starting material must be made from an expensive and low yielding transvinylation reaction, which leaves production of useful vinyl esters and, as a result, the organogels themselves, outside the realm of practical chemistry. We have developed a new, more practical production process and used it to directly synthesize a new polymer. This new process utilizes commercially available polyvinyl acetate and accomplishes the transformation with simple hydrolysis and anhydride addition steps. The new polymers form organogels with chloroform, acetone or toluene with swell ratios up to 30. They also show time-controlled release of crystal violet over a 100 h span. This new production process opens the possibility of producing organogels utilizing agricultural resources. 相似文献
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653.
Stefanie Walter Michael Brüggemann Sven Engesser 《Environmental Communication: A Journal of Nature and Culture》2018,12(2):204-217
Although there is a broad consensus among scientists and journalists about the existence of anthropogenic climate change as a global problem, some segments of the population remain doubtful about the human impact on it. The internet provides citizens with opportunities to publicly voice their doubts and user comment sections of online media are a popular form of user-generated content. This study identifies factors that foster comments that are sceptical or supportive of basic assumptions of anthropogenic climate change, drawing on online news in the US, the UK, Germany, India, and Switzerland. The results show that users adapt to the dominant opinion within the respective media outlet: user comment sections serve as echo chambers rather than as corrective mechanisms. Climate change denial is more visible in user comment sections in countries where the climate change debate reflects the scientific consensus on climate change and user comments create niches of denial. 相似文献
654.
Ringler Max Szipl Georgine Hödl Walter Khil Leander Kofler Barbara Lonauer Michael Provin Christina Ringler Eva 《Behavioral ecology and sociobiology》2017,71(8):1-14
Behavioral Ecology and Sociobiology - Colony size is an important predictor of annual survival and reproduction in social insects. By tracking monthly forager turn over, we measured the... 相似文献
655.
Anthony R. Prestigiacomo Steven W. Effler Rakesh K. Gelda David A. Matthews Martin T. Auer Benjamin E. Downer Anika Kuczynski M. Todd Walter 《Journal of the American Water Resources Association》2016,52(1):31-47
The integration of the phosphorus (P) bioavailability concept into a P loading analysis for Cayuga Lake, New York, is documented. Components of the analyses included the: (1) monitoring of particulate P (PP), soluble unreactive P (SUP), and soluble reactive P (SRP), supported by biweekly and runoff event‐based sampling of the lake's four largest tributaries; (2) development of relationships between tributary P concentrations and flow; (3) algal bioavailability assays of PP, SUP, and SRP from primary tributaries and the three largest point sources; and (4) development of P loading estimates to apportion contributions according to individual nonpoint and point sources, and to represent the effects of interannual variations in tributary flows on P loads. Tributary SRP, SUP, and PP are demonstrated to be completely, mostly, and less bioavailable, respectively. The highest mean bioavailability for PP was observed for the stream with the highest agriculture land use. Point source contributions to the total bioavailable P load (BAPL) are minor (5%), reflecting the benefit of reductions from recent treatment upgrades. The BAPL represented only about 26% of the total P load, because of the large contribution of the low bioavailable PP component. Most of BAPL (>70%) is received during high flow intervals. Large interannual variations in tributary flow and coupled BAPL will tend to mask future responses to changes in individual inputs. 相似文献
656.
Treated wastewater effluent from Las Vegas, Nevada and surrounding communities’ flow through Las Vegas Wash (LVW) into the Lake Mead National Recreational Area at Las Vegas Bay (LVB). Lake sediment is a likely sink for many hydrophobic synthetic organic compounds (SOCs); however, partitioning between the sediment and the overlying water could result in the sediment acting as a secondary contaminant source. Locating the chemical plumes may be important to understanding possible chemical stressors to aquatic organisms. Passive sampling devices (SPMDs and POCIS) were suspended in LVB at depths of 3.0, 4.7, and 6.7 (lake bottom) meters in June of 2008 to determine the vertical distribution of SOCs in the water column. A custom sediment probe was used to also bury the samplers in the sediment at depths of 0-10, 10-20, and 20-30 cm. The greatest number of detections in samplers buried in the sediment was at the 0-10 cm depth. Concentrations of many hydrophobic SOCs were twice as high at the sediment-water interface than in the mid and upper water column. Many SOCs related to wastewater effluents, including fragrances, insect repellants, sun block agents, and phosphate flame retardants, were found at highest concentrations in the middle and upper water column. There was evidence to suggest that the water infiltrated into the sediment had a different chemical composition than the rest of the water column and could be a potential risk exposure to bottom-dwelling aquatic organisms. 相似文献
657.
Walter F. Baber 《Journal of Environmental Policy & Planning》2020,22(1):72-83
ABSTRACTWhat would it mean to conceptualize some environmental relationships as bundles of rights, rather than as a good as generally defined by liberalism? Environmental rights are a category of human rights necessarily central to both democracy and global environmental protection and governance (ecological democracy). The world of democratic politics and governance since mid-twentieth century has been transformed by a rights revolution in which recognized rights have come to constitute a ‘global normative order.’ There are several policy spaces in which persuasive environmental rights discourses have been emerging from existing or foreseeable congruences of elite and popular environmental norms, including (1) rights involving access to information and decision-making processes; (2) rights ensuring access to food and water; and (3) rights providing environmental security to all. We analyze these three rights discourses and assess their current and necessary future trajectories. We identify next steps in achieving better understanding and more meaningful establishment of environmental rights and their integration into our thinking about human rights, with attention to how they can be reconciled with the social and cultural diversity of democratic environmental governance in coming turbulent times. 相似文献
658.
659.
ESTROM—a Romanian–Swiss research programme 总被引:1,自引:0,他引:1
Hua L Wu W Liu Y McBride MB Chen Y 《Environmental science and pollution research international》2009,16(1):1-9
Background, aim, and scope Composting is an effective treatment process to realize sludge land application. However, nitrogen loss could result in the
reduction of nutrient value of the compost products and the stabilization effect of composting on heavy metal concentration
and mobility in sludge has been shown to be very limited.
Materials and methods Laboratory-scale experiments were carried out to investigate the effects of bamboo charcoal (BC) on nitrogen conservation
and mobility of Cu and Zn during sludge composting.
Results The result indicated that the incorporation of BC into the sludge composting material could significantly reduce nitrogen
loss. With 9% BC amendment, total nitrogen loss at the end of composting decreased 64.1% compared with no BC amendment (control
treatment). Mobility of Cu and Zn in the sludge may also have been lessened, based on the decline in diethylenetriaminepentaacetic
acid-extractable Cu and Zn contents of composted sludge by 44.4% and 19.3%, respectively, compared to metal extractability
in the original material.
Discussion Ammonia adsorption capability of BC might be the main reason for the retention of nitrogen in sludge composting materials.
Decrease of extractable Cu2+ and Zn2+ in the composting material mainly resulted from the adsorption of both metals by BC.
Conclusions Incorporation of BC into composting material could significantly lessen the total nitrogen loss during sludge composting.
Mobility of heavy metals in the sludge composting material could also be reduced by the addition of BC.
Recommendations and perspectives Bamboo charcoal could be an effective amendment for nitrogen conservation and heavy metal stabilization in sludge composts.
Further research into the effect of BC-amended sludge compost material on soil properties, bioavailability of heavy metals,
and nutrient turnover in soil needs to be carried out prior to the application of BC-sludge compost in agriculture. 相似文献
660.