Cause analysis of the fire and explosion during crude oil desulfurization in China

A serious fire and explosion accident that resulted in massive crude oil leakage and severe environmental pollution occurred on 16 July, 2010, in Dalian Port, China. To investigate the root cause of accident and conduct a wide-range investigation, desulfurizing agent JH02, which has a similar ingredient to the desulfurizing agent HD used in Dalian Port, and TS02 were employed in this study to determine the role of desulfurizing agents in the accident. The thermal behavior of crude oil, desulfurizing agents, and their mixtures was measured by using a C80 calorimeter. By using the calorimetric data, the kinetic parameters of the chemical reaction, such as activation energy, pre-exponential factor, and self-accelerating decomposition temperature of crude oil, as well as JH02, TS02, and their mixtures, were calculated and compared. The results indicated that the direct cause of the accident was the thermal runaway initiated by the increasing instability of the crude oil–desulfurizing agent mixture. Excess pressure in the oil pipeline triggered the physical explosion, but it alone was not enough to cause a serious damage. Furthermore, a stable desulfurizing agent such as TS02 could not ensure a safe desulfurizing process. The results of this study would benefit the safety management of desulfurizing processes during production and storage.     

声波助清灰技术在滤筒除尘器中的应用研究

在试验的基础上，分析了声波助清灰技术对除尘效率的影响，并对各种清灰方式单独或组合使用的效果进行比较，最后对下一步的研究提出了一些建议。     

Fate of Chlorothalonil, Chlorpyrifos and Profenofos in a Vegetable Farm in cameron Highlands, Malaysia

The fate of chlorothalonil, chlorpyrifos and profenofos in sandy loam soil under tropical condition was studied in a vegetable plot in the Cameron Highlands, Malaysia. The plot was treated with chlorothalonil, chlorpyrifos and profenofos according to normal agricultural practices of the Cameron Highlands. Water (runoff and lysimeter), soil and bedload sediment samples were taken according to a sampling schedule. Residues in water, soil and bedload sediment samples were laboratory analysed to determine amount. Chlorothalonil residues were detected in the range of < 0.01–0.08 mg/kg in the soil, < 0.01–0.02 ng/mL in the leachate, < 0.01–0.02 ng/mL in the runoff and < 0.01–0.11mg/kg in the sediment. Field studies of chlorpyrifos showed residue levels of < 0.01–0.06 mg/kg in the soil, < 0.01–0.07 ng/mL in the leachate, < 0.01–0.08 ng/mL in the runoff and < 0.01–0.62 mg/kg in the sediment. Residue levels of profenofos were detected in the range of < 0.01–0.02 mg/kg in the soil, < 0.01–0.87 ng/mL in the leachate, < 0.01–0.08 ng/mL in the runoff and < 0.01–0.35 mg/kg in the sediment. The three pesticides dissipated rapidly, with DT50 (time for 50% loss) of less than two days. The study showed that these pesticides dissipated rapidly under the climatic conditions of the Cameron Highlands in Malaysia.     

Removal of batteries from solid waste using trommel separation

This paper describes the design and testing of a trommel for separation of batteries from solid waste. A trommel is a cylindrical separation device that rotates and performs size separation. It has also been used in areas such as municipal solid waste (MSW) processing, classifying construction and demolition debris, screening mass-burn incinerator ash and compost processing. A trommel has been designed based on size separation to separate household batteries from solid waste, which can then be used as feedstock for alternative applications of solid waste combustion, particularly where the metal content of the product is also a critical parameter, such as the Co-Co process for integrated cement and power production. This trommel has been tested with batches of university office and restaurant wastes against various factors. The recovery efficiency of batteries increases with decreasing inclination angle of the trommel and decreasing rotational speed. A physical characterization of the university solid waste has been performed with a 20-kg sample of the tested waste. It was found that there is a trend of decreasing recovery of batteries with increasing paper composition, and a trend of increasing recovery of batteries with increasing organic materials composition.     

石油钻井过程硫化氢污染和化学控制技术的研究与发展

根据硫化学的基础理论,分析和探讨了石油钻井过程硫化氢污染产生原因和化学控制原理,评述了硫化氢化学控制技术的研究与发展状况     

浙江省洪水成因初探

根据大量洪水和有关资料,从太阳活动、行星运行和地球系统等方面,分析了形成浙江洪水的物理因素,为洪水预测提供了一定的理论依据．     

环境规划中的非线性特征

 在实际环境规划中,很少考虑到非线性特征对环境投入的效益影响.以国内外目前主要3类水环境规划为例,研究了环境投入与环境改善之间的关系.对每一类环境规划,环境改善均随投入的增加而迅速减少.由于传统的环境管理或规划在选择下一种措施之前总是将大部分费用投入到前一种措施中,因此传统的环境管理或规划忽略了环境系统有关的非线性特征.应将有关费用投入以保证下一步措施获得最大的环境改善.与传统的环境管理或规划相比,这种考虑环境系统有关非线性特征影响的投入策略可以达到用较少的经费获得迅速的环境改善.     

兼氧—AB活性污泥法处理屠宰废水的工程性试验研究＊

本文报导了用兼氧—AB法处理内江肉联厂屠宰废水(2000m~3/d)的工艺流程、运行中的微生物学机理和处理效果。该工艺能更有效地发挥兼氧微生物和AB两级好氧微生物净化有机污染物的能力,处理后的废水完全达到《GB8978—88》污水综合排放标准的要求。     

TiO2-assisted photo-catalysis degradation process of dye chemicals

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关于职称评聘制度改革的几点思考

本文论述了现行职称评聘制度存在的主要问题。指出了深化职称评聘制度改革的必要 性,提出了深化职称评聘制度改革的几点思考。