我国典型城市PM_(2.5)空间分布均匀性分析

随着空气质量新标准的实施,从2013年开始我国部分城市先期开展了PM2.5的例行监测,从中选取不同区域的典型城市,分析了PM2.5在环境中的分布情况。分析结果表明:典型城市PM2.5日均值相对标准偏差(RSD)范围为13%~26%,平均值为18%;我国南方城市PM2.5空间分布均匀性优于北方城市,北方城市冬、春季节PM2.5分布的均匀性较差,南方城市夏季PM2.5分布的均匀性较差;PM2.5的空间分布均匀程度与PM10接近,但明显优于其他气态污染物。综合分析认为,目前我国国家监测网内PM2.5监测点位的代表性能够满足城市空气质量监测与评价工作需要。     

MBR中水力条件对五孔中空纤维膜污染的研究

为了对五孔中空纤维膜在分置式膜生物反应器(MBR)处理模拟印染废水中膜污染特性进行研究,提出从水力学角度考察膜污染特性。在曝气强度分别为25,50,75,100 L/h,出水通量分别为9,12,15,18 L/(m2·h)的工况下考察膜污染表征系数跨膜压差(TMP)的变化情况。得出如下结论:出水通量稳定时,在一定范围内曝气强度的增加可使TMP的增长率降低,即延长膜稳定运行时间,有效缓解膜污染;在次临界通量下曝气量恒定时,出水通量越小,TMP的增长率越小,即膜的稳定运行时间越长。此实验结果对MBR中膜污染的有效控制和水力条件优化提供数据依据。     

Enhanced CO2 adsorptive performance of PEI/SBA-15 adsorbent using phosphate ester based surfactants as additives

In this study,a series of polyetherimide/SBA-15: 2-D hexagonal P6 mm,Santa Barbara USA(PEI/SBA-15) adsorbents modified by phosphoric ester based surfactants(including tri(2-ethylhexyl)phosphate(TEP),bis(2-ethylhexyl) phosphate(BEP) and trimethyl phosphonoacetate(TMPA))were prepared for CO_2 adsorption.Experimental results indicated that the addition of TEP and BEP had positive effects on CO_2 adsorption capacity over PEI/SBA-15.In particular,the CO_2 adsorption amount could be improved by around 20% for 45PEI–5TEP/SBA-15 compared to the additive-free adsorbent.This could be attributed to the decrease of CO_2 diffusion resistance in the PEI bulk network due to the interactions between TEP and loaded PEI molecules,which was further confirmed by adsorption kinetics results.In addition,it was also found that the cyclic performance of the TEP-modified adsorbent was better than the surfactant-free one.This could be due to two main reasons,based on the results of in situ DRIFT and TG-DSC tests.First and more importantly,adsorbed CO_2 species could be desorbed more rapidly over TEP-modified adsorbent during the thermal desorption process.Furthermore,the enhanced thermal stability after TEP addition ensured lower degradation of amine groups during adsorption/desorption cycles.     

加热方式对垃圾热解过程中HCl析出特性影响的实验研究

在自行设计的小型外热式固定床试验台上，以垃圾中广泛存在的PVC为原料，通过改变加热方式、热解终温等参数。重点研究了快，慢两种加热方式下垃圾热解过程中HCl的析出特性，并从理论上进行了初步探讨。     

事故出流时河流综合水质的计算机预测方法研究

河流上游的污水排放口或倒虹管等污水构筑因有可能发生事故出流而对下游的取水口存在着潜在的威胁，常规的单参数模型不能就事故出流对下游的影响作出公正评价。本文以QUAL－Ⅱ模型为骨架，以生动形象的动画形式演示出在整个排污过程中多个水质参数沿河道分布的变化全过程，并且，在模型中融入隶属度BP神经网络综合评价水质的模块，用它来对发生事故出流时下游取水口水域的水质变化进行综合评价，最后通过一个例子说明了该方法的优越性和合理性。     

显像管玻壳铅尘污染特性的研究

以石家庄市显像管玻壳厂排放的铅尘为研究对象，通过在该玻壳厂周围土壤布点采样，较系统地研究了铅尘在大气和周围土壤中的迁移和转化规律，研究表明，用高斯模式能成功地预测铅尘在大气中的迁移扩散规律，玻壳厂周围土壤表层铅含量较大值出现在当地年主导风向（SSE，N）下风向，铅在土壤中的分布主要集中在0－20cm的耕作层，在20－40cm深度范围内，铅含量呈下降趋势，最大降幅达50％。     

云南白秧坪多金属成矿区构造特征及其控矿作用

通过区域地质构造、矿区构造特征分析 ,论述了云南白秧坪多金属成矿区东矿带、西矿带的主要地质构造特征及其构造控矿作用 ,并探讨了区域构造导矿与成矿及其对成矿带的控制作用、小型褶皱及推覆构造对矿床的控制作用、次级断裂对矿体的控制作用、构造环境下岩石的屏蔽与容矿作用和构造环境中碳质来源及其成矿作用等问题     

Management of process performance at low water temperatures in respect of filamentous organisms

The management of sludge-settling properties in Nordic conditions is of importance during the low temperature (spring) season because of the peak settler load. A survey was made in 10 Finnish waste water treatment plants(WWTP‘ s) and the total extended filament length and DSVI in haft of the plants exceeded the limits, which indicates sludge bulking( 15 km/g SS and 150 ml/g respectively). The dominant organism was Microthrix parvicella, the abundance of which was 59.22% of total extended filament length on average.Chemicals were tested to control the filaments, and it was found that special attention has to be paid to maintaining the nitrification at low temperature. A dosage of(H2O2-besed) oxidants controlled the growth of Microthrix parvicella effectively and rapidly, whereas with the use of aluminium hydroxidechloride a 2 to 5-week period was needed to decrease the filament length.     

Emission control for precursors causing acid rain (V): Improvement of acid soil with the bio-briquette combustion ash

The bio-briquette technique which mixes coal, biomass and sulfur fixation agent and bio-briquettes under 3-5 t/cm^2 line pressure has aroused people‘s attention in view of controlling the air pollution and the acid rain. In this paper, the physicochemical properties of bio-briquette and its ash were investigated. And the acid soil was improved by the bio-briquette combustion ash, which contained nutritive substances such as P, N, K and had the acid-neutralizing capacity(ANC). The pH, EC, effective nutrient elements(Ca, Mg, K, P and N), heavy metal elements(AI, Cu, Cd, Cr, Zn and Mn) and acid-neutralizing capacity change of ash-added soils within the range of 0-10%, were also studied. Specially, when 5% bio-briquette combustion ash was added to the tested soil, the content of the effective elements such as Ca, Mg and K rose by 100 times, ? times and twice, respectively. The total nitrogen also increased by about twice. The results showed the oxyanions such as that of AI, Cu, Cd, Cr, Zn and Mn were not potentially dangerous, because they were about the same as the averages of them in Chinese soil. It is shown that the ANC became stronger, though the ANC hardly increases in the ash-added soil. On the basis of the evaluation indices, it is concluded that the best mixture ratio is to add 2.5%--8% of the bio-briquette combustion ash to the tested soil.     

Scenario simulation of water security in China

Umited water resources, increasing demand, low use efficiency, and serious pollution result in severe water resource difficult in China. The evaluation of addressing water problems and the search for effective countermeasures that ensure sustainable water use are key to China‘ s sustainable development. The “compound water security“ consists of food security, life security, environmental security, and economic security. By establishing a conceptual model, the water security of China has been simulated in terms of four scenarios called BAU(the business-as-usual scenario), TEC(the technology and economics scenario), IVL(the institution, values, and lifestyles scenario) and TSD(toward sustainable development) in this paper. The results indicated that water crises, especially water shortages, are being experienced now and will continue to do so for a relatively long time in China and that it is possible to reach a basic balance between supply and demand of water and grain under the TSD developing pattern by a series of approaches including technological innovation, policy adjustments, and behaviour inducement.