农药污染对蚯蚓的群落结构与超微结构影响的研究

报道了农药污染对蚯蚓的群落结构与超微结构影响的研究,结果表明：随着农药污染程度增加,蚯蚓的种类和数量则减少。超微结构在扫描电镜下可观察到重污染区壮伟环毛蚓（Pheretimarobusta）胃粘膜出现溃疡灶,并产生穿孔现象;在中污染区只有微绒毛萎缩病变;在重污染区发现肠粘膜上的纤毛发生紊乱及萎缩,纤毛顶端膨大呈球形。对精子观察可见在中污染区就出现了畸形精子。在透射电镜下观察可见重污染区壮伟环毛蚓胃肠道粘膜上皮细胞中的粗面内质网（RER）出现扩张,高尔基复合体也产生扩张状,线粒体发生肿胀,线粒体嵴消失呈空泡状。另可见细胞核膜间隙扩张、断裂,核染色质边集或减少,胞质呈大片空白。蚯蚓以上病变指标均能很灵敏反映土壤农药污染程度。     

Amoxicillin effects on functional microbial community and spread of antibiotic resistance genes in amoxicillin manufacture wastewater treatment system

This study aimed to reveal how amoxicillin(AMX) affected the microbial community and the spread mechanism of antibiotic resistance genes(ARGs) in the AMX manufacture wastewater treatment system. For this purpose, a 1.47 L expanded granular sludge bed(EGSB) reactor was designed and run for 241 days treating artificial AMX manufacture wastewater. 454 pyrosequencing was applied to analyze functional microorganisms in the system. The antibiotic genes OXA_(-1), OXA_(-2), OXA_(-10), TEM_(-1), CTX-M_(-1), class I integrons(intI1) and 16 SrRNA genes were also examined in sludge samples. The results showed that the genera Ignavibacterium, Phocoenobacter,Spirochaeta, Aminobacterium and Cloacibacillus contributed to the degradation of different organic compounds(such as various sugars and amines). And the relative quantification of eachβ-lactam resistance gene in the study was changed with the increasing of AMX concentration.Furthermore the vertical gene transfer was the main driver for the spread of ARGs rather than horizontal transfer pathways in the system.     

国产十种合成洗衣粉诱发华西大蟾蜍(Bufo bufo andrewsi)蝌蚪红细胞微核的研究

研究了国产10种洗衣粉对华西大蟾蜍(Bufo bufo andrewsi)蝌蚪红细胞微核的诱变,结果表明“活力28超浓缩无泡加香”洗衣粉,“TM”及“SD”洗衣粉(1.2,6.0及12.0ppm)诱发蝌蚪微核率增高。在我们实验条件下,另外7种合成洗衣粉中的5种在12.0ppm浓度组也引起微核率升高。     

Regionalization based on spatial and seasonal variation in ground-level ozone concentrations across China

Owing to the vast territory of China and strong regional characteristic of ozone pollution,it's desirable for policy makers to have a targeted and prioritized regulation and ozone pollution control strategy in China based on scientific evidences. It's important to assess its current pollution status as well as spatial and temporal variation patterns across China.Recent advances of national monitoring networks provide an opportunity to insight the actions of ozone pollution. Here, we present rotated empirical orthogonal function(REOF)analysis that was used on studying the spatiotemporal characteristics of daily ozone concentrations. Based on results of REOF analysis in pollution seasons for 3 years' observations, twelve regions with clear patterns were identified in China. The patterns of temporal variation of ozone in each region were separated well and different from each other, reflecting local meteorological, photochemical or pollution features. A rising trend in annual averaged Eight-hour Average Ozone Concentrations(O_3-8 hr) from 2014 to 2016 was observed for all regions, except for the Tibetan Plateau. The mean values of annual and 90 percentile concentrations for all 338 cities were 82.6 ± 14.6 and 133.9 ± 25.8 μg/m~3,respectively, in 2015. The regionalization results of ozone were found to be influenced greatly by terrain features, indicating significant terrain and landform effects on ozone spatial correlations. Among 12 regions, North China Plain, Huanghuai Plain, Central Yangtze River Plain, Pearl River Delta and Sichuan Basin were realized as priority regions for mitigation strategies, due to their higher ozone concentrations and dense population.     

PW_(12)/g-C_3N_4光催化降解甲基橙

采用浸渍法制备了磷钨酸(PW12)/g-C3N4复合光催化剂,并将其用于溶液中甲基橙的光催化降解,运用IR技术对使用前后的光催化剂进行了表征。表征结果显示,PW12和g-C3N4的结构未在浸渍负载中发生改变,且PW12和g-C3N4结合牢固。实验结果表明:最佳的PW12负载量(光催化剂中PW12的质量分数)为50%;光催化降解甲基橙的优化反应条件为初始甲基橙质量浓度5 mg/L、光催化剂加入量0.6 g/L、初始溶液p H=7;在优化条件下,分别采用紫外光、模拟太阳光、可见光照射120 min后,甲基橙的降解率分别为96.59%,82.23%,42.78%;该光催化剂固载良好,使用中不易发生溶脱,稳定性好,可重复使用。     

一种改进的边界层参数化模式

在能量平衡方法的基础上提出一套利用常规气象资料求取边界层参数的改进方案。利用中国科学院大气物理研究所铁塔观测资料,与廓线法进行对比分析,表明这种方案具有输入要求少,输出信息量大,结果合理的优点。此外,对此方案中的4个可变参数作了敏感性试验,结果表明湿度变化参数α的敏感性较强,在使用时应当合理选择其数值。该方案可以满足新一代空气质量模式对边界层参数化的需求。同时,由于仅需常规气象资料就能求取所有的边界层参数,因此特别适合于空气质量模式的法规应用。     

风雨联合作用下风向对大跨度悬挑屋盖的压力分布影响研究

强降雨通常伴有强风作用,风向成为影响结构表面压力分布的重要因素之一。目前大跨度挑檐屋盖设计基本只考虑垂直于结构表面的单独雨荷载作用,对风雨联合作用下建筑表面压力分布研究甚少。研究风雨联合作用下,不同风向对大跨度悬挑屋盖表面的压力分布影响特性。基于数值模拟平台,采用欧拉-欧拉方法,模拟得到了不同风向工况下大跨度悬挑屋盖结构表面平均压力分布规律,并研究得到了一次自然降雨过程中最不利抗风雨位置,对相应大跨度悬挑结构设计提出了有益参考。     

Size distributions of aerosol and water-soluble ions in Nanjing during a crop residual burning event

To investigate the impact on urban air pollution by crop residual burning outside Nanjing, aerosol concentration, pollution gas concentration, mass concentration, and water-soluble ion size distribution were observed during one event of November 4-9, 2010. Results show that the size distribution of aerosol concentration is bimodal on pollution days and normal days, with peak values at 60-70 and 200-300 nm, respectively. Aerosol concentration is 10⁴ cm^-3. nm^-1 on pollution days. The peak value of spectrum distribution of aerosol concentration on pollution days is 1.5-3.3 times higher than that on a normal day. Crop residual burning has a great impact on the concentration of fine particles. Diurnal variation of aerosol concentration is trimodal on pollution days and normal days, with peak values at 03:00, 09:00 and 19:00 local standard time. The first peak is impacted by meteorological elements, while the second and third peaks are due to human activities, such as rush hour traffic. Crop residual burning has the greatest impact on SO₂ concentration, followed by NO₂, O₃ is hardly affected. The impact of crop residual burning on fine particles (< 2.1 μm) is larger than on coarse particles (> 2.1 μm), thus ion concentration in fine particles is higher than that in coarse particles. Crop residual burning leads to similar increase in all ion components, thus it has a small impact on the water-soluble ions order. Crop residual burning has a strong impact on the size distribution of K⁺, Cl^-, Na⁺, and F^- and has a weak impact on the size distributions of NH₄⁺, Ca²⁺, NO₃^- and SO₄^2-.     

Status of air pollution in Beijing

A study has been made on elements organic constituents, TSP, SO2,NO2 of atmospheric pollutants in Beijing. 17 elements, and some PAHs, e. g. B(a)P, B(b, j, k)P, and B(g, h, i)P, in airborne particles by X-ray fluorescence spectroscopy and HPLC, GC/MS, have been determined respectively. It has been shown that the elements Pb, Zn, S and Cu were more enriched in fine particles and different valence states of sulfur at various sites. It was found that the concentrations of S6+ and S2-were more than 85% and less than 15% of the total sulfur respectively. Concentrations of major PAHs and sulfur-containing compounds increased in winter and in urban area. High values for Pb and Zn in city, Fe and Mn at industrial area and Cu, Al rural sites were obtained respectively. This implies the functions of different elemental sources of various sites. Thus, elements can be from distingushed anthropogenic and natural sources.The main contribution of SO2 was found of to have same seasonal variation as the anthropogenic el     

新烟碱类农药的污染现状及转化行为研究进展

新烟碱类(neonicotinoids)农药自在20世纪80年代中期引入以来,便发展成为世界上使用最广泛的一类杀虫剂。近年来,该类化合物在环境中被不断检出,并通过饮用水和食物等方式进入食物链,给人类健康带来极大的安全隐患。文章综述了新烟碱类杀虫剂在空气、土壤、水相、生物体和人体中的暴露浓度,以及这类农药在环境中的转化行为。目前针对新烟碱类杀虫剂的环境暴露研究仍十分有限,需要更全面调查其在多环境介质中的暴露状况以综合评价其生态风险。关于新烟碱类化合物的毒理学研究主要集中在急性毒性试验,而对于其他形式的毒性效应有待进一步研究。最后对新烟碱农药未来的研究重点和方向提出了展望。