Highly selective capture of phosphate ions from water by a water stable metal-organic framework modified with polyethyleneimine

Environmental Science and Pollution Research - In this work, a series of polyethyleneimine (PEI) impregnated metal-organic framework (UiO-66) with varying PEI loadings were prepared and applied as...     

基于大数据技术的硫黄回收装置尾气SO2达标优化方法研究

运用大数据技术,对硫黄回收装置的工艺运行参数数据及SO_2排放数据进行挖掘与分析,提取与SO_2排放浓度强相关的关键性操作变量,完成硫黄回收装置环保大数据建模,从而实现硫黄回收装置SO_2排放浓度的预测和预警,并自动生成当前工况下硫黄回收装置尾气SO_2达标优化方案。     

我国安全生产的形势和任务

论述了我国安全生产工作发展概况与安全的关系 ,分析了我国安全生产状况 ;指出了我国安全生产面临的主要难点 ;提出了我国安全生产工作的重任所在 ;笔者认为 ,只要从实际出发 ,坚持改革、标本兼治和技术创新 ,发挥政府、企业、劳动者三方协调机制的作用 ,借鉴和吸收国际成功经验 ,我国安全生产水平是会列于世界先进行列的。     

Effect of ozone injection on the long-term performance and microbial community structure of a VOCs biofilter

For biofilters treating waste gases containing volatile organic compounds(VOCs), biomass accumulation is a common problem which will induce bed clogging and significant decrease in VOCs removal efficiency during long-term operation. In this study, ozone injection was developed as a biomass control strategy, and its effects on the biofilter performance and the microbial community structure were investigated in long-term operation. Two biofilters,identified as BF1 and BF2, were operated continuously for 160 days treating gaseous toluene under the same conditions, except that 200 mg/m3 ozone was continuously injected into BF1 during days 45–160. During the operation period, ozone injection did not change the toluene removal efficiency, while the pressure drop of BF1 with ozone injection was significantly lowered compared with BF2. The wet biomass accumulation rate of BF1 was 11 g/m~3/hr, which was only46% of that in BF2. According to the carbon balance result, ozone injection also increased the toluene mineralization rate from 83% to 91%, which could be an important reason for the low biomass accumulation. The PMA-q PCR result indicated that ozone injection increased the microbial viability of the biofilm. The high-throughput sequencing result also revealed that the dominant phyla and genera were not changed significantly by ozone injection, but some ozonetolerant genera such as Rhodanobacter, Dokdonella and Rhodococcus were enhanced by ozone exposure. All the results verified that ozone injection is capable of sustaining the long-term performance of biofilters by lowering the biomass accumulation, increasing the microbial viability and changing the microbial community structure.     

酸碱-微波耦合预处理对污泥胞外聚合物溶裂与产甲烷行为的影响

对酸碱-微波耦合预处理后不同EPS组分在污泥厌氧消化行为中扮演的角色进行研究，通过产甲烷潜能实验评价其甲烷转化性能。结果表明:酸碱-微波耦合预处理通过溶出胞内有机物和改变EPS的分布来影响污泥产甲烷行为。甲烷累积产量最优预处理条件为pH=10，微波500 W，预处理时间120 s。此时，预处理后溶解型胞外聚合物（S-EPS）中的溶解性化学需氧量（SCOD）浓度达到11460 mg/L，是对照组浓度的184.5%，累积甲烷产量为89.08 mL/g，较对照组增加59.9%。碱处理（pH=10和12）时，S-EPS对累积甲烷产量的贡献率分别达到了16.6%和30.4%，远高于松散结合型胞外聚合物（LB-EPS）与紧密结合型胞外聚合物（TB-EPS）。在48 d的厌氧消化过程中，S-EPS对产甲烷的贡献率在1~4 d内快速升高，随后缓慢持续下降。因此，酸碱-微波耦合预处理通过强化污泥S-EPS中的多糖、蛋白质等有机质的溶出，促进污泥甲烷化。     

多元信息综合的市县国土空间规划空间功能识别方法

空间功能识别是确定国土空间规划空间开发保护格局的关键环节,理论和实践意义重大。基于土地利用和地表覆盖现状、精细化DEM、地形单元等基础地理信息,水、生态、环境、灾害等专题数据,社会统计数据等多元信息,利用空间分析、多元统计、计量模型、基于规则的分类模型等技术方法,从多元信息综合集成和自动分类识别的角度,研究构建了一套市县国土空间规划空间主导功能识别的关键技术与方法,并对榆林市域进行空间功能分区。研究表明：本文方法有效将地理实体单元、功能评价指标综合于统一的地域单元,保证了空间功能分类识别的准确性;通过自动分类算法建模,实现空间功能识别的自动化,提高了国土空间规划的客观性和工作效率。     

生石灰孔结构对高温脱硫性能的影响

喷钙脱硫工艺的炉内脱硫率 ,不仅受工艺参数的影响 ,还与石灰石分解生成的新生CaO或直接喷入的CaO的表面结构有关。本研究用同一石灰石经不同方法 (煅烧、过烧、煅烧 -水合 -脱水等 )制备了四种具有不同比表面积和孔结构的生石灰。高温脱硫研究表明 :这四种不同孔结构的生石灰 ,具有不同的脱硫率。通过对高温脱硫前后吸着剂宏观结构变化的对比 ,发现半径小于 30 的孔易被反应产物堵塞 ,因而脱硫能力有限 ,而半径大于 5 0 的孔对脱硫更有效。本研究将为提高炉内喷钙的脱硫率、研制和开发高效脱硫剂提供新的途径。     

世界旅游精品建设目标下的张家界旅游环境管理对策研究

建设世界旅游精品是张家界制定的旅游业发展的战略目标，一流的旅游环境条件是实现这一目标的必备条件。然而，张家界目前的旅游环境与世界旅游精品存在差距，环境管理中存在基础性工作、基础性研究比较薄弱、制度不够健全等方面的问题，影响了环境管理效率。在分析研究张家界环境管理中存在问题的基础上，针对性地提出保护、改善环境的对策，是实现世界旅游精品战略目标的基础工作。