Distribution,source, and environmental risk assessment of phthalate esters (PAEs) in water,suspended particulate matter,and sediment of a typical Yangtze River Delta City,China

Phthalates (PAEs) in drinking water sources such as the Yangtze River in developing countries had aroused widespread concern. Here, the water, suspended particulate matter (SPM), and sediment samples were collected from 15 sites in wet and dry seasons in Zhenjiang, for the determination of six PAEs (DMP, DEP, DIBP, DBP, DEHP, and DOP) using the solid-phase extraction (SPE) or ultrasonic extraction coupled with gas chromatography-mass spectrometry (GC-MS). The total concentrations of six PAEs (Σ₆PAEs) spanned a range of 2.65–39.31 μg L^?1 in water, 1.97–34.10 μg g^?1 in SPM, and 0.93–34.70 μg g^?1 in sediment. The partition coefficients (K_d1) of PAEs in water and SPM phase ranged from 0.004 to 3.36 L g^?1 in the wet season and from 0.12 to 2.84 L g^?1 in the dry season. K_d2 of PAEs in water and sediment phase was 0.001–9.75 L g^?1 in the wet season and 0.006–8.05 L g^?1 in the dry season. The dominant PAEs were DIBP, DBP, and DEHP in water and SPM, DIBP, DEHP, and DOP in sediment. The concentration of DBP in water exceeded the China Surface Water Standard. The discharge of domestic sewage and industrial wastewater might be the main potential sources of PAEs. The risk quotient (RQ) method used for the risk assessment revealed that DBP (0.01 < RQ < 1) posed a medium risk, while DIBP and DEHP (RQ > 1) posed a high environmental risk in water, DIBP (RQ > 1) also showed a high risk in sediment.

     

以膨润土为辅助添加剂固化/稳定化污泥的试验研究

针对传统以水泥固化污泥,带来的水泥用量大与固化体的浸出液pH过高等问题,提出了以膨润土为添加剂辅助水泥固化/稳定化污泥的思路.通过开展无侧限抗压强度试验、毒性浸出试验,测量掺入膨润土后污泥固化体的强度、重金属浸出率、浸出液COD及pH值,研究该固化/稳定化方法的效果.结果表明,膨润土的掺入极大地提高了固化体的抗压强度,将掺入量为0.4(相对污泥的质量比)的水泥一半用膨润土替代时,固化体的强度提高了6左右.体积安定性也能够满足要求.随膨润土掺入量增加,固化体中锌、铅的浸出率与浸出液的pH值呈现不断减小的趋势,锌与铅的浸出率分别由6.9%下降至0.25%,9.6%下降至5%,pH值由12.3下降至12.1.在强碱条件下及烘干或风干条件下,铜会随着有机物的分解而析出,从而增加铜的浸出率,而膨润土的加入能弥补水泥造成的强碱环境及风干或烘干过程对固化污泥中铜的稳定产生的不利影响.     

长江集装箱港口岸线利用空间格局及其对资源环境的影响

长江岸线资源是沿江地区社会经济发展的重要支撑,同时其处于水陆交界地带有着无法替代的生态价值.通过遥感影像解译和相关数据资料汇总分析现代化航运组成之一的集装箱港口岸线利用格局,探究其对生态保护岸段的影响及成因,讨论如何合理组织港口岸线以实现绿色发展.长江集装箱港口岸线规模研究时段内大幅提升,上中下游分别形成各自较为密集的分布区域,集装箱港口更替以小型减量为主并将增量重心向大中型倾斜;港口岸线利用持续增长加速对保护岸段侵占,中小型港口为最主要占用类型,部分既有港口因所在城市大部分可利用岸段位于保护区内而留存;集装箱港口开发利用与保护间关系演变存在阶段性,岸线资源管理缺乏统筹协调,两者间冲突不可避免并已大量发生,但研究时段内港口扩张逐渐放缓、矛盾出现缓和,今后需更细致进行港口开发与岸线保护工作,提升综合管理能力.     

Aging and compressibility of municipal solid wastes

The expansion of a municipal solid waste (MSW) landfill requires the ability to predict settlement behavior of the existing landfill. The practice of using a single compressibility value when performing a settlement analysis may lead to inaccurate predictions. This paper gives consideration to changes in the mechanical compressibility of MSW as a function of the fill age of MSW as well as the embedding depth of MSW. Borehole samples representative of various fill ages were obtained from five boreholes drilled to the bottom of the Qizhishan landfill in Suzhou, China. Thirty-one borehole samples were used to perform confined compression tests. Waste composition and volume-mass properties (i.e., unit weight, void ratio, and water content) were measured on all the samples. The test results showed that the compressible components of the MSW (i.e., organics, plastics, paper, wood and textiles) decreased with an increase in the fill age. The in situ void ratio of the MSW was shown to decrease with depth into the landfill. The compression index, Cc, was observed to decrease from 1.0 to 0.3 with depth into the landfill. Settlement analyses were performed on the existing landfill, demonstrating that the variation of MSW compressibility with fill age or depth should be taken into account in the settlement prediction.     

可变模糊评价法在洪涝灾情评价中的应用

灾情评价实质上是一个模式识别问题.以往的灾情评价模型,虽解决了各单项指标灾情等级评估结果的不相容问题,但往往不能检验所给结果的准确性.基于可变模糊集理论,采用可变模糊评价模型可以科学、合理地确定样本指标对各级指标标准区间的相对隶属度和相对隶属函数,并且能够通过变换参数(α与P)变化模型进行评价.通过对多个评价结果进行比较分析,可以合理地确定出样本的评价等级.同时,由于该模型确定的灾级是连续的实数值,因而提高了灾情等级评价的灾级分辨率.最后将该方法应用于河南省洪涝灾情的综合评价中.应用实例表明,该模型计算简便,评价结果可信度高,可推广应用到其它灾情等级评估中.     

中国自然保护区可持续管理模式探讨——伦敦自然保护区管理模式借鉴

近年来,世界各地自然保护区迅速发展,如何有效持续地管理这些自然保护区成为一个重要的问题。文章分析了我国自然保护区现有管理模式的特点与存在的问题,简要介绍了伦敦自然保护区的管理模式现状,根据我国的实际情况,笔者认为中国的自然保护区应采用强制式和完全参与合作式相结合的管理模式,并提出了几点管理模式的改革建议。     

A mini review of fluoride-induced apoptotic pathways

Fluorine or fluoride can have toxic effects on bone tissue and soft tissue at high concentrations. These negative effects include but not limited to cytotoxicity, immunotoxicity, blood toxicity, and oxidative damage. Apoptosis plays an important role in fluoride-induced toxicity of kidney, liver, spleen, thymus, bursa of Fabricius, cecal tonsil, and cultured cells. Here, apoptosis activated by high level of fluoride has been systematically reviewed, focusing on three pathways: mitochondrion-mediated, endoplasmic reticulum (ER) stress-mediated, and death receptor-mediated pathways. However, very limited reports are focused on the death receptor-mediated apoptosis pathways in the fluoride-induced apoptosis. Therefore, understanding and discovery of more pathways and molecular mechanisms of fluoride-induced apoptosis may contribute to designing measures for preventing fluoride toxicity.     

CO2 emission driving forces and corresponding mitigation strategies under low-carbon economy mode: evidence from China’s Beijing–Tianjin–Hebei region

On account of the background of China’s “new normal” characterized by slower economic growth, this paper analyses the low-carbon economy status quo in the Beijing–Tianjin–Hebei region and empirically investigates the relationship between carbon dioxide (CO₂) emissions and its various factors for China’s Beijing–Tianjin–Hebei region using panel data econometric technique. We find evidence of existence of Environmental Kuznets Curve. Results also show that economic scale, industrial structure, and urbanization rate are crucial factors to promote CO₂ emissions. However, technological progress, especially the domestic independent research and development, plays a key role in CO₂ emissions abatement. Next, we further analyze the correlation between each subregion and various factors according to Grey Relation Analysis. Thereby, our findings provide important implications for policymakers in air pollution control and CO₂ emissions reduction for this region.     

Optimum ridge-to-furrow ratio in ridge-furrow mulching systems for improving water conservation in maize (Zea may L.) production

Environmental Science and Pollution Research - Water-saving cultivation techniques have been attracting increased attention worldwide. Ridge-furrow mulching system (RFMS), as a prospective...