大连市臭氧污染特征及典型污染日成因

通过对大连市区10个空气监测子站的监测数据进行分析,探讨了大连市臭氧污染的时空分布、气象条件对臭氧污染的影响,对臭氧污染日进行了归类分析。结果表明,大连市臭氧污染主要出现在4—10月。在强紫外辐射、高温、低湿、低压和低风速的气象条件下,监测点位的臭氧浓度较高。臭氧污染日的日变化分为单峰型、双峰型和夜间持续升高型3种类型。通过对2015年的一次高浓度臭氧污染过程的气象条件、污染物浓度和污染气团轨迹进行分析,发现臭氧浓度在夜间持续升高现象与区域输送密切相关。     

树状河流突发污染事故源强确定方法研究

源强确定在突发污染事故的预警与应急过程中极为重要。本文针对树状河流的特性,将污染源搜索和源强反算的方法结合起来构建了树状河流突发污染事故源强确定的一般方法,并利于假设的突发污染事故情形对方法就行了评估。结果表明,监测数据的误差对计算结果的影响很大,源强的计算结果相比事故的地点与发生时间更为敏感。     

Dissipation and residue of triforine in strawberry and soil

Two independent field trials were performed in Guangdong and Hubei, China in 2011 to investigate the dissipation and residue levels of triforine in strawberry and soil. A fast and simple method using gas chromatography with electron capture detector was developed and validated to determine triforine levels in strawberry and soil. The average recovery of triforine in strawberry ranged from 87.46 to 104.32 % with a relative standard deviation (RSD) of 0.72 to 4.54 %; that in soil ranged from 83.82 to 103.01 % with an RSD of 3.89 to 4.36 %. The limit of quantification of the proposed method was 0.01 mg/kg for both strawberry and soil. The results suggest that the triforine dissipation curves followed the first-order kinetic. The half-lives of triforine in strawberry from Guangdong and Hubei were 3.58 and 4.42 days, respectively; those in soil were 3.53 and 4.10 days, respectively. The terminal residues of triforine in strawberry ranged from 0.032 to 0.264 mg/kg at preharvest intervals of 0.5, 1, and 3 days. These values are lower than the maximum residue limit of 1 mg/kg in strawberry set by the Codex Alimentarius Commission.     

Spatial and seasonal characteristics of river water chemistry in the Taizi River in Northeast China

Anthropogenic activities have led to water quality deterioration in many parts of the world, especially in Northeast China. The current work investigated the spatiotemporal variations of water quality in the Taizi River by multivariate statistical analysis of data from the 67 sampling sites in the mainstream and major tributaries of the river during dry and rainy seasons. One-way analysis of variance indicated that the 20 measured variables (except pH, 5-day biological oxygen demand, permanganate index, and chloride, orthophosphate, and total phosphorus concentrations) showed significant seasonal (p?≤?0.05) and spatial (p?<?0.05) variations among the mainstream and major tributaries of the river. Hierarchical cluster analysis of data from the different seasons classified the mainstream and tributaries of the river into three clusters, namely, less, moderately, and highly polluted clusters. Factor analysis extracted five factors from data in the different seasons, which accounted for the high percentage of the total variance and reflected the integrated characteristics of water chemistry, organic pollution, phosphorous pollution, denitrification effect, and nitrogen pollution. The results indicate that river pollution in Northeast China was mainly from natural and/or anthropogenic sources, e.g., rainfall, domestic wastewater, agricultural runoff, and industrial discharge.     

Risk assessment of trace elements in cultured freshwater fishes from Jiangxi province,China

The levels of trace elements (As, Cd, Cr, Cu, Fe, Ni, Pb, Se, and Zn) in eight species of cultured freshwater fishes from Jiangxi province were determined by inductively coupled plasma-mass spectroscopy. All the studied trace element levels in fish muscles from Jiangxi province did not exceed Chinese national standard and European Union standard, and they were often lower than previous studies. The calculated target hazard quotient values for all the studied trace elements in fish samples were much less than 1, suggesting that the studied trace elements in fish muscles from Jiangxi province had not pose obvious health hazards to consumers. As and Cd concentrations in northern snakehead were much higher than that in other fishes, demonstrating that this fish species could be valuable as a bioindicator of As and Cd in environmental surveys. In addition, the highest concentrations of Fe, Zn, and moderate contents of other essential trace elements in crucian carp indicated that crucian carp could be a good nutrient source of essential trace elements for human health.     

Effects of pig manure containing copper and zinc on microbial community assessed via phospholipids in soils

Pig manure (PM) is widely used as an organic fertilizer to increase yields of crops. Excessive application of compost containing relatively great concentrations of copper (Cu) and zinc (Zn) can change soil quality. To clarify the effects of different rates of application and to determine the optimal rate of fertilization, PM containing 1,115 mg Cu kg^?1, dry mass (dm) and 1,497 mg Zn kg^?1, dm was applied to alkaline soil at rates of 0, 11, 22, 44, 88, and 222 g PM kg^?1, dm. Phospholipid fatty acids (PLFAs) were used to assess soil microbial community composition. Application of PM resulted in greater concentrations of total nitrogen (TN), NH₄ ⁺-N, NO₃ ^?-N, total carbon (TC), soil organic matter (SOM) but lesser pH values. Soils with application rates of 88–222 g PM kg^?1, dm had concentrations of total and EDTA-extractable Cu and Zn significantly greater than those in soil without PM, and concentrations of T-Cu and T-Zn in these amended soils exceeded maximum limits set by standards in china. Except in the soil with a rate of 11 g PM kg^?1, dm, total bacterial and fungal PLFAs were directly proportional to rate of application of PM. Biomasses of bacteria and fungi were significantly greater in soils with application rates of 44–222 g PM kg^?1, dm than in the soil without PM. SOM, TC and EDTA-Zn had the most direct influence on soil microbial communities. To improve fertility of soils and maintain quality of soil, rate of application should be 22–44 g PM kg^?1 dm, soil containing Cu and Zn.     

Migration of natural estrogens around a concentrated dairy-feeding operation

Concentrated animal feeding operations have been recognized as one of the most important contributors of natural estrogens which show significant endocrine-disrupting properties in aquatic environments. In this study, the concentrations of 17α-estradiol (17α-E2), 17β-estradiol (17β-E2), estrone (E1), and estriol (E3) in several matrices, including soils (surface and deep), sediments (surface and deep), and groundwaters, around a typical dairy farm were surveyed using gas chromatography/mass spectrometry. Of the two farmlands, surface and subsurface sediments in waste lagoon and along effluent drainage drench, the concentrations of 17α-E2, 17β-E2, and E1 ranged from below detection limit to the highest level of 6.60 μg/kg, except that E3 was not detectable. Three estrogens of 17α-E2, 17β-E2, and E1 with the concentrations of 3.18-31.61 ng/L were observed in two groundwater samples. The results clearly demonstrated the vertical migration and horizontal transport of estrogens in the investigated area. Within 750-m distance, it was observed the attenuation of 17α-E2, 17β-E2, and E1 along the effluent route and the horizontal migration of estrogens was less than 1,350 m in this survey.     

Molecular detection of three gastroenteritis viruses in urban surface waters in Beijing and correlation with levels of fecal indicator bacteria

To assess the presence of three gastroenteritis viruses responsible for human acute gastroenteritis in surface water, a 1-year study was carried out in the city of Beijing, China. A total of 108 urban surface water samples were collected from nine collection sites which were defined with a global positioning system in rivers or lakes from September 2006 to August 2007. The water samples were subjected to virus concentration using an HA electronegative filter, followed by polymerase chain reaction (PCR) for rotavirus (RV) astrovirus (AV), and norovirus (NV). It showed that the number of viruses detected in water samples from different sites was variable, totaling 63 virus strains, with rotavirus (48.1%) verified as the most prevalent detected, followed by astrovirus (AV, 5.6%), and norovirus (NV, 4.6%). RV was also quantified by real-time PCR and the concentration of RV ranged from 0 to 18.27 genome copies·L(-1). And the distributions of RV in surface water were abundant in cold weather (from September to February) while less prevailing in warm weather (from March to August). The high detection rate of RV we encountered in this study provided convincing evidence that RV circulated at a certain frequency in the Beijing population. There was no statistically significant correlation between RV levels and both fecal coliform (R (2)?=?0.02) and Enterococcus faecalis (R (2)?=?0.02) densities. Our study suggests prolonged virus persistence in aquatic environments and emphasizes the enteric virus group as the most reliable for environmental monitoring.     

Genotoxicity of the sediments collected from Pearl River in China and their polycyclic aromatic hydrocarbons (PAHs) and heavy metals

The accelerated industrialization and urbanization in the last three decades around the Pearl River Delta within Guangdong Province in China have led to serious concerns about the impacts on the aquatic environment. In the present study, the genotoxicity of the sediments collected from the Pearl River was evaluated by micronucleus (MN) assay with Vicia faba root tip cells, and the 16 EPA priority polycyclic aromatic hydrocarbons (PAHs) and heavy metals (HMs, including Cr, Cu, As, Se, Cd, Hg, and Pb) in the sediments were determined respectively by GC-MS, inductively coupled plasma mass spectrometry, and inductively coupled plasma atomic emission spectrometry. The results showed that there were significant increases of MN frequencies observed in the sediment-exposed groups, compared with the negative group (P?相似文献   

底质农残测定中固相柱净化体系的选择

使用固相柱对底质中的7种农残进行净化。结果表明,在相同淋洗条件下,使用氟罗里硅土柱比硅胶柱净化效果好。比较了不同溶剂体系、不同溶剂配比下2种萃取柱的净化效果,选择乙醚-正己烷(体积比1∶2)或丙酮-正己烷(体积比1∶4)作为净化溶剂,较小的收集体积都可满足所有目标化合物的回收率要求;相比较而言,丙酮-正己烷(体积比1∶4)作为净化溶剂,洗脱液的杂质干扰更小,净化效果更好。使用氟罗里硅土柱和丙酮-正己烷(体积比1∶4)对样品净化,方法简单,快速,净化效果好,适合大批量底质样品的前处理净化过程。