全文获取类型
收费全文 | 3808篇 |
免费 | 100篇 |
国内免费 | 1443篇 |
专业分类
安全科学 | 210篇 |
废物处理 | 214篇 |
环保管理 | 304篇 |
综合类 | 1867篇 |
基础理论 | 692篇 |
环境理论 | 1篇 |
污染及防治 | 1630篇 |
评价与监测 | 147篇 |
社会与环境 | 125篇 |
灾害及防治 | 161篇 |
出版年
2024年 | 2篇 |
2023年 | 63篇 |
2022年 | 183篇 |
2021年 | 128篇 |
2020年 | 96篇 |
2019年 | 87篇 |
2018年 | 148篇 |
2017年 | 161篇 |
2016年 | 205篇 |
2015年 | 250篇 |
2014年 | 304篇 |
2013年 | 365篇 |
2012年 | 327篇 |
2011年 | 305篇 |
2010年 | 233篇 |
2009年 | 271篇 |
2008年 | 265篇 |
2007年 | 221篇 |
2006年 | 210篇 |
2005年 | 150篇 |
2004年 | 114篇 |
2003年 | 143篇 |
2002年 | 129篇 |
2001年 | 109篇 |
2000年 | 120篇 |
1999年 | 130篇 |
1998年 | 142篇 |
1997年 | 84篇 |
1996年 | 77篇 |
1995年 | 74篇 |
1994年 | 59篇 |
1993年 | 55篇 |
1992年 | 48篇 |
1991年 | 16篇 |
1990年 | 19篇 |
1989年 | 11篇 |
1988年 | 12篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 7篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1971年 | 2篇 |
排序方式: 共有5351条查询结果,搜索用时 15 毫秒
61.
Zhike Li Jie Chi Zhenyu Wu Yiyan Zhang Yiran Liu Lanlan Huang Yiren Lu Minhaz Uddin Wei Zhang Xuejun Wang Yan Lin Yindong Tong 《Frontiers of Environmental Science & Engineering》2022,16(3):37
62.
Occurrence of PAHs, PCBs and organochlorine pesticides in the Tonghui River of Beijing, China 总被引:48,自引:0,他引:48
Tonghui River, a typical river in Beijing, People's Republic of China, was studied for its water and sediment quality, by determining the levels of 16 polycyclic aromatic hydrocarbons (PAHs), 12 polychlorinated biphenyls (PCBs) and 18 organochlorine pesticides in water and sediment samples. Total PAHs, PCBs and organochlorine pesticides concentrations in water varied from 192.5 to 2651 ng/l, 31.58-344.9 ng/l and 134.9-3788 ng/l, respectively. The total PAHs, PCBs and organochlorine pesticides concentrations in surficial sediments were 127-928 ng/g, 0.78-8.47 ng/g and 1.79-13.98 ng/g dry weight, respectively. The results showed that the concentration of these selected organic pollutants in sediment was higher than those in surface water. It may be due to the fact that organic hydrophobic pollutants tend to stay in the sediments. The PAHs were dominated by 2-, 3-ring components in water samples and by 3- and 4-ring compounds in sediment. For organochlorines, alpha-HCH, delta-HCH, Heptachlor, Endosulfan II, DDT are the major organochlorine pesticides in water while Heptachlor, Dieldrin and DDE composed of 95% of total organochlorine pesticides in sediment. For HCHs (HCHs=alpha-HCH+beta-HCH+gamma-HCH+delta-HCH), the predominance of alpha-HCH of total HCHs were clearly observed in water and sediment. PCB18, PCB31 and PCB52 were predominant in water, on average these compounds collectively accounted for 67% of total PCBs. But in sediment, the predominant compounds were PCB28, PCB31 and PCB153, which accounted for 71% of total PCBs in sediment. The levels of micro pollutants in our study areas were compared with other studies. 相似文献
63.
In order to investigate the enzyme transformation of PBDEs and to track the key enzymes involved in PBDE degradation in plants, in vivo exposure of plants of ryegrass, pumpkin and maize and in vitro exposure of their root crude enzyme extracts to PBDEs were conducted. Degradation of PBDEs in the root crude enzyme solutions fit well with the first order kinetics (R2 = 0.52–0.97, P < 0.05), and higher PBDEs degraded faster than the lower ones. PBDEs could be transformed to lower brominated PBDEs and hydroxylated-PBDEs by the root crude enzyme extracts with debromination as the main pathway which contributed over 90% of PBDE depletion. In vitro and in vivo exposure to PBDEs produced similar responses in root enzyme activities of which the nitroreductase (NaR) and glutathione-transferase (GST) activities decreased significantly, while the peroxidase, catalase and cytochrome P-450 activities had no significant changes. Furthermore, higher enzyme concentrations of NaR and GST led to higher PBDE debromination rates, and the time-dependent activities of NaR and GST in the root crude enzyme extracts were similar to the trends of PBDE depletion. All these results suggest that NaR and GST were the key enzymes responsible for PBDE degradation. This conclusion was further confirmed by the in vitro debromination of PBDEs with the commercial pure NaR and GST. 相似文献
64.
铜氰溶液的电子束辐照降解 总被引:1,自引:0,他引:1
研究了铜氰溶液中总氰初始浓度、pH、铜浓度等对总氰降解效率的影响,比较了KCN溶液和铜氰溶液的总氰降解率,初步推断了铜氰溶液在辐照过程中的降解机制.实验结果表明,在同样的辐照剂量下,随着总氰初始浓度的增加,总氰降解率降低,相应的总氰降解G值增大;铜浓度越低,总氰降解率越高;pH越小的铜氰溶液总氰降解率越高.电子束辐照KCN溶液和铜氰溶液的总氰降解反应属于表观一级反应.在相同的辐照剂量下,KCN溶液的总氰降解率比铜氰溶液要高得多.铜氰溶液的电子束辐照降解过程非常复杂,主要是铜氰络合离子逐步离解出的CN-与·OH的反应. 相似文献
65.
66.
本研究采用原子力显微镜(AFM)结合自制的膜探针以及Zeta电位仪通过分别测量不同有机污染物,即腐殖酸(HA)、牛血清蛋白(BSA)和海藻酸钠(SA)与微滤膜之间的粘附力以及相应污染物的Zeta电位,对高岭土在不同有机物微滤过程的影响进行了系统性研究。结果表明,高岭土对污染膜通量衰减的影响主要发生在膜过滤的初期阶段,其存在使HA污染膜的初期通量衰减幅度增加,BSA和SA污染膜的初期通量衰减幅度减缓;清洗后HA污染膜的通量恢复率降低,而BSA和SA污染膜的通量恢复率增大。而且,高岭土的存在使膜-HA之间的粘附力变大以及HA溶液的Zeta电位变小,膜-BSA、SA之间的粘附力变小以及相应污染物的Zeta电位都增大。因此,膜-污染物之间粘附力以及溶液的Zeta电位的变化可以指示膜污染的变化趋势。 相似文献
67.
68.
69.
This study aims to increase the inactivation efficiency of CO_2 against Escherichia coli under mild conditions to facilitate the application of pressurized CO_2 technology in water disinfection. Based on an aerating-cycling apparatus, three different treatment methods(continuous aeration, continuous reflux, and simultaneous aeration and reflux) were compared for the same temperature, pressure(0.3–0.7 MPa), initial concentration, and exposure time(25 min). The simultaneous aeration and reflux treatment(combined method) was shown to be the best method under optimum conditions, which were determined to be 0.7 MPa, room temperature, and an exposure time of 10 min. This treatment achieved 5.1-log reduction after 25 min of treatment at the pressure of 0.3 MPa and 5.73-log reduction after 10 min at 0.7 MPa. Log reductions of 4.4 and 5.0 occurred at the end of continuous aeration and continuous reflux treatments at 0.7 MPa, respectively.Scanning electron microscopy(SEM) images suggested that cells were ruptured after the simultaneous aeration and reflux treatment and the continuous reflux treatment. The increase of the solubilization rate of CO_2 due to intense hydraulic conditions led to a rapid inactivation effect. It was found that the reduction of intracellular p H caused by CO_2 led to a more lethal bactericidal effect. 相似文献
70.
采用生物膜填料塔进行净化低浓度甲苯废气的研究结果表明,构成生物膜的假单胞菌属中的短杆菌对废气中甲苯有很强的生化降解能力,每升体积的生物膜填料对甲苯的生化去除量最大可达104.4mg/h,且当入口气体甲苯浓度约低于2.0mg/L时,单塔净化效率可保持在80%以上。反应级数的转换约在其液相浓度为0.8—1.2mg/L(相当于气相浓度约1.7—2.1mg/L)时发生。 相似文献