CuCoOx/TiO2催化氧化NO性能研究

采用浸渍法制备了CuCoOx/TiO₂催化剂,考察了焙烧温度、反应温度、氧含量、NO浓度和空间速度对催化剂催化氧化NO性能的影响,并考察了催化剂的抗硫抗水性能。XRD、TPR和BET分析表明,350℃焙烧的催化剂具有CuCo₂O₄尖晶石结构,比表面积大,对NO的氧化效果好。在空速为5 000 h^-1,NO进口浓度500 mg/m³,含氧量10%的条件下,反应温度300℃时NO转化率可达79.5%,250℃时NO转化率接近50%。该催化剂具有良好的单独抗SO₂、抗H₂O毒化性能,H₂O和SO₂同时存在时很快失活。该催化剂可用于不同时含H₂O和SO₂的含NO气体催化氧化后再吸收处理。     

Effect of arsenic on chloroplast ultrastructure and calcium distribution in arsenic hyperaccumulator Pteris vittata L

This study investigated the impacts of arsenic (As) on the chloroplast ultrastructure and calcium (Ca) distribution in Chinese brake (Pteris vittata L.) mainly by histochemical methods, with an emphasis on the possible function of Ca in As detoxification and accumulation in P. vittata. P. vittata was grown in an artificially contaminated soil added with different concentrations of Na(2)HAsO(4) (0, 100, 300 and 800 mg kg(-1) As dry soil) for 24 weeks in a greenhouse. The addition of As did not affect the chloroplast ultrastructure of young pinna, meanwhile most of the membrane systems of chloroplasts in mature pinna were severely damaged under high As condition. Calcium concentration in the fronds of P. vittata was not significantly affected by the addition of As, but Ca concentration in the mature pinna significantly increased by As addition, consistent with the position appearing As toxicity. When no As was added, most of calcium precipitates distributed around the inner membrane of vacuole. But when the pinna appeared plasmolysis, more calcium precipitates resided outside the cell membrane and bigger particles evenly distributed in the cytoplasm. All the results indicated that Ca had a close relation with As toxicity in P. vittata.     

Modeling the spatial pattern of farmland using GIS and multiple logistic regression: a case study of Maotiao River Basin, Guizhou Province, China

Land use change is an important topic in the field of global environmental change and sustainable development. Land use change modeling has attracted substantial attention because it helps researchers understand the mechanisms of land use change and assists regulatory bodies in formulating relevant policies. Maotiao River Basin is located in the province of Guizhou, China, which has a developed agricultural industry in the karst mountain areas. This paper selected biophysical and social–economic factors as independent variables, and constructed a multiple logistic regression of farmland spatial distribution probability by random sampling. Then, by using GIS technology and integrating the 2000 data, this study predicted the farmland spatial pattern. When the predicted map was compared with the actual farmland map for 2000, we noted that 71% of the simulation is in accordance with the 2000 farmland pattern. The result satisfactorily proves the reasonability and applicability of our model.     

Considering climate change and regional differences: An efficiency assessment of coal mine use and land restoration

China is the country with the largest coal mining production and consumption in the world, but due to a large amount of coal burning, air pollution and climate change are exasperating related problems. The previous literature mainly has discussed coal mine production and environmental pollution, but failed to take into account external factors such as climate change and seldom discussed the relationship between coal mine land use and land restoration. Therefore, this study uses the meta-Epsilon-Based Measure two-stage Data Envelopment Analysis under the exogenous model and incorporates coal mine land use and land restoration use into the model to explore the relationship between the two under climate change. The research results are as follows. (1) If the external climate factors are not considered, then the phenomenon of overestimation or underestimation of the technology gap arises. (2) The efficiency value of the coal mining stage in most provinces is generally higher than the land restoration efficiency value.     

包头市企业环境行为信用评价指标体系研究

企业环境行为信用评价是一种符合国情的先进的环境管理手段,是对当前环境管理制度的重要补充和完善.为了强化政府对污染源的监管,提升环保部门的环境监管力度和水平,督促企业持续改进环境行为,文章对不同尺度的指标体系进行了分析对比,结合包头市实际情况,构建了包含污染防治、环境管理、社会影响和组织管理四部分共二十五项指标的包头市企业环境行为信用评价指标体系,以期对环境管理起到检查和促进作用、前瞻和导向功能.     

污水汽提塔的优化设计与运行

通过分析当前污水汽提塔运行中存在的主要问题，提出了污水汽提塔设计与运行中的优化建议。增加汽提塔板数，净化水质量可控制在氨氮小于50mg／L，硫化物小于10mg／L；汽提塔做多段变径设计可大幅降低装置能耗，保持良好的气提效果。     

利用底栖动物评价图们江污染的研究

作者于1977年8月至1979年8月在图们江上中游的9个采样点上,主要使用人工基质采样器采集底栖无脊椎动物。结果证明图们江底栖动物比较丰富,出现的主要种类属于襀翅目、蜉蝣目的稚虫,毛翅目幼虫,摇蚊科幼虫和水栖寡毛类。其中崇善江段种类多,表现出明显的多样性。根据三年来所收集到的资料,计算了Trent生物指数,Chandler记分制以及Shannon多样性指数,并对图们江的污染状况作出生物学评价,上游地段属于清洁水到中污染;中游地段在污染源以下至图们站属于重污染;自河东站开始,水质又明显好转,属于轻污染。     

Carbonyl emissions from vehicular exhausts sources in Hong Kong

Vehicular emission (VE) is one of the important anthropogenic sources for airborne carbonyls in urban area. Six types of VE-dominated samples were collected at representative locations in Hong Kong where polluted by a particular fueled type of vehicles, including (i) a gas refilling taxis station (liquefied petroleum gas [LPG] emission); (ii) a light-duty passenger car park (gasoline emission); (iii) a minibus station (diesel emission); (iv) a single-deck-bus depot (diesel emission); (v) a double-deck-bus depot (diesel emission); and (vi) a whole-food market entrance for light- and heavy-duty vehicles (diesel emission). A total of 15 carbonyls in the samples were quantified. Formaldehyde was the most abundant carbonyl among the VE-dominated samples, and its contribution to the total quantified amount on a molar basis ranged from 54.8% to 60.8%. Acetaldehyde and acetone were the next two abundant carbonyls. The carbonyls were quantified at three roadside locations in Hong Kong. The highest concentrations of formaldehyde and acetaldehyde, 22.7 +/- 8.4 and 6.0 +/- 2.8 microg/m3, respectively, were determined in the samples collected at a main transportation gate for goods between Hong Kong and Mainland China. The total quantified carbonyl concentration, 37.9 +/- 9.3 microg/m3, was the highest at an entrance of a cross-harbor tunnel in downtown area. The theoretical carbonyls compositions of the three roadside locations were estimated according to the VE-dominated sample profiles and the statistics on vehicle numbers and types during the sampling period. The measured compositions of formaldehyde were much higher than the theoretical compositions in summer, demonstrating that photochemical reactions significantly contributed to the formaldehyde production in the roadsides.     

陶瓷印花废水处理的混凝剂及工艺条件

采用混凝剂聚合氯化铝（PAC）、聚丙烯酰胺（PAM）、聚合硫酸铁（PFS）对陶瓷印花废水进行混凝沉降处理,监测水样的吸光度、浊度、悬浮物,以脱色率、浊度去除率、悬浮物去除率评价混凝处理的效果。结果表明：PAC是陶瓷印花废水沉降处理的理想混凝剂;水样的吸光度、浊度、悬浮物随混凝剂用量增大和沉降时间延长而呈降低趋势,而脱色率、浊度去除率、悬浮物去除率随混凝剂和沉降时间的增大呈增大的趋势;PAC投加量为20mg／L,沉降时间约为24h,水样脱色率达到90．0％,而当PAC投加量达到100mg／L,沉降时间约为4h,陶瓷印花水的脱色率可达到96．0％。证明了药剂用量的增加与沉降时间的延长对混凝过程具有增效作用。     

县级生态农业建设的人工神经网络模型

引入人工神经网络的评价识别方法，建立了ＢＰ模型，以前人建立的县级生态农业建设评价指标体系评价标准，和某县生态农业综合评价指标数据为实例，比较ＢＰ模型的有效性，得到的评价分类结果和指标优先发展顺序决策与实际情况相吻合。