首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   251篇
  免费   27篇
  国内免费   95篇
安全科学   32篇
废物处理   9篇
环保管理   26篇
综合类   163篇
基础理论   41篇
污染及防治   69篇
评价与监测   11篇
社会与环境   7篇
灾害及防治   15篇
  2023年   2篇
  2022年   12篇
  2021年   21篇
  2020年   11篇
  2019年   12篇
  2018年   11篇
  2017年   11篇
  2016年   21篇
  2015年   14篇
  2014年   21篇
  2013年   14篇
  2012年   25篇
  2011年   27篇
  2010年   17篇
  2009年   13篇
  2008年   13篇
  2007年   16篇
  2006年   11篇
  2005年   8篇
  2004年   12篇
  2003年   16篇
  2002年   8篇
  2001年   11篇
  2000年   6篇
  1999年   5篇
  1998年   4篇
  1997年   9篇
  1996年   8篇
  1995年   5篇
  1994年   1篇
  1993年   2篇
  1992年   1篇
  1991年   2篇
  1988年   1篇
  1987年   1篇
  1986年   1篇
排序方式: 共有373条查询结果,搜索用时 15 毫秒
131.
基于2008年及2009年分4个季节对北京市3种类型道路(开阔型、交叉路口型和峡谷型)空气中的NOx的现场监测结果,分析了3种类型道路空气中NOx的污染现状和时空变化规律及影响因素。实验结果表明,昼间北京市各类型街道空气中NOx浓度呈早晚浓度高、中午浓度低的变化规律,NOx浓度随季节和车流量变化较明显。交通道路空气中NO占NOx的分担率高,且有较好的相关性,而NO2分担率较低,与NOx相关性较差。  相似文献   
132.
Sources of anthropogenic radionuclides in the environment: a review   总被引:1,自引:0,他引:1  
Studies of radionuclides in the environment have entered a new era with the renaissance of nuclear energy and associated fuel reprocessing, geological disposal of high-level nuclear wastes, and concerns about national security with respect to nuclear non-proliferation. This work presents an overview on sources of anthropogenic radionuclides in the environment, as well as a brief discussion of salient geochemical behavior of important radionuclides. We first discuss the following major anthropogenic sources and current developments that have lead, or could potentially contribute, to the radionuclide contamination of the environment: (1) nuclear weapons program; (2) nuclear weapons testing; (3) nuclear power plants; (4) uranium mining and milling; (5) commercial fuel reprocessing; (6) geological repository of high-level nuclear wastes that include radionuclides might be released in the future, and (7) nuclear accidents. Then, we briefly summarize the inventory of radionuclides 99Tc and 129I, as well as geochemical behavior for radionuclides 99Tc, 129I, and 237Np, because of their complex geochemical behavior, long half-lives, and presumably high mobility in the environment; biogeochemical cycling and environment risk assessment must take into account speciation of these redox-sensitive radionuclides.  相似文献   
133.
基于2008年及2009年分4个季节对北京市3种类型道路(开阔型、交叉路口型和峡谷型)空气中的NOx的现场监测结果,分析了3种类型道路空气中NOx的污染现状和时空变化规律及影响因素。实验结果表明,昼间北京市各类型街道空气中NOx浓度呈早晚浓度高、中午浓度低的变化规律,NOx浓度随季节和车流量变化较明显。交通道路空气中NO占NOx的分担率高,且有较好的相关性,而NO2分担率较低,与NOx相关性较差。  相似文献   
134.
Radical chemistry in the nocturnal urban boundary layer is dominated by the nitrate radical, NO3, which oxidizes hydrocarbons and, through the aerosol uptake of N2O5, indirectly influences the nitrogen budget. The impact of NO3 chemistry on polluted atmospheres and urban air quality is, however, not well understood, due to a lack of observations and the strong impact of vertical stability of the boundary layer, which makes nocturnal chemistry highly altitude dependent.Here we present long-path DOAS observations of the vertical distribution of the key nocturnal species O3, NO2, and NO3 during the TRAMP experiment in Summer 2006 in Houston, TX. Our observations confirm the altitude dependence of nocturnal chemistry, which is reflected in the concentration profiles of all trace gases at night. In contrast to other study locations, NO3 chemistry in Houston is dominated by industrial emissions of alkenes, in particular of isoprene, isobutene, and sporadically 1,3-butadiene, which are responsible for more than 70% of the nocturnal NO3 loss. The nocturnally averaged loss of NOx in the lowest 300 m of the Houston atmosphere is ~0.9 ppb h?1, with little day-to-day variability. A comparison with the daytime NOx loss shows that NO3 chemistry is responsible for 16–50% of the NOx loss in a 24-h period in the lowest 300 m of the atmosphere. The importance of the NO3 + isoprene/1,3-butadiene reactions implies the efficient formation of organic nitrates and secondary organic aerosol at night in Houston.  相似文献   
135.
以酸处理脱铝后信阳天然斜发沸石为载体,硫酸钛、钛酸正丁酯和四氯化钛为钛源,分别采用浸渍法和气相法制备出钛掺杂沸石光催化剂。采用X-射线衍射和傅立叶红外光谱分析了沸石酸处理及钛取代前后结构。结果表明,80℃下,4 mol/L盐酸处理10 h后沸石结构发生了显著变化,但仍保持Al-O-Si骨架结构。红外光谱结果证明Ti4+与沸石形成稳定的Ti-O-Si键。在以300 W紫外灯为光源进行罗丹明B脱色反应,考察了含钛沸石的光催化活性。初始浓度为80 mg/L,光照1.5 h后罗丹明B的去除率为98.18%。  相似文献   
136.
The aim of this study was to evaluate short-term concentration and time effects of cadmium on Kandelia obovata (S., L.) Yong root exudation, thereby evaluating and predicting the ecophysiological effects of mangrove to heavy metals at the root level. Mature K. obovata propagules were cultivated in a sandy medium for 3 months, and then six concentrations of Cd (0, 2.5, 5, 10, 20, and 40 mg L?1) were applied. After exposure time of 24 h and 7 days, respectively, the root exudates of K. obovata were collected and low molecular weight organic acids (LMWOAs) and amino acids of which were analyzed. In addition, we measured glutathione, soluble protein content, and Cd concentration in the plant. We found 10 and 15 types of LMWOAs and amino acids in root exudates of K. obovata with total concentrations ranging from 29.54 to 43.08 mg g?1 dry weight (DW) roots and from 737.35 to 1,452.46 ng g?1 DW roots, respectively. Both of them varied in quality and quantity under different Cd treatment strengths and exposure times. Oxalic, acetic, l-malic, tartaric acid, tyrosine, methionine, cysteine, isoleucine, and arginine were dominant. Both LMWOAs and amino acids excreted from K. obovata roots play a key role in Cd toxicity resistance. The responsiveness of amino acids was less than that of LMWOAs. We suggest that the ecological effect of root-excreted free amino acids in the rhizosphere is mainly based on the role of nutrients, supplemented with detoxification to heavy metals.  相似文献   
137.
Synchrotron X-ray microfluorescence and X-ray absorption near-edge microstructure spectroscopy techniques were applied to Typha latifolia (cattail) root sections and rhizosphere soils collected from a brownfield site in New Jersey to investigate lead (Pb) accumulation in T. latifolia roots and the role of iron (Fe) plaque in controlling Pb uptake. We found that Pb and Fe spatial distribution patterns in the root tissues are similar with both metals present at high concentrations mainly in the epidermis and at low concentrations in the vascular tissue (xylem and phloem), and the major Pb and Fe species in T. latifolia root are Pb(II) and Fe(III) regardless of concentration levels. The sequestration of Pb by T. latifolia roots suggests a potential low-cost remediation method (phytostabilization) to manage Pb-contaminated sediments for brownfield remediation while performing wetland rehabilitation.  相似文献   
138.
以氯化铁为铁源,硼氢化钠为还原剂,壳聚糖为稳定剂,采用液相还原法制备壳聚糖稳定纳米铁(CS-Fe);并以氯化铁为铁源,硫酸镍为镍源,硼氢化钠为还原剂,壳聚糖为稳定剂,采用液相还原共沉淀法制备壳聚糖稳定纳米铁镍(CS-Fe/Ni)。通过SEM、EDS、XRD、FT-IR等表征手段,对所制备的CS-Fe和CS-Fe/Ni的形貌及微观结构进行表征,并以Co2+为目标去除物评价CS-Fe和CS-Fe/Ni的反应活性。初步研究表明,制成的CS-Fe含有单质纳米铁,颗粒多数以30~90 nm球形颗粒为主;而CS-Fe/Ni材料中含有纳米铁镍,颗粒多数以30~60 nm球形颗粒为主;在相同的实验条件下,反应60 min,CS-Fe/Ni对Co2+的去除率高达100%,但是CS-Fe仅为88%,即CS-Fe/Ni对Co2+的去除率比CS-Fe高。  相似文献   
139.
环境保护督察巡视:党政同责的顶层制度   总被引:2,自引:2,他引:0       下载免费PDF全文
环境保护督察巡视是党政同责的核心制度安排。本文从环保督察巡视与党政同责的关系与实践出发,认为该制度是从决策源头监督,既有法律依据,也有政策要求,其他部门的督察以及环保考核、约谈等实践为环保督察巡视积累了经验。从环保督察巡视制度的内涵与特征来看,该制度有明确的行动指南、统一的党政同责督察体系、较高的督察组权威、明确的巡视重点与突破方向等特点。最后,本文从理顺环境目标责任制度、制定督察实施细则、提升督察巡视权威性、开展第三方评估与社会监督等方面提出了政策建议。  相似文献   
140.
This study developed an integrated (flow, voltage, and temperature) micro sensor using the micro-electro-mechanical systems (MEMS) technology. It was inserted into the high temperature proton exchange membrane fuel cell (HT-PEMFC) for local real-time measurement. The integrated micro sensor is made of 40 µm thick stainless steel base material, and its protective layer is formed by polyimide (PI) that has better temperature resistance. The integrated micro sensor has three functions, and is favorably characterized by small size, good acid resistance and temperature resistance, quick response, real-time measurement, and being able to be put in any place for measurement. After calibration, and its reliability confirmed, the integrated micro sensor is inserted into the HT-PEMFC for local microcosmic measurement.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号