进口废塑料环境保护管理研究

随着塑料资源的大量消耗,废塑料的利用引起了社会的高度重视。工艺简单,投入成本少,入行门槛低导致部分废塑料加工利用企业技术水平低、管理模式差、环境污染重。为规范进口废塑料行业,通过调研统计、实验分析、咨询论证和研究了进口废塑料环境保护管理规定,对进口废塑料企业的规模、设备、人员和管理等方面提出了要求,为进一步规范提升进口废塑料行业提供技术支撑。     

Degradation of poly(butylene adipate-co-terephthalate) by Stenotrophomonas sp. YCJ1 isolated from farmland soil

In recent years, poly (butylene adipate-co-terephthalate) (PBAT) has been widely used. However, PBAT-degrading bacteria have rarely been reported. PBAT-degrading bacteria were isolated from farmland soil and identified. The effects of growth factors on the degradation of PBAT and the lipase activity of PBAT-degrading bacteria were assessed. The degradation mechanism was analyzed using scanning electron microscopy, attenuated total reflection Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, X-ray diffraction, and liquid chromatography-mass spectrometry. The results showed that Stenotrophomonas sp. YCJ1 had a significant degrading effect on PBAT. Under certain conditions, the strain could secrete 10.53 U/mL of lipase activity and degrade 10.14 wt.% of PBAT films. The strain secreted lipase to catalyze the degradation of the ester bonds in PBAT, resulting in the production of degradation products such as terephthalic acid, 1,4-butanediol, and adipic acid. Furthermore, the degradation products could participate in the metabolism of YCJ1 as carbon sources to facilitate complete degradation of PBAT, indicating that the strain has potential value for the bioremediation of PBAT in the environment.     

Reinforcing and Toughening Modification of PPC/PBS Blends Compatibilized with Epoxy Terminated Hyperbranched Polymers

Journal of Polymers and the Environment - Polypropylene carbonate (PPC)/polybutylene succinate (PBS) blends were prepared by melt-blending with terminal epoxy-based hyperbranched polymers (EHBP) as...     

Functional flax fiber with UV-induced switchable wettability for multipurpose oil-water separation

● A PAA-ZnO-HDTMS flax fiber with UV-induced switchable wettability was developed. ● The property of flax fiber could be switched from hydrophobicity to hydrophilicity. ● The mechanism of the acquired UV-induced switchable wettability was discussed. ● The developed flax fiber was successfully used for multipurpose oil-water separation. The large number of oily wastewater discharges and oil spills are bringing about severe threats to environment and human health. Corresponding to this challenge, a functional PAA-ZnO-HDTMS flax fiber with UV-induced switchable wettability was developed for efficient oil-water separation in this study. The developed flax fiber was obtained through PAA grafted polymerization and then ZnO-HDTMS nanocomposite immobilization. The as-prepared PAA-ZnO-HDTMS flax fiber was hydrophobic initially and could be switched to hydrophilic through UV irradiation. Its hydrophobicity could be easily recovered through being stored in dark environment for several days. To optimize the performance of the PAA-ZnO-HDTMS flax fiber, the effects of ZnO and HDTMS concentrations on its switchable wettability were investigated. The optimized PAA-ZnO-HDTMS flax fiber had a large water contact angle (~130°) in air and an extremely small oil contact angle (~0°) underwater initially. After UV treatment, the water contact angle was decreased to 30°, while the underwater oil contact angle was increased to more than 150°. Based on this UV-induced switchable wettability, the developed PAA-ZnO-HDTMS flax fiber was applied to remove oil from immiscible oil-water mixtures and oil-in-water emulsion with great reusability for multiple cycles. Thus, the developed flax fiber could be further fabricated into oil barrier or oil sorbent for oil-water separation, which could be an environmentally-friendly alternative in oil spill response and oily wastewater treatment.     

Dawson结构磷钨钒杂多酸的表征及其光催化性能

通过FTIR、UV、循环伏安法对自制的Dawson结构磷钨钒杂多酸催化剂的结构及电化学性能进行表征.以甲基橙溶液模拟工业染料废水,考察了磷钨钒杂多酸光催化降解性能的影响因素.实验结果表明:自制磷钨钒杂多酸具有Dawson结构,表现出良好的电化学性能;在磷钨钒杂多酸加入量为1.5 g/L、初始甲基橙质量浓度为10 mg/L、紫外灯功率为500W的条件下,经紫外光照射200 min,甲基橙降解率可达98.3％.     

高速铁路高填复合路堤边坡安全问题探讨

路基是高速铁路安全系统的关键和薄弱环节 ,建在软土上的高填路堤边坡是否稳定 ,更是直接关系到路基乃至整个高速铁路系统的安全 ,采用桩—网复合地基形式修建高路堤是一个好办法 ,这种路堤形式尚不多见。笔者结合其特点 ,从理论上提出了一种新的边坡安全实用计算方法 ;讨论了影响边坡安全的主要因素 ;验证了这一计算方法的合理性     

工业设备的震害预测研究

综合考虑地震作用和结构材料的随机性 ,运用概率论的知识建立了地震作用下钢铁工业设备各种破坏形式的极限状态方程 ,并求出了对应于某种地震烈度 ,设备出现各种破坏状态的概率。在此基础上 ,通过模糊综合评判的手段提出了工业设备的震害预测方法 ,并编制了相应的软件。此种方法的建立使设备抗震预测变得方便、可行。     

九寨沟自然保护区4种水深梯度下芦苇分株地上生物量的分配与生长

芦苇是世界自然遗产--九寨沟自然保护区的一种重要的湿地植物.本文对该地区芦苇海4个不同水深梯度下芦苇的无性系地上分株的生物量分配、生长与繁殖策略进行了比较研究.结果表明,在47 cm (水在土层表面上)水深环境中,芦苇单株的平均生物量(4.2 g)最大.在-15 cm (水在土层表面下15 cm)的生境中,叶生物量百分比(叶生物量占单株总生物量的百分比, 46.1%)最大.芦苇地上分株高度、地上分株有分枝的单株百分比(茎上有分枝的分株占样地总分株的百分数)也存在明显的差别.茎的生物量分配百分比和生长速率随水深的增加而增加.在滩地生境中,开花率、花序的生物量百分比明显大于水较深的生境.分株株高与分株生物量、茎生物量与叶生物量都表现出较明显的幂指数异速生长规律.在-15 cm水深的生境中,叶生物量的生长快于茎的增长;在其他水深梯度的生境中,则是茎生物量的增加快于叶生物量的增加.     

Review on synthesis of three-dimensional graphene skeletons and their absorption performance for oily wastewater

Water pollution is a global environmental problem that affects the ecosystem severely. Treatment of oily wastewater and organic pollutants is a major challenge that waits to be solved as soon as possible. Adsorbing is one of the most effective strategies to deal with this problem. Three-dimensional (3D) porous adsorbents made of graphene or graphene-based nanomaterials skeletons had attracted more attention in wastewater treatment because of their large surface area, high porosity, low density, high chemical/thermal stability, and steady mechanical properties, which allow different pollutants to easily access and diffuse into 3D networks of adsorbents. This work presents an extensive summarization of recent progress in the synthesis methodologies and microstructures of 3D graphene foams and 3D graphene-based foams and highlights their adsorption performance for oils and organic solvents. Advantages and disadvantages of various preparation strategies are compared and the corresponded structures of these skeletons are studied in detail. Furthermore, the effects of the structures on oil-adsorption properties are analyzed and some data and parameters of the oil-adsorption properties are listed and studied for easier comparison. At last, the future research directions and technical challenges are prospected, which is hoped that the researchers will be inspired to develop the new graphene-based adsorbents.