纯净水、净化水、凉开水、自来水的水质分析及其卫生学意义

目的：分析比较4种常用生活饮用水的水质，为选择健康饮水提供参考。方法：按照国家卫生标准GB5750－85推荐的方法对纯净水、净化水、凉开水、管道自来水进行包括感官性状、一般化学、毒理学、细菌学指标、常量、微量元素在内的39项指标的水质分析，并参照国家卫生GB5749－85和GB17324－1998进行分析比较。结果与结论：按现行国家卫生标准评价；（1）自来水（未处理）、净化水各项指标均符合相应的国家生活饮用水卫生标准、安全卫生。（2）凉开水除铝元素含量超标外，其余亦符合国家生活饮用水卫生标准；（3）纯净水符合国家纯净水卫生标准，但所有指标数值（包括常量及微量元素）均明显低于其他三种饮用水，长期饮用后的健康效应值得深入研究。     

新疆阿尔泰地槽成矿元素分布特征

新疆阿尔泰地槽内成矿元素 ,自北东向南西分为四个带 ,每个带内分布有元素区和矿床 :①阿尔泰山北缘元素带 (阿克萨拉等区 ) ;②阿尔泰山中脊元素带 (冲呼等五个区和可可托海 3号脉稀有金属矿等矿床 ) ;③阿尔泰山南缘元素带 (阿舍勒等四个区和阿舍勒铜矿等矿床 ) ;④额尔齐斯元素带 (喀拉通克等区和喀拉通克铜镍矿等矿床 )。成矿元素区带是寻找新矿床的有利地段     

A complete set of procedure for determination of multiresidue of pesticides in vegetables

A complete set of procedure for determination of multiresidue of pesticides in vegetables was presented in this paper.The complete set of procedure included three steps:bioassay,cholinesterase inhibition and GLC analysis.The samples could be identified to be contaminated with pesticides if 5% of house flies was knocked down in 50 tested house flies. Those samples contaminated with pesticides needed to be detected by AChE inhibition method.The qualitative and quantitative analyses were carried out by GLC.Recoveries ranged from 83.7% in Chinese cabbages to 105.6% in tomatoes for pyrethroids,and 84.0% in tomatoes to 102.7% in sweetbell redpeppes for organophosphorus compounds.Coefficients of variations ranged from 0.59% to organophosphorus compounds.Coefficients of variations ranged from 0.59% to 7.87% for pyrethroids. and 0.33% to 9.88% for organophosphorus compounds with vegetables. The complete set of procedure has been used successfully to analyze 7000 samples collected in Beijing. About 1% of the samp     

甘肃省环境天然放射性水平研究

近年来,国内外在环境天然放射性水平研究方面做了一些工作.在国内,由于研究目的各有侧重,因而在布点原则等方面有所不同.在全国环境保护系统的天然放射性水平研究中,象甘肃省这种跨度大(东经92°13′—108°46′,北纬32°31′—42°57′)、地形地貌极其复杂(有沙漠、戈壁、山区、高原、草原、河谷盆地等)、海拔高度差别悬殊(有600m河     

高岭土矿成因分类的氢氧同位素证据

本文论述了氢、氧同位素作为高岭土矿成因类型地球化学指标的意义.根据氢、氧同位素数据,我国浙闽沿海地区高岭土矿床主要可分为热液蚀变型和风化作用型两大类.其成矿溶液以大气降水为主.     

利用浮游动物评价滇池的污染状况

应用Sanders氏稀疏曲线法及Shannon-Wiener多样性指数法对滇池不同水域浮游动物种类和数量进行分析,结合指示种的分布情况分析结果表明,①滇池草海和外海的污染状况有明显的不同,草海处于α中污染阶段,外海处于β中污染阶段;②滇池污染的梯度变化:新河>楼外楼>草海中>灰湾>大河尾>观音山中;③草海正趋向于池沼泽化。     

氯氟烃及其替代物

近年来,臭氧衰竭比原先预料的更严重,对人类健康和环境构成了严重威胁。“蒙特利尔议定书”和“大气清洁法案”要求2000年要完全清除致臭氧衰竭物质——氯氟烃(CFCs)的生产和使用。目前,世界各地积极开发CFCs的替代物,以加速转换。虽然已开发的氧氯氟烃(HCFCs)、氢氟烃(HFCs)等替代物与CFCs相比还有一定缺点,但最终一定会实现替代转换。     

上海市第二水源长江取水口环境生物调查和质量评价——(Ⅰ.浮游生物)

本文应用水生物、污水生物体系的划分阶段,以评价上海市第二水源长江两个取水口的环境质量.1989年枯水期(2～3月)和丰水期(7月)在长江口河流段南岸的浏河和浪港二个站位,分别在近岸(5m水深)和远岸(10m水深上、下层)的断面,进行浮游植物,浮游动物调查.结果认为两个取水口应是β中污型(βm),属尚清洁带.相比之下,浏河站比浪港站差,近岸比远岸差,丰水期低潮时比高潮时差,浏河站丰水期比枯水期差,浪港站枯水期比丰水期差.其主要受自邻近河道排放水,上海市污水排放和涨落潮污水流向变化的影响,反映了河口区环境的复杂性.     

化学法综合治理草浆造纸黑液的研究

本文采用凝聚-离心分离法对黑液进行预除硅,酸析沉淀法回收黑液中的木质素,并重点研究了混凝法和催化氧化法除去经提取木质素后的黑液中COD的最佳条件.研究结果表明,采用预先除硅-酸析沉淀-混凝-催化氧化联合流程可有效地处理黑液,处理水COD小于300mg/L,同时回收了木质素.     

Simultaneous quantification of fifty-one odor-causing compounds in drinking water using gas chromatography-triple quadrupole tandem mass spectrometry

A wide range of compounds with various structural features can cause taste and odor(TO)problems in drinking water. It would be desirable to determine all of these compounds using a simple analytical method. In this paper, a sensitive method combining liquid–liquid extraction(LLE) with gas chromatography-triple quadrupole tandem mass spectrometry(GC–MS/MS)was established to simultaneously analyze 51 odor-causing compounds in drinking water,including organic sulfides, aldehydes, benzenes, phenols, ethers, esters, ketones, nitrogenous heterocyclic compounds, 2-methylisoborneol and geosmin. Three deuterated analogs of target analytes, dimethyl disulfide-d6, benzaldehyde-d6 and o-cresol-3,4,5,6-d4,were used to correct the variations in recovery, and five isotope-labeled internal standards(4-chlorotoluene-d4, 1, 4-dichlorobenzene-d4, naphthalene-d8, acenaphthene-d10, phenanthrene-d10 respectively) were used prior to analysis to correct the variations arising from instrument fluctuations and injection errors. The calibration curves of the target compounds showed good linearity(R2 0.99, level = 7),and method detection limits(MDLs) below 1/10 of the odor threshold concentrations were achieved for most of the odorants(0.10–20.55 ng/L). The average recoveries of most of the analytes in tap water samples were between 70% and 120%, and the method was reproducible(RSD 20%, n = 7). Additionally, concentrations of odor-causing compounds in water samples collected from three drinking water treatment plants(DWTPs) were analyzed by this method.According to the results, dimethyl trisulfide, dimethyl disulfide and indole were considered to be the key odorants responsible for the swampy/septic odor. 2-Methylisoborneol and geosmin were detected as the main odor-causing compounds for musty/earthy odor in DWTP B.