钢渣处理技术的环境性能比较

随着钢铁工业的快速发展,大量钢渣弃置堆积,不仅成为环境污染源,而且占用大量的土地。目前钢渣处理技术较多,其中主要的处理方法有冷弃法、热闷法、热泼法、浅盘法、水淬法、风淬法等。本研究采用生命周期评价方法,对主要钢渣处理技术进行评估,定义了生命周期评估边界和清单指标,建立了清单计算模型,得到了不同钢渣处理技术的生命周期清单。为了提高结果的可信性,对模型进行了不确定性分析。结果表明滚筒法和风淬法的环境性能较好,是值得推广的钢渣处理技术。     

四川某中小城镇污水处理厂进水水质统计分析

生活污水水质对处理工艺的选择、设计参数的选取以及稳定运行十分重要。运用SPSS软件,对四川某中小城镇污水处理厂为期一年的进水指标(水量、COD、氨氮、总磷、pH、SS)进行方差和相关性分析。方差分析结果显示进水量、氨氮和SS在月份和季节之间存在显著性差异,而总磷和pH仅在月份之间存在显著差异,COD在季度和月份之间无显著性差异;指标相关性分析表明,进水量和氨氮之间呈负相关,氨氮和总磷、COD和总磷之间呈正相关,且相关性显著。在此分析的基础上对污水处理厂设计、工艺选择及运行管理提出了一些建议。     

影响水中COD测定值关键因素的探讨

随着国家节能减排工作的大力推进,COD作为减排中四个重要约束性指标之一,其分析的准确性极大地影响着COD减排工作的顺利实施。本文根据《水质化学需氧量的测定重铬酸盐法》（GB11914—89）,结合《水质采样技术指导》（HJ494-2009）要求及笔者多年COD分析测试工作经验,着重探讨重铬酸盐法中水样中悬浮物及氯离子对测定结果的影响,以求在实际工作中能更准确、更方便地完成水样中COD的分析工作。     

基于功率法的结构⁃TMD减震控制分析∗

建立了结构-TMD振动方程,推导了无控结构和带TMD受控结构基于功率表达的运动方程,分别解释并给出了各种功率表达参数的物理意义,推导了随机激励下结构耗能功率流均值的随机表达式,对比分析了基于功率法的结构-TMD优化方法与其他优化方法的优化分析结果,并对其减震控制效果进行了对比分析。结果表明,结构-TMD系统的参数可以通过耗能功率流随机分析方法所得均值进行优化,且通过功率法优化后,结构在减震效果上优于其他传统方法得到的结果,从耗能功率均值的随机分析和时程功率分析角度证明了TMD控制的有效性;TMD做功功率为负时对结构有控制效果,起吸收转移能量的作用,且功率幅值越大控制效果越好,做功功率为正时则相反。     

Unregulated emissions from diesel engine with particulate filter using Fe-based fuel borne catalyst

The alteration and formation of toxic compounds and potential changes in the toxicity of emissions when using after-treatment technologies have gained wide attention. Volatile organic compound（VOC）, carbonyl compound and particle-phase polycyclic aromatic hydrocarbon（PAH） emissions were tested at European Steady State Cycle（ESC） to study unregulated emissions from a diesel engine with a fuel-borne catalyst and diesel particulate filter（FBC–DPF）. An Fe-based fuel-borne catalyst was used for this study. According to the results, brake specific emissions of total VOCs without and with DPF were 4.7 and4.9 mg/kWh, respectively, showing a 4.3% increase. Benzene and n-undecane emissions increased and toluene emission decreased, while other individual VOC emissions basically had no change. When retrofitted with the FBC–DPF, total carbonyl compound emission decreased 15.7%, from 25.8 to 21.8 mg/kWh. The two highest carbonyls, formaldehyde and acetaldehyde, were reduced from 20.0 and 3.7 to 16.5 and 3.3 mg/kWh respectively. The specific reactivity（SR） with DPF was reduced from 6.68 to 6.64 mg/kWh. Total particle-phase PAH emissions decreased 66.4% with DPF compared to that without DPF. However, the Benzo[a]pyrene equivalent（BaPeq） with DPF had increased from 0.016 to 0.030 mg/kWh.Fluoranthene and Pyrene had the greatest decrease, 91.1% and 88.4% respectively. The increase of two- and three-ring PAHs with DPF indicates that the fuel-borne catalyst caused some gas-phase PAHs to adsorb on particles. The results of this study expand the knowledge of the effects of using a particulate filter and a Fe-based fuel-borne catalyst on diesel engine unregulated emissions.     

Effect of a high strength chemical industry wastewater on microbial community dynamics and mesophilic methane generation

A high strength chemical industry wastewater was assessed for its impact on anaerobic microbial com- munity dynamics and consequently mesophilic methane generation. Cumulative methane production was 251 mL/g total chemical oxygen demand removed at standard temperature and pressure at the end of 30 days experimental period with a highest recorded methane percentage of 80.6% of total biogas volume. Volatile fatty acids （VFAs） analysis revealed that acetic acid was the major intermediate VFAs produced with propionic acid accumulating over the experimental period. Quantitative analysis of microbial communities in the test and control groups with quantitative real time polymerase chain reaction highlighted that in the test group, Eubacteria （96.3%） was dominant in comparison with methanogens （3.7%）. The latter were dominated by Methanomicrobiales and Methanobacteriales while in test groups increased over the experimental period, reaching a maximum on day 30. Denaturing gradient gel electrophoresis profile was performed, targeting the 16S rRNA gene of Eubacteria and Archaea, with the DNA samples extracted at 3 different time points from the test groups. A phylogenetic tree was constructed for the sequences using the neighborhood joining method. The analysis revealed that the presence of organisms resembling Syntrophomonadaceae could have contributed to increased production of acetic and propionic acid intermediates while decrease of organisms resembling Pelotomaculum sp. could have most likely contributed to accumulation of propionic acid. This study suggested that the degradation of organic components within the high strength industrial wastewater is closely linked with the activity of certain niche microbial communities within eubacteria and methanogens.     

宜昌市三级监测站标准化建设现状分析及对策研究

标准化站建设是提升环境监测站能力水平的重要途径和抓手,为促进宜昌市三级站的整体达标验收,该研究分析了辖区三级监测站标准化建设存在的主要共性问题为：在岗人员数量少和人才流失严重、经费保障和监测用房面积不足、监测项目偏少、管理体系不健全,并结合实际提出了加强人才队伍建设、拓宽监测经费来源、提高监测分析能力和强化质量管理等对策建议.     

电子束辐照降解水中氯霉素的研究

本研究对氯霉素(CAP)在不同条件下的电子束辐照降解进行了研究.结果表明,电子束辐照可有效去除水中CAP,低浓度CAP在酸性条件下的辐照降解更为显著,且降解过程符合准一级动力学模型.通过添加不同的自由基清除剂,发现HO·在CAP降解中起关键作用,此外,CAP分子也会吸收辐照而发生分解.水中共存的阴离子和腐殖酸(HA)对CAP辐照降解均有抑制作用,这跟其与HO·的反应速率常数大小有关,并且反应速率越大,其抑制能力越强.CAP在去离子水中的去除率高于其他实际水体,但辐照剂量为4 k Gy时,污水厂污水过滤水和胶体浓缩液中的CAP也可分别去除89.1%和81.7%.利用GC-MS检测到辐照后溶液中有6种中间产物,主要是通过脱水、不对称中心断键和脱酰胺作用形成.此外,IC检测有Cl-、NO-3和NO-2的产生,并且TOC在一定程度上降低,说明部分CAP被矿化.     

Source analysis of particulate-phase polycyclic aromatic hydrocarbons in an urban atmosphere of a northern city in China

Particle-associated polycyclic aromatic hydrocarbon (PAH) concentrations were investigated at six sampling sites in the heating (February to March 2001) and nonheating (August to September 2001) periods in an industrial city in Northern China. Thirteen PAHs were measured. The total average concentrations (nanograms per meter cubed) of PAHs ranged between 78.93 and 214.63 during the heating period and from 31.48 to 102.26 in the nonheating period. Benzo(a)pyrene occurred at the highest level at a site near an industrial area but occurred at low concentrations far from the city center and industrial areas. In addition, ambient PAH profiles were studied. The five and six-ring species occurred in high fractions at the sampling site. By diagnostic ratio analysis, the major source at each sampling site in the city was coal combustion in the heating period; in the nonheating period, the major sources were relatively complex. Finally, the similarities among the six regions were assessed by principal component analysis, cluster analysis, and coefficient of divergence. These multivariate statistical analyses produced similar results, which agreed with the results from the diagnostic ratio analysis.     

Selected organochlorine pesticide and polychlorinated biphenyl residues in house dust in Singapore

Although the use of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) has been prohibited in Singapore since 1980, OCPs and PCBs still can be detected in the environment and represent a potential threat to public health. In this study, OCPs and PCBs were measured in house dust samples collected from 31 homes across the island-state of Singapore. Organochlorine pesticides, such as hexachlorocyclohexanes (HCHs), chlordanes and dichlorodiphenyltrichloroethanes (DDTs) were tested, with a range of 相似文献