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121.
废弃SCR脱硝催化剂的再生及其脱硝性能研究 总被引:1,自引:1,他引:0
对废弃脱硝催化剂处理后重新加工再生,研究了添加剂对其粉体成型和再生催化剂脱硝活性的影响,探讨了反应温度、空速、n(NH3)∶n(NO)摩尔比、氧含量、H2O和SO2对再生催化剂NH3选择性催化还原(SCR)NO的影响。结果表明:最佳再生条件是使用5%羧甲基纤维素和10%无机粘结剂辅助成型;废弃催化剂再生利用率高达90%;再生催化剂抗压强度为4.73 MPa,优于商用催化剂;空速5 000 h-1、氨氮摩尔比1、氧含量6%时,脱硝活性温度窗口为310450℃,350℃时活性最高为94%;350℃时,单独通入1 000×10-6SO2或10%H2O对再生催化剂活性均有一定抑制作用,最低活性分别为70%和81%,停止通入SO2或H2O后其活性逐渐恢复;同时通入1 000×10-6SO2和10%H2O,再生催化剂活性下降至63%并于1 h内保持相对稳定,停止通入SO2和H2O 2 h后,活性逐渐恢复到73%。 相似文献
122.
We used aerated systems to assess the influence of the bacterioplankton community on cyanobacterial blooms in algae/post-bloom of Lake Taihu, China. Bacterioplankton community diversity was evaluated by polymerase chain reaction-denaturing gradient gel electrophoresis(PCR-DGGE) fingerprinting. Chemical analysis and nitrogen dynamic changes illustrated that NH4+-N was nitrified to NO2-N and NO3-N by bacterioplankton. Finally, NH4+-N was exhausted and NO3-N was denitrified to NO2-N, while the accumulation of NO2-N indicated that bacterioplankton with completely aerobic denitrification ability were lacking in the water samples collected from Lake Taihu. We suggested that adding completely aerobic denitrification bacteria(to denitrify NO2-N to N2)would improve the water quality. PCR-DGGE and sequencing results showed that more than 1/3 of the bacterial species were associated with the removal of nitrogen, and Acidovorax temperans was the dominant one. PCR-DGGE, variation of nitrogen, removal efciencies of chlorophyll-a and canonical correspondence analysis indicated that the bacterioplankton significantly influenced the physiological and biochemical changes of cyanobacteria. Additionally, the unweighted pair-group method with arithmetic means revealed there was no obvious harm to the microecosystem from aeration. The present study demonstrated that bacterioplankton can play crucial roles in aerated ecosystems, which could control the impact of cyanobacterial blooms in eutrophicated fresh water systems. 相似文献
123.
Effects of physical and chemical characteristics of surface sediments in the formation of shallow lake algae-induced black bloom 总被引:12,自引:0,他引:12
Qiushi Shen Cheng Liu Qilin Zhou Jingge Shang Lei Zhang ChengXin Fan 《环境科学学报(英文版)》2013,25(12):2353-2360
Surface sediments are closely related to lake black blooms. The dissolved oxygen (DO) distribution and its penetration depth in surface sediments as well as the migration and transformation of redox sensitive elements such as Fe and S at the sediment-water interface are important factors that could influence the formation of the black bloom. In this study, dredged and undredged sediment cores with different surface properties were used to simulate black blooms in the laboratory. The Micro Profiling System was employed to explore features of the DO and ∑H2S distribution at the sediment-water interface. Physical and chemical characteristics in sediments and pore waters were also analyzed. The results showed that sediment dredging effectively suppressed the black blooms. In the undredged treatment, DO penetration depth was only 50 μm. Fe^2+ concentrations, ∑H2S concentrations, and ∑H2S production rates were remarkably higher in surface sediments and pore waters compared to control and dredged treatments. Furthermore, depletion of DO and accumulation of Fe^2+ and ∑H2S in surface sediments and pore waters provided favorable redox environments and necessary material sources for the blooms. The study results proved that physical and chemical characteristics in surface sediments are important factors in the formation of the black bloom, and could provide scientific guidance for emergency treatment and long-term pre-control of black blooms. 相似文献
124.
文章通过对PM2.5的基本组成、来源与影响因素的分析,构建中国PM2.5全过程管理体系,建立、完善PM2.5削减和控制长效机制,进而实现中国PM2.5管理。 相似文献
125.
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127.
臭氧是一种存在于地球臭氧层和近地面的气体,它对人类和环境是否有益取决于大气中存在的位置。高空臭氧层使人类免受紫外线伤害,而近地面臭氧是光化学烟雾产生的主要污染物,损害农作物、树木和其他植物生长,危害人体健康诱发儿童哮喘等疾病。本文结合2013年8月12日常州市出现的臭氧污染天气,利用气象和空气自动监测数据,对污染过程、变化特征和成因进行了分析。结果表明,在连续高温、太阳辐射强度大、风速低、大气扩散条件差等气象因素和臭氧前体物(NMHC)较高等不利条件下,易形成臭氧污染天气,导致空气质量下降。 相似文献
128.
本文应用东大别地区层析成像研究结果,对研究区重大地震事件的深部地壳结构特征进行了研究,结果表明:霍山地区的2次MS≥6.0级地震在深部地壳结构上具有一定的相似性;1970年以来的12次MS≥4.0地震在25 km深度的地壳速度结构特征比较接近。 相似文献
129.
Removal of phosphate by Fe-coordinated amino-functionalized 3D mesoporous
silicates hybrid materials
Phosphate removal from aqueous waste streams is an important approach to control the eutrophication downstream bodies of water.
A Fe(III) coordinated amino-functionalized silicate adsorbent for phosphate adsorption was synthesized by a post-grafting and metal
cation incorporation process. The surface structure of the adsorbent was characterized by X-ray di raction, N2 adsoropion/desoprotion
technique, and Fourier transform infrared spectroscopy. The experimental results showed that the adsorption equilibrium data were well
fitted to the Langmuir equation. The maximum adsorption capacity of the modified silicate material was 51.8 mg/g. The kinetic data
from the adsorption of phosphate were fitted to pseudo second-order model. The phosphate adsorption was highly pH dependent and
the relatively high removal of phosphate fell within the pH range 3.0–6.0. The coexistence of other anions in solutions has an adverse
e ect on phosphate adsorption; a decrease in adsorption capacity followed the order of exogenous anions: F?? > SO2?? 4 > NO??3 > Cl??. In
addition, the adsorbed phosphate could be desorbed by NaOH solutions. This silicate adsorbent with a large adsorption capacity and
relatively high selectivity could be utilized for the removal of phosphate from aqueous waste streams or in aquatic environment. 相似文献
130.
By using optical microscope, the microstructures of 5083/6082 friction stir welding (FSW) weld and parent materials were analyzed. Meanwhile, at ambient temperature and in 0.2 mol/L NaHS03 and 0.6 mol/L NaCl solutionby gravimetric test, potentiodynamic polarization curve test, electrochemical impedance spectra (EIS) and scanning electron microscope (SEM) observation, the electrochemical behavior of 5083/6082 friction stir welding weld and parent materials were comparatively investigated by gravimetric test, potentiodynamic polarization curve test, electrochemical impedance spectra (EIS) and scanning electron microscope (SEM) observation. The results indicated that at given processing parameters, the anti-corrosion property of the dissimilar weld was superior to those of the 5083 and 6082 parent materials. 相似文献