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281.
根据安全系统工程原理,探讨和提出了一种被当地试点所证明、可行的工业企业安全生产综合、简便的规范化管理方法。把国家有关安全生产法律法规有机地贯穿于基础规范管理工作过程之中;建立了动态性管理模式;为积极引导企业的安全管理工作,由事故管理向预防性管理,从行政管理向依法管理,由传统管理向技术性管理的方向转变,并为促进现代企业形成自主经营,相互制约,依法管理安全生产的运行机制提供了新思路 相似文献
282.
Research efforts dealing with chemical transportation in soils are needed to prevent damage to ground water. Methanol-containing solvents can increase the translocation of nonionic organic chemicals (NOCs). In this study, a general log-linear retention equation, log k' = log k'w - Sphi (Eq. [1]), was developed to describe the mobilities of NOCs in soil column chromatography (SCC). The term phi denotes the volume fraction of methanol in eluent, k' is the capacity factor of a solute at a certain phi value, and log k'w and -S are the intercept and slope of the log k' vs. phi plot. Two reference soils (GSE 17204 and GSE 17205) were used as packing materials, and were eluted by isocratic methanol-water mixtures. A model of linear solvation energy relationships (LSER) was applied to analyze the k' from molecular interactions. The most important factor determining the transportation was found to be the solute hydrophobic partition in soils, and the second-most important factor was the solute hydrogen-bond basicity (hydrogen-bond accepting ability), while the less important factor was the solute dipolarity-polarizability. The solute hydrogen-bond acidity (hydrogen-bond donating ability) was statistically unimportant and deletable. From the LSER model, one could also obtain Eq. [1]. The experimental k' data of 121 NOCs can be accurately explained by Eq. [1]. The equation is promising to estimate the solute mobility in pure water by extrapolating from lower-capacity factors obtained in methanol-water mixed eluents. 相似文献
283.
Spatial and temporal organic and heavy metal pollution at Mai Po Marshes Nature Reserve,Hong Kong 总被引:8,自引:0,他引:8
An intensive monthly sampling of water and sediments from 12 sites over 8 months covering wet and dry seasons at Mai Po Marshes Nature Reserve was conducted during June 1997-February 1998. Major organic (C, N and P) and heavy metal pollutants (Cd, Cr, Cu, Ni, Pb, Zn) water and sediment samples were examined. The results showed that Mai Po Marshes were severely polluted by organic matter and heavy metals, and the water from Deep Bay appeared to be the source of pollution. Up to 13-55% chance that the sediments of Mai Po Marshes were classified as moderately to seriously metal contaminated materials, according to the guideline set by Hong Kong Government. Empirical models describing organic matter and heavy metal spatial and seasonal dynamics in the water and sediments were formulated, based on data analysis. During wet season (June-October), more than 58% variations of total P can be explained by ortho-P in water, while ammonia-N explained up to 90% variations of total Kjeldahl nitrogen in water. Throughout the whole sampling period (June-February), there were significant correlations (p<0.01) between total organic C in water. pH in the sediments and salinity in water appeared to be important factors determining heavy metal mobility in sediments, while potential metal release from the sediments is a concern when any oxidizing processes such as flooding or dredging are imposed on sediments. 相似文献
284.
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286.
梁高勇 《中国个体防护装备》2007,(3):9-10
本文主要对机织物与非织造布复合材料的网络互穿结构进行了描述,并从材料选择、单体试制、复合工艺方面进行了实践,研制出了较高透气性能和剥离强度的复合材料。 相似文献
287.
基于道化学法的大型合成氨装置安全评价 总被引:1,自引:0,他引:1
根据道化学公司火灾、爆炸危险指数的基本原理。用VH6.0开发的安全评价软件DowSE1.0,对某大型合成氨装置进行安全评价,得出其安全措施补偿前后的火灾、爆炸指数F&EI以及危险暴露面积,危害系数,危险等级,实际可能财产损失程度等指数。结果表明。合成氨装置中实际最大可能财产损失值都没有超过200万美元,气化系统在合成氨装置中实际最大可能财产损失值占损失替换值比例高达53%,超过了10%的相对危险值界限。说明在引进国外技术时应注重其安全防范配套措施消化吸收,并结合实际采取切实可行的安全措施,降低合成氨装置的风险程度。 相似文献
288.
Z. Liang L. Bdard-Tremblay L. Bauwens 《Journal of Loss Prevention in the Process Industries》2007,20(4-6):570-577
The structure of the steady planar detonation wave is analyzed for three-step chain-branching kinetics consistent with hydrogen–air chemistry. The initiation and chain-branching steps are described by an Arrhenius rate. Both are thermally neutral, so that heat release is due to termination. The initiation rate is typically very low and very stiff. As a result, a small fraction of the reactant is consumed in the initiation region, which is very long but ends in an exponential chain-branching explosion. Next, the reactant is rapidly converted into chain-branching radicals, within a very thin zone, which ends when the concentration of the chain-branching radical reaches a peak, because of reactant depletion. Finally, the termination step consumes the chain-branching radicals and releases heat within a region thicker than the peak zone, but much thinner than the initiation region. The analysis is based upon two assumptions: that the chain-branching activation energy is high and that initiation is slow. The structure of the initiation and chain-branching zones is different for post-shock states within or outside the explosion region in the chain-branching diagram. In the former situation, chain-branching is already stronger than termination at the von Neumann point, and vice versa. In the no-explosion case, the initiation zone becomes very long, while the little chain-branching specie produced by initiation is directly converted into product by the termination step. Temperature increases slowly until reaching the explosion curve, when chain-branching becomes stronger than termination. The subsequent structure is similar to the explosion case. 相似文献
289.
ABSTRACT. Planning an optimal system of activities for generating economic goods and services within an existing natural resource capacity is a difficult problem to solve. A mathematical programming model with the capacity to check multiple resource demand and supply compatibility over many time periods was developed for the solution to this type of problem. The characteristics of natural resource supply and the demand of activities were utilized to reduce the number of time periods and to minimize the loss of the dynamic reality of the problem. Reduction in the number of time periods extended the capability of the model to the solution of complex resource planning problems without oversimplification. 相似文献
290.
Chao Jin Bingqing Liang Jingxin Li Fang Li 《Journal of Polymers and the Environment》2013,21(4):1088-1099
This work was aimed at researching the aerobic biodegradation of poly(p-dioxanone) (PPDO), a novel kind of degradable polymer material, by simulating real-life conditions in a laboratory-scale test, specified by the standard methods based on two biodegradation environments, composting and aqueous media. To measure and describe the biodegradability of PPDO, not only had carbon dioxide produced by respiratory metabolism of microorganism been measured, which determines the ultimate aerobic biodegradability of chemical compounds, but also the detailed results of biodegradation were further characterized by monitoring physical, chemical and thermal properties changes of test materials at different incubation times in the two media, confirmed by using the appropriate analytical techniques. Scanning electron microscopy was used to observe the surface morphology, and the thermal performance of PPDO was characterized by differential scanning calorimetry. The changes of molecular weight were detected by intrinsic viscosity ([η]) and gel permeation chromatography, and the variations of the molecular structure were monitored by the nuclear magnetic resonance and FT-IR. The results show that PPDO has outstanding character of biodegradation and may be more adapted for biodegrading in liquid medium than in composting. 相似文献