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21.
Kristin Quednow Wilhelm Püttmann 《Environmental science and pollution research international》2009,16(6):630-640
Background, aim, and scope
The present study focuses on the temporal concentration changes of four common organic pollutants in small freshwater streams of Hesse, Germany. The substances (tris(2-chloroethyl)phosphate (TCEP), the technical isomer mixture of 4-nonylphenol (NP), 2-(t-butylamino)-4-(ethylamino)-6-(methylthio)-s-triazine (terbutryn), and N,N-diethyl-m-toluamide (DEET)) are subject to differing regulations. Whereas the use of NP and the related nonylphenolethoxylates (NPEOs) are almost completely banned under EU directive 2003/53/EC, the herbicide terbutryn is only restricted for use as a herbicide in the majority of member states of the European Union (EU). In contrast, TCEP and DEET are not regulated by legislation, but have been replaced in some products through consumer pressure. The impact of regulation on the environmental concentrations of these pollutants is discussed. 相似文献22.
A. Tieber H. Lettner P. Bossew A. Hubmer B. Sattler W. Hofmann 《Journal of environmental radioactivity》2009
Cryoconites are airborne sediments which accumulate on the surface of glaciers. In samples of cryoconites a temperate Austrian glacier high activity concentrations of anthropogenic radionuclides were found, which stem from global and Chernobyl fallouts. Radionuclides identified were 137Cs, 134Cs, 238Pu, 239+240Pu, 90Sr, 241Am, 60Co, 154Eu, 207Bi, and 125Sb. 相似文献
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Summary. A diverse group of brown seaweeds produce bouquets of C11 metabolites, some of which act as pheromones that cue gamete release or attract sperm to eggs following release. We demonstrate
that these C11 metabolites and their degradation products also frequently and strongly deter feeding by the herbivorous amphipod Ampithoe longimana, but rarely by the herbivorous sea urchin Arbacia punctulata. Across the range of concentrations tested, seven of twelve C11 metabolites or mixtures that we tested deterred feeding by the amphipod, but only two of eleven deterred the sea urchin.
For those compounds where we could rigorously contrast the magnitude of deterrence against the amphipod with the magnitude
of deterrence against the urchin, the amphipod was deterred significantly more than the urchin by five of six metabolites.
Thus, C11 compounds were more frequently and more strongly deterrent to the amphipod than to the sea urchin. These findings for C11 metabolites conflict with previous investigations, where other classes of seaweed chemical defenses have been shown to deter
feeding by large mobile herbivores like urchins and fishes but to be relatively ineffective against mesograzers, especially
the species of amphipod that we used here. Our results suggest that C11 metabolites are unusual among the known seaweed chemical defenses in that they are especially effective against mesograzers,
which often consume seaweed spores, zygotes, and juveniles. The high concentrations of C11 metabolites in brown algal eggs could allow these defenses to be especially important in defending gametes, zygotes, or young
sporelings from herbivorous mesograzers.
Received 26 February 1998; accepted 9 April 1998. 相似文献
25.
Corina Oldenburg Sudha Kanaujia Dieter Spiteller Neil J. Oldham Wilhelm Boland Karl-Ernst Kaissling 《Chemoecology》2001,11(4):183-190
Summary. Benzoic acid is a known stimulant of olfactory receptor cells in trichoid sensilla on the antennae of adult females of Bombyx mori. Exposure of freshly excised antennae, from B. mori females and males, to vapours of [14C]-benzoic acid revealed that the adsorbed acid is rapidly metabolized (15% conversion in 10 s), suggesting the presence of
a highly active enzymatic system. The major product could be identified as N-benzoylserine by use of [2H5]-benzoic acid, and mass spectrometry linked to a gas chromatograph (GC-MS) or a liquid chromatograph (LC-MS), for analysis
of the metabolites. The conjugation of benzoic acid with an amino acid apparently represents a novel mode for the rapid deactivation
of odorant molecules.
Received 26 March 2001. 相似文献
26.
The presence of the anesthetic lidocaine (LDC), the analgesic tramadol (TRA), the antidepressant venlafaxine (VEN) and the metabolites O-desmethyltramadol (ODT) and O-desmethylvenlafaxine (ODV) was investigated in wastewater treatment plant (WWTP) effluents, in surface waters and in groundwater. The analytes were detected in all effluent samples and in only 64% of the surface water samples. The mean concentrations of the analytes in effluent samples from WWTPs with wastewater from only households and hospitals were 107 (LDC), 757 (TRA), 122 (ODT), 160 (VEN) and 637 ng L(-1) (ODV), while the mean concentrations in effluents from WWTPs treating additionally wastewater from pharmaceutical industries as indirect dischargers were for some pharmaceuticals clearly higher. WWTP effluents were identified as important sources of the analyzed pharmaceuticals and their metabolites in surface waters. The concentrations of the compounds found in surface waters ranged from 相似文献
27.
Hussain Majid Khan Alam Pierre Madl Werner Hofmann 《Environmental monitoring and assessment》2013,185(6):5265-5276
Ambient aerosol concentrations along the roadside of metropolitan cities of Pakistan were measured using a Grimm 1.109 dust monitor. Considering the high ambient aerosol concentrations, regional lung deposition of aerosol particles in the human respiratory tract was calculated to assess extent of exposure. Lung deposition was computed in terms of mass concentration and the associated surface area for 12 male traffic wardens using the latest version of the stochastic lung deposition code Inhalation, Deposition, and Exhalation of Aerosols in the Lung. The results have revealed 4 to 10 times higher concentrations than recommended by WHO guidelines. The deposition results derived from the model disclose that extrathoracic deposition is in the range of 22 to 28 % with total lung deposition ranging from 40 to 44 % for the scanned particle window of 0.25–10 μm. Considering an average 8-h shift per day and an average breathing rate of 1.3 m3?h?1, it is approximated that in a worker, up to 1.6 mg of inhalable particle mass can deposit per day. 相似文献
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