Altitude profiles of total chlorinated paraffins in humus and spruce needles from the Alps (MONARPOP)

Chlorinated paraffins (CPs) are toxic, bioaccumulative, persistent, and ubiquitously present in the environment. CPs were analyzed in humus and needle samples, which were taken within the Monitoring Network in the Alpine Region for Persistent and other Organic Pollutants (MONARPOP) at sampling sites of 7 different altitude profiles in the Alps. Gas chromatography combined with electron ionization tandem mass spectrometry (EI-MS/MS) was used for the determination of total CPs (sum of short, medium and long chain CPs). CPs were found in all samples; the concentrations varied between 7 and 199 ng g⁻¹ dry weight (dw) and within 26 and 460 ng g⁻¹ dw in humus and needle samples, respectively. A clear vertical tendency within the individual altitude profiles could not be ascertained. Within all altitude profiles, elevated concentrations were observed in humus samples taken between 700 and 900 m and between 1300 and 1500 m. In the needle samples no similar correlation could be observed due to higher variation of the data.     

Seasonal lipid dynamics of the copepods <Emphasis Type="Italic">Pseudocalanus minutus</Emphasis> (Calanoida) and <Emphasis Type="Italic">Oithona similis</Emphasis> (Cyclopoida) in the Arctic Kongsfjorden (Svalbard)

Seasonal lipid dynamics of various developmental stages were investigated in Pseudocalanus minutus and Oithona similis. For P. minutus, the dominance of 16:1(n−7), 16:4(n−3) and 20:5(n−3) fatty acids indicated a diatom-based nutrition in spring, whereas 22:6(n−3), 16:0, 18:2(n−6) and 18:1(n−9) pointed to a flagellate-based diet during the rest of the year as well as omnivorous/carnivorous low-level feeding during winter. The shorter-chain fatty alcohols 14:0 and 16:0 prevailed, also reflecting biosynthetic processes typical of omnivores or carnivores. Altogether, the lipid signatures characterized P. minutus as an opportunistic feeder. In contrast, O. similis had consistently high amounts of the 18:1(n−9) fatty acid in all stages and during all seasons pointing to a generally omnivorous/carnivorous/detritivorous diet. Furthermore, the fatty alcohol 20:1(n−9) reached high percentages especially in adult females and males, and feeding on Calanus faecal pellets is suggested. Fatty alcohols, as wax ester moieties, revealed significant seasonal variations in O. similis and a seasonal trend towards wax ester accumulation in autumn in P. minutus. P. minutus utilized its lipid deposits for development in the copepodite stages III and IV and for gonad maturation in CV and females during the dark season. However, CVs and females depended on the spring phytoplankton bloom for final maturation processes and reproduction. O. similis fueled gonad maturation and egg production for reproduction in June by wax esters, whereas reproduction in August/September co-occurred with the accumulation of new depot lipids. Both species revealed significantly higher wax ester levels in deeper (>50 m) as compared to surface (0–50 m) dwelling individuals related to a descent prior to overwintering.     

Environmental perspectives of pupils: the development of an attitude and behaviour scale

Summary The object of this study was to construct a measurement instrument to assess two different environmental world views of adolescents and, additionally, to address the adolescents' verbal commitment and actual behaviour. Using a multiple-choice questionnaire the instrument was designed to identify and measure the existing factors that underlie concern for ecological/environmental problems and behaviour towards environment/nature in the age group of 10 to 16 year old pupils. Within the traditional tripartite model covering cognitive, affective and behavioural components the study selected items that made up the majority of corresponding subscales from various previous studies. Using factor analysis the configuration of the scale's dimensionality was stated. Based on the responses of approximately 2000 Bavarian pupils, subscales were extracted via factor analysis and, subsequently, addressed to different segments of environmental concern ranging from attitudes to verbal commitment and actual behaviour. Correlation coefficients and the standardized Cronbach's -values were also surveyed. Additionally, a Kruskal-Wallis analysis was applied in order to locate the subscales' influences on sociodemographic variables such as gender and age and self-reported variables such as the pleasure of being a pupil and school performance. The further purpose of the present study is to provide the basis for follow-up comparisons of preferences and values in pupils within other countries.

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Résumé Le but de la présente étude est la réalisation d'un système de mesure pour l'évaluation de différents niveaux de conscience par rapport à la nature et à la protection de l'environnement, ainsi que des comportements actuels ou envisagés. Le système de mesure s'appuie sur un questionnaire à choix multiples pour évaluer les différents facteurs qui déterminent les niveaux de conscience et les comportements correspondants chez les adolescents de 10 à 16 ans. Dans le cadre du modèle à trois niveaux, qui comprend des composantes cognitives, affectives et comportementales, un grand nombre d'items, en partie issus d'études antérieures, ont été sélectionnés pour former les sous-catégories nécessaires. La configuration des catégories a été garantie par une analyse factorielle.Sur la base des réponses d'environ 2000 élèves, des sous-catégories ont été définies, qui vont depuis les positions de départ jusqu'au comportement actuel. En outre, nous avons défini les coefficients de corrélation, ainsi que les valuers Cronback-Alpha, et une analyse des régressions a été effectuée, qui prend en compte les influences, par exemple, des variables sociodémographiques comme le sexe et l'âge, des résultats scolaires ou de la manière dont l'école est perçue par chacun.La présente étude représente la base aussi bien pour des investigations comparatives entre pays, que pour l'évaluation de l'influence d'un enseignement extra-scolaire adopté.

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Dr. Franz Bogner is the senior author to whom correspondence should be addressed. Manfred Wilhelm is based at the Institut für Medizinische Statistik, Technische Universität, Ismaninger Straße 22, D-81675 München, Germany.