The applications of chlorine have been broadly used in many industrial products, such as bleaching agents, synthetic rubbers, plastics, disinfectants, iron chlorides, fire refractory materials, insecticides, and anti-freezers, etc. According to the Taiwan Environmental Protection Administration (TEPA), more than 30 thousand tons were used in the year 2000. In addition, there were more than 12 reported incidents from 2000 to 2003—mostly on using chlorine as disinfectants (five) and as process agents (four).
This study investigated 15 chlorine operation plants in central Taiwan. These chlorine usages included bleaching agents, disinfectants, iron chloride, synthesizing rubber plastics, and others. Thirteen plants were located in the industrial parks and two were in or near residential zones. The consequence analysis were used three different methods to analyze the worst-case scenarios (WCSs) and alternative release case scenarios (ACSs) in order to compare impact zones for applying various active and passive mitigation systems, such as confined space, scrubber, water-spray, and so no. For two plants in or near residential zones, multi-layers mitigation systems and operation limits should be implemented in order to enforce more stringent protection measures. However, there was no specific regulation for chlorine plants operated at different locations, such as industrial parks or residential zones. In order to reduce chemical accidents and their impacts on public safety, our results suggest that source mitigation/management and warning systems should be adopted simultaneously. 相似文献
As part of the program monitoring the ecosystem health of Moreton Bay, Queensland, Australia, we developed a means for assessing
ecosystem health that allows quantitative evaluation and spatial representations of the assessments. The management objectives
for achieving ecosystem health were grouped into ecosystem objectives, water quality objectives, and human health objectives.
For the first two groups, aspects of the ecosystem (e.g., trophic status) were identified, and an indicator was chosen for
each aspect. Reference values for each indicator were derived from management objectives and compared with the mapped survey
values. Subregions for which the indicator statistic was equal to or better than the assigned reference value are referred
to as “compliant zones.” High-resolution surface maps were created from spatial predictions on a fine hexagonal grid for each
of the indicators. Eight reporting subregions were established based on the depth and predicted residence times of the water.
Within each reporting subregion, the proportion that was compliant was calculated. These results then were averaged to create
an integrated ecosystem health index. The ratings by a team of ecosystem experts and the calculated ecosystem health indices
had good correspondence, providing assurance that the approach was internally consistent, and that the management objectives
covered the relevant biologic issues for the region. This method of calculating and mapping ecosystem health, relating it
directly to management objectives, may have widespread applicability for ecosystem assessment. 相似文献
Zerovalent iron (ZVI) has been widely used in the removal of environmental contaminants from water. In this study, ZVI was used to remove selenate [Se(VI)] at a level of 1000 microg L(-1) in the presence of varying concentrations of Cl-, SO(2-)4, NO(-)3, HCO(-)3, and PO(3-)4. Results showed that Se(VI) was rapidly removed during the corrosion of ZVI to iron oxyhydroxides (Fe(OH)). During the 16 h of the experiments, 100 and 56% of the added Se(VI) was removed in 10 mM Cl- and SO(2-)4 solutions under a closed contained system, respectively. Under an open condition, 100 and 93% of the added Se(VI) were removed in the Cl- and SO(2-)4 solutions, respectively. Analysis of Se species in ZVI-Fe(OH) revealed that selenite [Se(IV)] and nonextractable Se increased during the first 2 to 4 h of reaction, with a decrease of Se(VI) in the Cl- experiment and no detection of Se(VI) in the SO(2-)4 experiment. Two mechanisms can be attributed to the rapid removal of Se(VI) from the solutions. One is the reduction of Se(VI) to Se(IV), followed by rapid adsorption of Se(IV) to Fe(OH). The other is the adsorption of Se(VI) directly to Fe(OH), followed by its reduction to Se(IV). The results also show that there was little effect on Se(VI) removal in the presence of Cl- (5, 50, and 100 mM), NO(-)3 (1, 5, and 10 mM), SO(2-)4 (5 mM), HCO(-)3 (1 and 5 mM), or PO(3-)4 (1 mM) and only a slight effect in the presence of SO(2-)4 (50 and 100 mM), HCO(-)3 (10 mM), and PO(3-)4 (5 mM) during a 2-d experiment, whereas 10 mM PO(3-)4 significantly inhibited Se(VI) removal. This work suggests that ZVI may be an effective agent to remove Se from Se-contaminated agricultural drainage water. 相似文献
The restoration of river environments has been of growing importance to river management and planning in the UK. The extension of ecological restoration to floodplains as well as river channels is more complex, partly because of the range of stakeholders and the diversity of relevant management institutions. This paper draws on a qualitative survey of river managers in the UK to identify institutional factors relevant to the success or failure of floodplain restoration projects. 相似文献
ABSTRACT: The concentrations of iron and sulfate in community water supplies are a concern for a number of areas in southwestern Minnesota. This study used the contingent valuation method to determine how much consumers would be willing to pay to improve their drinking water quality. On average, individuals were willing to pay US$5.25 per month (in 1995 U.S. dollars) to reduce the level of iron and US$4.33 per month to reduce the level of sulfate in their water to the USEPA's secondary standards for drinking water quality. Respondents with negative perceptions of their drinking water quality were willing to pay more to improve water quality. The aggregate annual willingness to pay (WTP) for all consumers in community water systems in southwestern Minnesota that were out of compliance with water quality standards were estimated to be US$2.4 million and US$2.0 million (in 1995 dollars) for reducing the levels of iron and sulfate, respectively. Yet the total WTP of consumers who use small community water systems may not be enough to pay the full cost of providing improved water in those systems. Economies of scale in water treatment and difficulties in financing improvements mean that technical innovation, government assistance, or institutional changes may be needed to improve water quality in these areas. 相似文献
In this paper, we describe a model designed to simulate seasonal dynamics of warm and cool season grasses and forbs, as well as the dynamics of woody plant succession through five seral stages, in each of nine different plant communities on the Rob and Bessie Welder Wildlife Refuge. The Welder Wildlife Refuge (WWR) is located in the Gulf Coastal Prairies and Marshes ecoregion of Texas. The model utilizes and integrates data from a wide array of research projects that have occurred in south Texas and WWR. It is designed to investigate the effects of alternative livestock grazing programs and brush control practices, with particular emphasis on prescribed burning, the preferred treatment for brush on the WWR. We evaluated the model by simulating changes in the plant communities under historical (1974-2000) temperature, rainfall, livestock grazing rotation, and brush control regimes, and comparing simulation results to field data on herbaceous biomass and brush canopy cover collected on the WWR over the same period. We then used the model to simulate the effects of 13 alternative management schemes, under each of four weather regimes, over the next 25 years. We found that over the simulation period, years 1974-2000, the model does well in simulating the magnitude and seasonality of herbaceous biomass production and changes in percent brush canopy cover on the WWR. It also does well in simulating the effects of variations in cattle stocking rates, grazing rotation programs, and brush control regimes on plant communities, thus providing insight into the combined effects of temperature, precipitation, cattle stocking rates, grazing rotation programs, and brush control on the overall productivity and state of woody plant succession on the WWR. Simulation of alternative management schemes suggests that brush canopy removal differs little between summer and winter prescribed burn treatments when precipitation remains near the long-term average, but during periods of low precipitation canopy removal is greater under winter prescribed burning. The model provides a useful tool to assist refuge personnel with developing long-term brush management and livestock grazing strategies. 相似文献
Conserving freshwater habitats and their biodiversity in the Amazon Basin is a growing challenge in the face of rapid anthropogenic changes. We used the most comprehensive fish-occurrence database available (2355 valid species; 21,248 sampling points) and 3 ecological criteria (irreplaceability, representativeness, and vulnerability) to identify biodiversity hotspots based on 6 conservation templates (3 proactive, 1 reactive, 1 representative, and 1 balanced) to provide a set of alternative planning solutions for freshwater fish protection in the Amazon Basin. We identified empirically for each template the 17% of sub-basins that should be conserved and performed a prioritization analysis by identifying current and future (2050) threats (i.e., degree of deforestation and habitat fragmentation by dams). Two of our 3 proactive templates had around 65% of their surface covered by protected areas; high levels of irreplaceability (60% of endemics) and representativeness (71% of the Amazonian fish fauna); and low current and future vulnerability. These 2 templates, then, seemed more robust for conservation prioritization. The future of the selected sub-basins in these 2 proactive templates is not immediately threatened by human activities, and these sub-basins host the largest part of Amazonian biodiversity. They could easily be conserved if no additional threats occur between now and 2050. 相似文献