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Bernhardt A  Ruck W 《Chemosphere》2004,57(10):1563-1570
The pesticide contamination of water samples collected in and nearby a beech forest in northern Germany was evaluated. For this purpose, a method for the collection of water samples from stemflow and throughfall of beeches (Fagus sylvatica L.) and rainfall was developed in response to the demands for the analysis of organic contaminants in water samples. Furthermore a sensitive and selective multiresidue method was developed to determine 18 pesticides, frequently used in Germany, in aqueous samples. The samples collected were taken from the stemflow, the crown throughfall and the rainfall between May and November 2001. Analysis based on reversed-phase liquid chromatography with a pneumatically assisted electrospray mass spectrometer followed a solid phase extraction using C-18 extraction cartridges. Isoproturon, metolachlor, prosulfocarb and terbuthylazine were found during and shortly after their application period. In rainfall metolachlor, terbuthylazine and prosulfocarb were detectable in concentrations between 5 and 65 ng l(-1) and isoproturon in concentrations between 20 and 360 ng l(-1) respectively. In most of the samples, concentrations of those four pesticides were higher and detectable for a longer time in stemflow than in rainfall. Crown throughfall samples were collected from the end of August to November. Absolute deposition of isoproturon to forest soil were up to 70 times higher in comparison to rainwater samples.  相似文献   
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There are 109±0.5 neutron stars in the Galaxy. They are born in supernova explosions. Isolated neutron stars are observed as (radio-)pulsars, in some cases also as γ-ray pulsars and as IR-, optical and X-ray pulsars. Binary neutron stars, when accreting mass from their companion, become flickering, periodic and/or bursting X-ray sources, and probably also γ-ray bursters. They may all derive from binary star systems. The masses of population-I-neutron stars are compatible with (1.4 ±0.2)M ; their surface magnetic fields fall almost exclusively within 1012.2 and 1013.2 Gauss (at birth). The radii of population-II-neutron stars are (10 -3 +6 )km. Even in exotic sources like SS 433 and Cyg X-1, the compact core may well be a neutron star.  相似文献   
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Rapid test methods have been developed to classify waste. These procedures includes rapid elution and analytical determination methods for the detection of such elements as copper, nickel and zinc. Test kits for matter analysis (with a time requirement of about 30 minutes) have been modified with regard to the matrix waste. A comparison between such rapid testing methods and standard procedures using real samples leads to a similar waste classification. The reduction in time and costs via rapid assay methods allows multiple determinations of wastes to consequently increase the reliability of results from heterogeneous samples. The simple and rapid employment of these tests also makes an “on-site” performance possible.  相似文献   
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