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91.
Bernhardt A  Ruck W 《Chemosphere》2004,57(10):1563-1570
The pesticide contamination of water samples collected in and nearby a beech forest in northern Germany was evaluated. For this purpose, a method for the collection of water samples from stemflow and throughfall of beeches (Fagus sylvatica L.) and rainfall was developed in response to the demands for the analysis of organic contaminants in water samples. Furthermore a sensitive and selective multiresidue method was developed to determine 18 pesticides, frequently used in Germany, in aqueous samples. The samples collected were taken from the stemflow, the crown throughfall and the rainfall between May and November 2001. Analysis based on reversed-phase liquid chromatography with a pneumatically assisted electrospray mass spectrometer followed a solid phase extraction using C-18 extraction cartridges. Isoproturon, metolachlor, prosulfocarb and terbuthylazine were found during and shortly after their application period. In rainfall metolachlor, terbuthylazine and prosulfocarb were detectable in concentrations between 5 and 65 ng l(-1) and isoproturon in concentrations between 20 and 360 ng l(-1) respectively. In most of the samples, concentrations of those four pesticides were higher and detectable for a longer time in stemflow than in rainfall. Crown throughfall samples were collected from the end of August to November. Absolute deposition of isoproturon to forest soil were up to 70 times higher in comparison to rainwater samples.  相似文献   
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Large crowds in parks can be a problem for park managers and visitors. However, perceptions of crowding are difficult to measure due to coping mechanisms deployed by park visitors. Furthermore, perceptions of crowding should not be measured in isolation, but rather as part of a suite of conditions that comprise the visitors’ outdoor experience. We used a dichotomous choice experiment with visual images and eight attributes to estimate park users’ utilities associated with their visitor experience in Garibaldi Provincial Park in British Columbia, Canada. Our visual method allowed us to control for background view and compare user preferences on hiking trails with preferences at final destinations. We find that utilities are more sensitive to crowding at viewpoints than to other aspects of the outdoor experience. Thus, visitor satisfaction and crowding perceptions are more likely to be defined by where visitors have these encounters rather than the total number of encounters.  相似文献   
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ABSTRACT: Analyses of cumulative impacts to riparian systems is an important yet elusive goal. Previous analyses have focused on comparing the number of hectares impacted to the number of hectares restored, without addressing the loss of riparian function or the effect of the spatial distribution of impacts. This paper presents an analysis of the spatial distribution of development‐related impacts to riparian ecosystems, that were authorized under Section 404 of the Clean Water Act. Impacts on habitat structure, contiguity, and landscape context were evaluated using functional indices scaled to regional reference sites. Impact sites were mapped using GIS and analyzed for spatial associations. Positive spatial autocorrelation (i.e. clustering of impact sites) resulted from the piecemeal approach to impact assessment, which failed to prevent cumulative impacts. Numerous small projects in close proximity have resulted in adverse impacts to entire stream reaches or have fragmented the aquatic resources to a point where overall functional capacity is impaired. Additionally, the ecological functions of unaffected areas have been diminished due to their proximity to degraded areas. A proactive approach to managing cumulative impacts is currently being used in Orange County, California as part of a Corps of Engineers sponsored Special Area Management Plan (SAMP). The SAMP process is evaluating the ecological conditions and physical processes of the study watersheds and attempting to plan future development in a manner that will guard against cumulative impacts.  相似文献   
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