军绿有机涂层破损腐蚀行为研究

目的研究不同破损程度下军绿有机涂层的腐蚀行为,确定破损率对其防护性能变化的影响。方法通过人工制作不同的破损率,并利用电化学阻抗谱技术,研究不同破损程度下军绿有机涂层的电化学特征。结果根据不同破损程度下的军绿有机涂层的电化学特征,确定了涂层从完好到失效的四个阶段,初始完好阶段(破损率K≤0.0004%)、破损增大阶段(0.0016%K≤0.04%)、破损过大阶段(0.16%K≤1%)和失效阶段(4%K≤16%)。结论破损率K为0.04%的点是该涂层防护性能急转直下的转折点,因此破损率K大于0.04%时,应及时对车辆表面涂层进行修补和防护。     

2013 — 2016年西安市臭氧时空变化特性与影响因素

臭氧污染主要是由前体物氮氧化物（NO_x）和挥发性有机物（VOC）的过量排放引起的,通过NO_x/?SO₂的比值可得知西安地区已经受到了光化学烟雾型污染的影响,大气中臭氧含量与NO_x的含量相关性较高;西安13个站点的8小时平均浓度分布变化大体可分为单峰变化和持续递减类型,浓度主要集中在0?—?90 μg???m^?3,不同站点臭氧含量相差较大;2013?—?2016年,高新西区臭氧超标天数最多,为146天,是超标天数最少的兴庆小区的2倍多。高浓度臭氧主要出现在高温度、低湿度、实时风向为东南风或南风的天气。此外,治理臭氧污染必须限制机动车尾气排放,同时研究表明来自秦岭的植物VOC对于西安臭氧浓度影响很大。     

三峡库区蓄水初期大宁河重金属食物链放大特征研究

三峡库区蓄水后重金属在库区沉积物中累积,为了解由此带来的鱼类重金属富集放大风险,于2012年3月以库区支流大宁河为例,采集16种代表性鱼类,利用稳定同位素技术对鱼类间营养关系和Cr、Ni、Cu、Zn、Pb、Cd、As和Hg等重金属元素在食物链中的生物放大情况进行了研究.结果表明,大部分重金属在鱼体中处于较低水平,但在不同种类鱼体中含量差异显著.鱼体样品δ13C与鱼类生活水层关系密切,分布范围为-22.80‰~-28.97‰,水体上层鱼类δ13C值较低,而水体底层鱼类δ13C值较高;而δ15N受鱼类食性影响明显,范围为6.41‰~13.88‰.在食物链的传递过程中,鱼体Hg浓度随营养等级的升高而显著增大,但放大效率较低.除Hg外的金属元素与δ15N的关系均不显著,未出现明显生物放大.但小个体鱼类体内金属含量较高,存在潜在污染风险.     

苦草(Vallisneriaspiralis)对城市缓流河道黑臭底泥理化性质的影响

以苦草(Vallisneria spiralis)和城市缓流河道黑臭底泥为研究对象采用模拟实验方法,探讨了苦草对城市缓流河道黑臭底泥理化性质的影响.结果表明,苦草可以显著改善城市缓流污染河道底泥氧化还原环境.实验期间表层底泥Eh从-70 mV升高至90 mV;减少致黑物质亚铁的含量,实验组表层底泥降低25%,而对照却升高38%;促进铁、硫的自然循环,防止亚铁、H2S的累积;明显改善底泥黑臭现象,实验组表层底泥第7 d出现约3 mm厚灰黄色氧化层,氧化层随时间推移逐渐增厚,第28 d厚度为11 mm.该氧化层无明显恶臭气味.对照则在实验第14 d出现1 mm氧化层并维持至实验结束,期间恶臭气味未消减;种植苦草可显著提高沉积物致密程度,降低底泥含水率,有效改善表层底泥流动状态,且在段头浜、河湾、人工湿地景观等处不影响防汛等功能,对减少河道底泥冲刷迁移和抑制黑臭物质悬浮具有积极的生态学意义.     

白洋淀水体和沉积物中碱性磷酸酶活性的时空分布及其影响因素

2011—2012年期间,以白洋淀8个国控监测点为采样点,通过对水体和沉积物碱性磷酸酶活性（APA）和理化参数的分析,揭示了白洋淀碱性磷酸酶活性时空分布特征及影响因素.结果表明,白洋淀碱性磷酸酶活性具有明显的时空分布规律,春季碱性磷酸酶活性增大,夏秋季达最高值,冬季最低,富营养化程度高的样点碱性磷酸酶活性较高.相关性分析结果表明,水体碱性磷酸酶活性与氨氮和氮磷比显著负相关（p<0.05）,与温度、总磷、浮游植物密度显著正相关（p<0.01）.推测浮游植物密度可能是影响水体碱性磷酸酶活性的主要因素;沉积物中碱性磷酸酶活性可能主要与微生物相关,与沉积物总磷含量显著正相关（p<0.05）.水体和沉积物中碱性磷酸酶活性与采样点富营养化程度一致,可以作为白洋淀富营养化的评价指标.     

Pollination syndromes ignored: importance of non-ornithophilous flowers to Neotropical savanna hummingbirds

Generalization prevails in flower–animal interactions, and although animal visitors are not equally effective pollinators, most interactions likely represent an important energy intake for the animal visitor. Hummingbirds are nectar-feeding specialists, and many tropical plants are specialized toward hummingbird-pollination. In spite of this, especially in dry and seasonal tropical habitats, hummingbirds may often rely on non-ornithophilous plants to meet their energy requirements. However, quantitative studies evaluating the relative importance of ornithophilous vs. non-ornithophilous plants for hummingbirds in these areas are scarce. We here studied the availability and use of floral resources by hummingbirds in two different areas of the Cerrado, the seasonal savannas in Central Brazil. Roughly half the hummingbird visited plant species were non-ornithophilous, and these contributed greatly to increase the overall nectar availability. We showed that mean nectar offer, at the transect scale, was the only parameter related to hummingbird visitation frequency, more so than nectar offer at single flowers and at the plant scale, or pollination syndrome. Centrality indices, calculated using hummingbird–plant networks, showed that ornithophilous and non-ornithophilous plants have similar importance for network cohesion. How this foraging behaviour affects reproduction of non-ornithophilous plants remains largely unexplored and is probably case specific, however, we suggest that the additional energy provided by non-ornithophilous plants may facilitate reproduction of truly ornithophilous flowers by attracting and maintaining hummingbirds in the area. This may promote asymmetric hummingbird–plant associations, i.e., pollination depends on floral traits adapted to hummingbird morphology, but hummingbird visitation is determined more by the energetic "reward" than by pollination syndromes.     

黄河三角洲碱蓬湿地土壤有机碳及其组分分布特征

应用物理分组方法研究了黄河三角洲典型碱蓬湿地土壤有机碳及其组分分布特征.结果表明,研究区土壤重组有机碳是土壤有机碳的主要组成部分,土壤重组有机碳含量、土壤颗粒有机碳含量与土壤总有机碳含量都显著正相关.研究区土壤轻组组分比例和含量范围分别在0.008%～0.15%和0.10～0.40 g·kg-1,颗粒有机碳分配比例范围为8.83%～30.58%,说明黄河三角洲碱蓬湿地土壤有机碳中非保护性组分较低,碳库相对稳定.     

Cost-performance analysis of nutrient removal in a full-scale oxidation ditch process based on kinetic modeling

A full-scale oxidation ditch process for treating sewage was simulated with the ASM2d model and optimized for minimal cost with acceptable performance in terms of ammonium and phosphorus removal. A unified index was introduced by integrating operational costs (aeration energy and sludge production) with effluent violations for performance evaluation. Scenario analysis showed that,in comparison with the baseline (all of the 9 aerators activated), the strategy of activating 5 aerators could save aeration energy significantly with an ammonium violation below 10%. Sludge discharge scenario analysis showed that a sludge discharge flow of 250–300 m3/day (solid retention time (SRT), 13–15 days) was appropriate for the enhancement of phosphorus removal without excessive sludge production. The proposed optimal control strategy was: activating 5 rotating disks operated with a mode of "111100100" ( "1"represents activation and "0" represents inactivation) for aeration and sludge discharge flow of 200 m3/day (SRT, 19 days). Compared with the baseline, this strategy could achieve ammonium violation below 10% and TP violation below 30% with substantial reduction of aeration energy cost (46%) and minimal increment of sludge production (< 2%). This study provides a useful approach for the optimization of process operation and control.     

Preparation of MgO/B2O3 coatings by plasma spraying on SUS304 surface and effects of heat-resistant

This study mainly deals with the preparation of MgO/B₂O₃ coatings by plasma spraying on the SUS304 surface and the effects of heatresistant. The power materials of low thermal conductivity were selected to control the heat divergent performance of high temperature parts. The reticular micro-structure between the cover thermal layer and the substrate was prepared by using the plasma spraying method. The powder mixture of MgO and B₂O₃ were selected as spraying materials and the SUS304 was used as the substrate material. The MgO/B₂O₃ coating was prepared on the surface of the SUS304 to provide better cover thermal performance. The properties of the microstructures and the morphologies were studied by Optical Microscope, Scanning Electron Microscope, Electron Probe Microanalyzer, and X-ray Diffraction. The results showed that the cover thermal performance has been improved.     

Homogeneous and heterogeneous reactions of anthracene with selected atmospheric oxidants

The reactions of gas-phase anthracene and suspended anthracene particles with O3 and O3-NO were conducted in a 200-L reaction chamber, respectively. The secondary organic aerosol (SOA) formations from gas-phase reactions of anthracene with O3 and O3-NO were observed. Meanwhile, the size distributions and mass concentrations of SOA were monitored with a scanning mobility particle sizer (SMPS) during the formation processes. The rapid exponential growths of SOA reveal that the atmospheric lifetimes of gas-phase anthracene towards O3 and O3-NO are less than 20.5 and 4.34 hr, respectively. The particulate oxidation products from homogeneous and heterogeneous reactions were analyzed with a vacuum ultraviolet photoionization aerosol time-of-flight mass spectrometer (VUV-ATOFMS). Gas chromatograph/mass spectrometer (GC/MS) analyses of oxidation products of anthracene were carried out for assigning the time-of-flight (TOF) mass spectra of products from homogeneous and heterogeneous reactions. Anthrone, anthraquinone, 9,10- dihydroxyanthracene, and 1,9,10-trihydroxyanthracene were the ozonation products of anthracene, while anthrone, anthraquinone, 9-nitroanthracene, and 1,8-dihydroxyanthraquinone were the main products of anthracene with O3-NO.