决策树模型在水环境监测网络中选取代表性样点的应用

地表水体中的硝酸盐污染已经成为全球关注的热点环境问题之一。现今,国内外均建立了相关的监测网络对地表水体的水质实施长期监测,但是却导致大量的监测数据累积,给后续的科学研究工作带来了不便,尤其是在庞大的监测网络中如何选取有代表性样点的研究点则成为急需解决的问题之一。以比利时弗拉芒地区地表水的长期监测物理化学指标为例,利用决策树模型评估地表水样点的硝酸盐污染来源专家分类的有效性,为点位优化提供理论依据。原有监测点位的污染源专家分类和模型输出的可匹配率为80%,优化后监测点位从原有47个点降低到30个点,提高了监测工作效率。     

基于熵权综合健康指数法的瀛湖水生态系统健康评估

瀛湖是南水北调丹江口水库重要的水源涵养区,承担着丹江口水库60%的供水量,又是沿线乡镇和安康市城区饮用水水源地。在充分调查的基础上,采用综合健康指数法对1986—2012年之间瀛湖的水生态系统健康状况进行了评估,结果表明,1986—2005年,瀛湖水生态系统健康指数呈逐渐下降趋势,健康状态由健康降至一般病态;2005—2012年之间,瀛湖水生态系统健康指数总体呈上升趋势,健康状态除2010年为一般病态外,其余均为亚健康状态。     

浅谈秸秆焚烧对空气质量的影响

对2014年6月江苏省淮安市秸秆焚烧事件进行分析,研究表明:秸秆焚烧可以导致区域PM2.5、CO、NO2日均浓度分别上升4.2倍、2.9倍、4.4倍。通过对淮安市夏季秸秆焚烧对大气污染程度的分析,提出相应的解决对策,以供环境管理部门提供参考。     

减排监测体系建设存在的问题与对策

对全国减排监测体系建设的现状进行了较详尽的分析,指出减排监测体系建设中主要存在管理体制不顺、自动监控管理不到位、资金投入不畅等问题,并针对这些问题提出了相应的对策。     

皂素和柠檬酸复合淋洗土壤中的钍

采用振荡淋洗和土柱动态淋洗实验研究了皂素和柠檬酸复合对土壤中钍的淋洗性能。实验结果表明:将质量浓度为20 g/L的皂素与浓度为20 mmol/L的柠檬酸以体积比1∶10配制复合淋洗液对污染土壤中钍的去除效果最佳,淋洗3.0 h,钍去除率为84.98%;准一级动力学方程能更好地描述复合淋洗液对钍的淋洗动力学特征;动态淋洗实验中当复合淋洗液用量为1 600 mL时,钍的累积去除量为73.66 mg/kg;淋洗后土壤中钍的酸可提取态、氧化结合态和有机结合态含量分别减少了79.63%、38.13%和20.34%,残渣态含量变化不大;淋洗后土壤中钍的稳定性增加。     

Genotoxicity in adult residents in mineral coal region—a cross-sectional study

The present study assessed the DNA damage in environmentally exposed volunteers living in seven municipalities in an industrial coal region, through the use of the comet assay with blood cells and the micronucleus test with buccal cells. Blood and buccal smears were collected from 320 male volunteers living in seven cities inserted in a coal region. They were ages of 18 and 50 years and also completed a questionnaire intended to identify factors associated with DNA damage through a Poisson regression analysis. The comet assay detected significant differences in DNA damage in volunteers from different municipalities, and neighboring cities (Pedras Altas, Aceguá, and Hulha Negra) had a higher level of DNA damage in relation to control city. Some of the risk factors associated with identified DNA lesions included residence time and life habits. On the other hand, the micronucleus test did not identify differences between the cities studied, but the regression analysis identified risk factors such as age and life habits (consumption of mate tea and low carbohydrates diet). We conclude that there are differences in the DNA damage of volunteers from different cities of the carboniferous region, but the presence of micronuclei in the oral mucosa does not differ between the same cities. Furthermore, we alert that some related factors may increase the risk of genotoxicity, such as residence location and time, and living and food habits. Finally, we suggest the need for continuous biomonitoring of the population, as well as for investing in health promotion in these vulnerable populations.

     

基于MSPA与MCR模型的余江县生态网络构建基于MSPA与MCR模型的余江县生态网络构建

在我国社会经济快速发展的背景下,城市化进程的不断推进导致城市生态斑块日益减少,生态环境问题正在逐年增加,构建生态网络是改善城市生态环境与服务功能的有效方法之一。以余江县为研究区,采用形态学空间格局分析(MSPA)方法和景观指数法,提取对生态网络具有重要意义的生态源地,并基于MCR模型构建综合阻力面,采用最小成本路径方法生成潜在廊道,再基于重力模型、中介中心度等对关键廊道及踏脚石斑块进行识别并提取,从而构建研究区潜在生态网络。结果表明：MSPA方法能够与MCR模型有机的结合,通过定量的分析识别出研究区潜在生态廊道,并根据斑块的中介作用选定踏脚石斑块,明确研究区景观要素的保护优先度,将景观中的潜在生态源地及廊道作为生态网络构建的主要依据,能够更加科学地为余江县生态网络的构建提供指导,同时也可为其他区域提供参考。     

中瑞排污许可证制度的对比研究

对中国水排污许可和瑞典综合排污许可的审批程序和要求、审批内容等进行了对比分析。重点分析了环境法庭在瑞典综合排污许可申报过程中的作用和功能,以及瑞典排污许可证文件的起草和颁发过程。在此基础上,从政府、企业和公众3个层面提出了瑞典综合排污许可证制度对中国排污许可证制度建设和完善的重要借鉴意义。     

Heterogeneous photocatalytic degradation of pesticides using decatungstate intercalated macroporous layered double hydroxides

Decatungstate W₁₀O₃₂ ^4? was efficiently intercalated between the layers of three-dimensionally ordered macroporous Mg₂Al-layered double hydroxide. The structural and textural properties of as-prepared intercalated compound were characterized using different solid-state characterization techniques such as X-ray powder diffraction, FTIR and Raman spectroscopies and electronic microscopy. The photocatalytic properties of immobilized W₁₀O₃₂ ^4? within Mg₂Al structure were investigated using 2-(1-naphthyl) acetamide (NAD) as a model of pesticide. The influence of different parameters such as amount of catalyst, pH and oxygen concentration were investigated. An optimal NAD degradation was obtained for a photocatalyst concentration of 60 mg l^?1. Under our experimental conditions, this heterogeneous photocatalyst induces photodegradation of 60 % of NAD after 17 h of irradiation at 365 nm and at pH 6.6. Interestingly, pesticide photodegradation leads to the mineralization of substrates to H₂O and CO₂ and the photocatalyst can be recycled and reused without any loss of activity over four cycles.     

Multiresidue determination of carbamate,organochlorine, organophosphorus,and dicarboximide pesticides in lettuce by GC/MS

An extraction method based on matrix solid-phase dispersion was developed to determine pirimicarb, methyl parathion, malathion, procymidone, α -endosulfan and β -endosulfan in lettuce using gas chromatography-mass spectrometry. The best results were obtained using 4.0 g of lettuce, 2.0 g of silica as dispersant sorbent, 0.1 g of activated carbon as clean up sorbent and acetonitrile as eluting solvent. The method was validated using lettuce samples fortified with pesticides at six different concentration levels (0.1 to 2.0 mg/kg). Average recoveries (7 replicates) ranged from 50 to 120 %, with relative standard deviations between 0.6 and 8.0 %. Detection and quantification limits for lettuce ranged from 0.01 to 0.02 mg/kg and 0.04 to 0.10 mg/kg, respectively.