UASB-SBR组合工艺在丙烯腈废水处理中的应用研究

针对丙烯腈污水处理场存在的问题,提出采用UASB—SBR组合工艺处理丙烯腈废水的新工艺,并进行试验和讨论,获得了试验基础数据,为该厂丙烯腈污水处理装置技术改造提供技术支持。     

杭州交通噪声投诉点污染现状调查与防治

近年来杭州交通噪声投诉点主要分布在高架道路、立交桥和绕城高速附近的高层住户。对其中9个交通噪声投诉点的监测表明,昼间超4 a类标准的有4个,超标范围为0.1~7.6 dB;夜间9个点全部超4 a标准,超标范围为5.4~17.4 dB,夜间噪声超标特别严重。采用低噪声路面,设置隔声屏障,对敏感点安装通风隔声窗以及加强交通噪声管理等对策,可减轻交通噪声对敏感点的影响,从而减少交通噪声的投诉。     

Identification and characterization of the chromium（Ⅵ） responding protein from a newly isolated Ochrobactrum anthropi CTS-325

A Gram-negative, chromium(VI) tolerant and reductive strain CTS-325, isolated from a Chinese chromate plant, was identified as Ochrobactrum anthropi based on its biochemical properties and 16S rDNA sequence analysis. It was able to tolerate up to 10 mmol/L Cr(VI) and completely reduce 1 mmol/L Cr(VI) to Cr(III) within 48 h. When the strain CTS-325 was induced with Cr(VI), a protein increased significantly in the whole cell proteins. Liquid chromatography tandem mass spectrometry (LC-MS/MS) analysis revealed that this protein was a superoxide dismutase (SOD) homology. The measured superoxide dismutase activity was 2694 U/mg after three steps of purification. The SOD catalyzes the dismutation of the superoxide anion (O₂^·−) into hydrogen peroxide and molecular oxygen. This protein is considered to be one of the most important anti-oxidative enzymes for O. anthropi as it allows the bacterium to survive high oxygen stress environments, such as the environment produced during the reduction process of Cr(VI).     

环境空气SO2自动监测仪的维护

分析环境空气二氧化硫（SO2）自动监测仪故障产生原因,提出判断和处理故障的维修方法。     

西南地区近60年商品材消耗和经济增长关系

首次定义和使用了"GDP黄金当量"作为经济全球化背景下经济增长的新指标。"GDP黄金当量"是指把历年GDP总量按年均汇价和国际黄金市场年均价换算成黄金重量,其可在一定程度上绕开纸币的贬值或升值,反映GDP的贵金属本质,把资源消耗和经济增长的关系分析转变成物物关系分析。研究资源消耗和经济增长的关系有助于提高资源使用效率和调整经济发展方式。通过分析西南地区1949年以来历年商品材产量、人口数量、GDP总量、GDP黄金当量及其单位木材能耗之间的关系,检验了近现代资源环境与经济发展关系中的"资源诅咒"和"库兹涅茨曲线"假设,结果表明:①1952—2008年GDP总量增长了422倍,人口增长了1倍,GDP黄金当量增加了4.5倍,商品材产量增加了12倍;②商品材产量1997—2000年因天然林保护工程下降了80%,然而2008年的946×104m3又恢复到了天然林保护工程前的水平,总体上增长趋势未变;③经济发展出现3个GDP黄金当量"平台",目前处在第3个"平台"上,GDP黄金当量和商品材产量仅前20 a成线性相关(P0.01);④商品材产量和人口数量之间线性相关显著(P0.01),GDP黄金当量和人口数量之间非参数相关显著(P=0.005),人均GDP增长了162倍,人均GDP黄金当量只增长了1.5倍,商品材产量和人均GDP(或人均GDP黄金当量)之间不存在环境库兹涅茨曲线关系,也不存在森林资源诅咒经济增长现象;⑤每万元GDP或每kg GDP黄金当量的商品材消耗量先增加后减少,呈现倒"U"曲线走势,经济发展走过了劳动和森林资源密集型时期。     

A comparative investigation of NdSrCu_(1-x) Co_x O_(4-δ) and Sm_(1.8) Ce_(0.2) Cu_(1-x) Co_x O_(4-δ) (x:0–0.4) for NO decomposition

A series of single-phase T-structured NdSrCu 1-x Co x O 4-δ with oxygen vacancies and T -structured Sm 1.8 Ce 0.2 Cu 1-x Co x O 4-δ (x: 0–0.4) with oxygen excess were prepared using ultrasound-assisted citric acid complexing method, and characterized by means of techniques such as thermogravimetric analysis and NO temperature-programmed desorption (NO-TPD). The catalytic activities of these materials were evaluated for the decomposition of NO. It was found that the NdSrCu 1-x Co x O 4-δ catalysts were of oxygen vacancies whereas the Sm 1.8 Ce 0.2 Cu 1-x Co x O 4-δ ones possessed excessive oxygen (i.e., over-stoichiometric oxygen); with a rise in Co doping level, the oxygen vacancy density of NdSrCu 1-x Co x O 4-δ decreased while the over-stoichiometric oxygen amount of Sm 1.8 Ce 0.2 Cu 1-x Co x O 4-δ increased. The NO-TPD results revealed that NO could be activated much easier over the oxygen-deficient perovskite-like oxides than over the oxygen-excessive perovskite-like oxides, with the NdSrCuO 3.702 catalyst showing the best efficiency in activating NO molecules. Under the conditions of 1.0% NO/helium, 2800 hr -1 , and 600–900°C, the catalytic activity of NO decomposition followed the order of NdSrCuO 3.702 NdSrCu 0.8 Co 0.2 O 3.736 NdSrCu 0.6 Co 0.4 O 3.789 Sm 1.8 Ce 0.2 Cu 0.6 Co 0.4 O 4.187 Sm 1.8 Ce 0.2 Cu 0.8 Co 0.2 O 4.104 Sm 1.8 Ce 0.2 CuO 4.045 , in concord with the sequence of decreasing oxygen vacancy or oxygen excess density. Based on the results, we concluded that the higher oxygen vacancy density and the stronger Cu 3+ /Cu 2+ redox ability of NdSrCu 1-x Co x O 4-δ account for the easier activation of NO and consequently improve the catalytic activity of NO decomposition over the catalysts.     

海水养殖区沉积物中溴氰菊酯检测方法研究

根据海水养殖区沉积物特点,研究建立了其中溴氰菊酯提取、浓缩、净化方法,对溴氰菊酯及其杂质进行分离,用配有电子捕获检测器(ECD)的气相色谱仪测定.该方法具有简便、快速、灵敏度高和费用低等特点.通过对不同养殖区中沉积物进行加标试验测定,方法回收率为79.1%～99.3%,精密度3.6～7.1%.     

三峡库区滩坪滑坡治理工程锚索抗滑桩施工技术

介绍了采用泵送混凝土浇注抗滑桩和风动潜孔锤偏心跟管钻进方法作为治理三峡库区巴东县滩坪滑坡锚索抗滑桩的施工技术,为滑坡灾害防治提供了可供借鉴的工程施工措施.     

全程高温好氧堆肥快速降解城市生活垃圾

为了提高堆肥处理城市生活垃圾（MSW）的速率和质量,设计了一种外加热源的全程高温好氧堆肥工艺.实验以全程高温好氧堆肥和传统好氧堆肥两种方法对MSW进行了60d的堆肥处理.同时,监测了堆肥的pH和温度等参数的变化情况,并以C/N、种子发芽率(GI)、可溶性有机碳(DOC)、比好氧速率(SOUR)和脱氢酶（DH-ase）活性为指标评价了堆肥的腐熟度和质量.结果表明,全程高温堆肥法和传统堆肥法的堆肥周期分别为16d和28d,两种方法得到的产品其pH值均在7左右.在第31d将全程高温堆肥产品置于30℃恒温箱时,其理化性质没有出现明显波动,说明其堆肥产品性质稳定.因此,全程高温好氧堆肥法能明显缩短堆肥周期、提高堆肥质量,具有很大的应用潜力.     

新标准下垃圾焚烧飞灰化学稳定技术的比选和研究

研究了新的生活垃圾填埋场污染控制标准(GB168892008)实施后,飞灰要进入生活垃圾卫生填埋场时传统的重金属稳定方法可行性,并在此基础上提出了新的复合药剂稳定法.研究结果表明,已经报道的化学药剂稳定法均有必要重新检验其对重金属的稳定效果是否满足新的填埋标准的要求.绿矾与TMT-18配合使用、绿矾用量为25%（质量分数）以下、TMT-18的用量为8‰左右时完全可以使飞灰中所有重金属浸出浓度满足新的填埋标准要求,是处理二噁英含量不高于3 ng·g-1(以TEQ计)飞灰的一种经济处理技术.对二噁英含量高于3 ng·g-1 (TEQ)的飞灰,采用绿矾辅助水热处理的方法可以稳定包括Pb、Cd在内的所有重金属和降解二噁英使之符合新填埋标准对飞灰填埋的要求.