Emission characterization of unintentionally produced persistent organic pollutants from iron ore sintering process in China

Emission of unintentionally produced persistent organic pollutants (Unintentional POPs), including polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychorinated biphenyls (PCBs), hexachlorobenzene (HxCBz) and pentachlorobenzene (PeCBz), were investigated in four typical iron ore sintering plants in China. The emission factors and annual mass releases of the Unintentional POPs were calculated. The results indicated that PCDFs contributed more than 60% to the overall toxic equivalent quantity (TEQ) values, while the contribution of the dl-PCBs is relatively low, and only in the range of 8-9%. The dominant congeners of PCDD/Fs and dl-PCBs contributing most to the total TEQ were 1,2,3,7,8-PeCDD, 2,3,4,7,8-PeCDF and PCB-126. With regard to the TEQ contributions, the most abundant homologues were PeCDFs and HxCDD/Fs, followed by PeCDDs and non-ortho dl-PCB, whereas HpCDD/Fs, OCDD/Fs and mono-ortho dl-PCBs almost made no contributions. Due to the massive use of recycled waste in the feeding materials, the average emission factor of PCDD/Fs and dl-PCBs of the four plants was 3.95 μg WHO-TEQ ton⁻¹. Based on the results, the annual release of PCDD/Fs and dl-PCBs in 2007-2009 were estimated to be 2070 g, 2212 g, and 2307 g WHO-TEQ, respectively.     

分子生物技术在环境工程微生物领域中的应用

目前分子生物技术发展日新月异,已渗透到各相关学科。本文综述了分子生物技术的基本原理与方法,及其在环境工程微生物领域的应用。讨论了分子生物技术在环境工程微生物的检测应用及在污泥、生物膜、底泥和土壤等微生物种群的多样性分析方面,以及环境工程菌的挑选和培养等方面的研究成果及其巨大研究前景,对该技术在环境工程领域的应用与发展提出了一些见解。     

Concentrations and distributions of 18 organochlorine pesticides listed in the Stockholm Convention in surface sediments from the Liaohe River basin,China

Organochlorine pesticides (OCPs) were analyzed in 26 surface sediment samples from the Liaohe River basin, and the distributions of and potential environmental risks posed by OCPs in the basin were evaluated. Eighteen OCPs listed in the Stockholm Convention were determined using isotope-dilution gas chromatography–high resolution mass spectrometry. This is the first study of hexachlorobenzene (HCB) in the Liaohe River basin sediments. The total OCP concentrations were 0.39–68.06 ng g^?1 dry weight. The total α-, β-, γ-, and δ-hexachlorocyclohexane (HCH), the total dichlorodiphenyltrichloroethane (DDT – p,p′-dichlorodiphenyldichloroethane (DDD), p,p′-dichlorodiphenyldichloroethylene (DDE), o,p^'-DDT, and p,p′-DDT), and the HCB concentrations in the sediment samples were 0.1–28.48 ng g^?1 (mean 4.01 ng g^?1), 0.08–6.52 ng g^?1 (mean 3.07 ng g^?1), and 0.18–24.8 ng g^?1 (mean 4.38 ng g^?1), respectively. The HCB concentrations were higher than the concentrations of the other OCPs, and the HCHs and HCB together were the dominant OCPs. β-HCH was the most abundant HCH isomer. The concentrations of DDTs and other OCPs were relatively low, and the (DDE+DDD)/DDT ratios (>0.5) and DDD/DDE ratios (<1) indicated that no recent DDT inputs had occurred in the Liaohe River system. The main sources of HCHs were probably the historical production and agricultural use of HCH in the study area. The DDT and HCH concentrations were generally below or similar to the concentrations that have been found in other parts of the world. An ecotoxicological evaluation indicated that HCHs in surface sediments pose slight risks to human and ecological health in the Liaohe River basin.     

垃圾填埋场渗滤液运移规律分析与模拟

基于多孔介质流体力学、多相流以及土壤水动力学理论,利用理论分析和数值模拟相结合的方法,研究了垃圾填埋场中渗滤液运移过程的基本规律,并对填埋场底部可渗和不可渗2种情况下渗滤液的运移规律进行了模拟比对,研究成果可为填埋场渗滤液控制系统的设计和管理提供科学的理论依据和技术支持。     

CAS工艺与AOE工艺曝气池水质信息场的测量与分析

为了研究曝气池空间内水质的分布及变化规律,采用了YSI6600 V2多参数水质检测仪对成都市三瓦窑污水处理厂的一期工程传统污泥法(CAS)、二期工程缺氧、好氧和内源呼吸(AOE)工艺中的曝气池分别进行了包括DO、NH3-N、NO3--N、pH、氯化物和温度等水质指标的场的检测,通过分析这些数据,揭示了曝气池内部水质变化的规律,并比较了CAS工艺与AOE工艺内水质处理效果的差别。结果表明,(1)溶解氧沿池深方向呈现出一定的分布规律,CAS工艺中随池深增加,溶解氧增加,AOE工艺中随着池深的增加,溶解氧降低;(2)AOE工艺对氨氮在O区的去除率可达97.64%,明显高于CAS工艺的41.76%;(3)沿曝气池长度测量溶解氧空间分布规律,参照理论曲线及依据水质处理要求,调整曝气量的方法具有长期运行经济、水质处理效果好的特点。     

TiO2光催化处理络合铜废水的实验研究

研究了以悬浮态TiO2为催化剂,在紫外光的作用下对络合铜废水进行光催化反应,分别考察了常温下TiO2投加量、反应时间、废水初始pH值、反应气氛等因素对处理效果的影响,并探讨了反应机理。结果表明:TiO2投加量为2 g/L,废水pH=4,300 W高压汞灯照射下,载入60 mL/min的空气反应40 min,120 mg/L EDTA络合铜废水的Cu(II)与COD的去除率达到最高,分别为96.56%和57.67%。     

人工湿地污水处理工艺及除污机理

对人工湿地污水处理工艺及其对水中污染物的去除机理进行了综述,并对人工湿地处理污水的技术进行了展望。     

粘性泥石流运动模型的实验研究

粘性泥石流运动模型的研究因受实验条件的限制,还很不完善。国内外学者应用较多的５种模型都有一定的适用性,但也都存在不同的缺陷。本文应用粘性泥石流土样中的细颗粒和粗颗粒进行流变实验,不仅得到了粗颗粒在浆体中的沉降特性和泥石流体的流变特性,还研究了粘性泥石流运动模型及其参数。所提模型能很好地反映泥石流体的流变特性,较现有的５种模型能更好地描述粘性泥石流。     

高海拔排土场边坡安全稳定性的PS⁃InSAR监测

为了解决高海拔排土场边坡灾害监测难度大以及安全稳定性预警等问题,提出利用 PS-InSAR 技术对高海拔排土场边坡进行安全稳定性监测分析。通过对西藏山南桑日县某排土场边坡进行监测分析研究,采用 2018 年 11 月 04 日至 2020 年 12 月 23 日的 25 景 Sentinel-1A 数据,利用时序差分干涉相位的时空分析方法,进行差分干涉、模型迭代计算和地理编码等解算,解算得到平均形变速率分布,基于平均形变速率结果分析该排土场边坡的安全稳定性。结果表明：利用 PS-InSAR 技术能够获取排土场边坡区域的地表形变信息;该研究区域坡体 2018 年 11 月至 2020 年 12 月的平均形变速率最大值为 -20.00 mm/a,最大形变速率区域出现在排土场边坡的下部 ;通过 PS-InSAR 技术能够对其安全稳定状态进行准确评价,并进行预警预报,为排土场边坡的安全稳定服役提供有效技术保证。     

近场地震作用下库区深水钢筋混凝土高墩地震易损性分析∗

为研究近场地震作用下库区深水钢筋混凝土高墩的概率损伤特性,以90 m高的矩形空心薄壁钢筋混凝土深水高墩为研究对象,综合考虑桥墩设计参数和近场地震动的随机性,基于OpenSees软件建立深水高墩有限元模型,开展不同水深的7种工况(水深:0、15、30、45、60、75、90 m)下,顺桥向和横桥向近场地震激励的增量动力非线性分析。以截面临界曲率值为损伤指标,研究深水高墩的易损性。结果表明:各工况下,轻微损伤、中等损伤和严重损伤阶段的损伤概率均随地震波峰值加速度的增加而增大,并且当峰值加速度达到1.0g时损伤概率达到最大,而完全损伤阶段的损伤概率则在峰值加速度为0.5g时出现峰值点;近场地震顺桥向激励时,墩身中上部和墩底区域均较容易损伤,而横桥向激励时仅墩底区域较容易损伤;当水深超过45 m后,高墩最大损伤概率变化不大且截面曲率概率需求基本一致,45 m水深为深水高墩显著水深。因此,应重点分析水深达到高墩高度一半时深水高墩的损伤情况。