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1994年夏季调查和测定了南京市市售青菜中甲胺磷、乐果、甲基-1605等5种有机磷农药残留量。结果表明,夏季青菜(包括青菜秧)中有机磷农药残留量有超标现象,其中甲胺磷在青菜中的平均残留量为0.063mg/kg,超标率为11.5%,其余4种有机磷农药在青菜中未检出。 相似文献
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The estimation of solute sorptive behaviors is essential when direct sorption data are unavailable and will provide a convenient way to assess the fate and the biological activity of organic solutes in soil/sediment environments. In this study, the sorption of 2,4-dichlorophenol (2,4-DCP) on 19 soil/sediment samples and the sorption of 13 organic solutes on one sediment were investigated. All sorption isotherms are nonlinear and can be described satisfactorily by a simple dual-mode model (DMM): q(e)=KpCe+Q0 . bCe/(1+bCe), where Kp (mlg(-1)) is the partition coefficient; Ce (microgml(-1)) is the equilibrium concentration; Q0 (microgg(-1)) is the maximum adsorption capacity; Q0 . b (mlg(-1)) is the Langmuir-type isotherm slope in the low concentration (Henry's law) range and b (mlmicrog(-1)) is a constant related to the affinity of the surface for the solute. Based on these nonlinear sorption isotherms and similar other nonlinear isotherms, it is observed that, for both polar 2,4-DCP and nonpolar phenanthrene, Kp, Q0 and Q0 . b are linearly correlated with soil/sediment organic carbon content (f(oc) in the range of 0.118-53.7%). The results indicate that the nonlinear sorption of organic solutes results primarily from interactions with soil/sediment organic matter. The K*oc K*oc=Kp/f(oc)), Qoc (Qoc=Q0/f(oc)), Loc (Loc=Q0 . b/f(oc)) and b for a given organic solute with different soils/sediments are largely invariant. Furthermore, logK*oc, logb and logLoc for various organic solutes are correlated significantly with the solute logKow or logSw (logKow in the range of 0.9 to 5.13 and logSw in the range of -6.176 to -0.070). A fundamental empirical equation was then established to calculate approximately the nonlinear sorption from soil/sediment f(oc) and solute Sw for a given solute equilibrium concentration. 相似文献
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This paper concerns the incineration of isopropyl alcohol (IPA) using the ferrospinel catalyst MnFe2O4. It covers the preparation of the ferrospinel catalyst, the screening of catalytic activity, catalytic incineration testing, and 72-hr decay testing of the catalyst. The experimental results of catalyst screening reveal that the Mn/Fe catalyst is the best of five prepared catalysts (chromium/iron [Cr/Fe], manganese/iron [Mn/Fe], zinc/iron [Zn/Fe], nickel/iron [Ni/Fe], and pure magnetite [Fe3O4]). In tests of the catalytic incineration system used to convert IPA, 98% conversion was obtained at a space velocity of 24,000 hr(-1), an oxygen (O2) content of 21%, 1700 ppm of IPA, and a reaction temperature of 200 degrees C. 相似文献
115.
五氯酚是氯酚族中最具毒性和最难降解的有机污染物,其废水的处理一直受人关注.文章概述了五氯酚的生物降解规律和近年来国内外有关五氯酚废水生化处理技术的最新研究进展,对各种方法的优缺点进行了评述,对未来的研究方向提出了建议. 相似文献
116.
Urban water resources have been facing significant pressure from population growth, urbanization, and climate change. A system dynamics urban water management model was proposed to simulate the dynamic interactions between urban water demands and society, economy, climate, and water conservation. The residents'' water conservation willingness was incorporated in the model and water-saving effects were quantified. The simulation results for Macau showed that population size was the main driving force for urban water demand. The change of temperature and precipitation has obvious effects on the landscape water demand. The water demand output is sensitive to the change in population, per capita demand, and temperature. Increased precipitation will reduce urban water demand and increased economic growth will increase water demand. By implementing integrated water conservation measures and improved water conservation willingness, water demand could be reduced by 17.5%. 相似文献
117.
Lin Gu Huaqing Guo Pin Zhou Nanwen Zhu Daofang Zhang Haiping Yuan Ziyang Lou 《Environmental science and pollution research international》2014,21(3):2043-2053
The disposal of sewage sludge (SS) and reed straw (RS) has becoming a critical issue due to their rapid production. In this study, the SS-based activated carbon (SSC) was produced by introducing the RS as a component material. Properties including BET surface area, pore volume, surface chemical groups, and morphologies were characterized. The adsorption of 1-diazo-2-naphthol-4-sulfonic acid (1,2,4-Acid) and 2-Naphthol (2-Nap), which differs in their physicochemical properties, on as-prepared carbons were investigated. The overall adsorption was found to be jointly controlled by external mass transfer and intraparticle diffusion, and the optimal pH was found to be 5 due to their electrostatic attraction. Further study revealed that the SS- and RS-based carbons (SC and RSC, respectively) exhibited different adsorption behavior toward 1,2,4-Acid and 2-Nap. The calculated adsorption capacity from Langmuir–Freundlich model of SC and RSC for the two intermediates was 141.0, 84.6 mg g-1 and 48.2, 110.2 mg g-1, respectively, whereas their hybrid product (SSC) showed comparable capacity for 1,2,4-Acid (117.8 mg g-1), as well as higher capacity for 2-Nap (157.5 mg g-1). It was found that the presence of meso- or macropores facilitates the precipitation of mineral phases of inorganic substances during carbonization, attracting the molecules with polar functional groups, while the introduction of C-rich RS to SS enhances the adsorption of hydrophobic molecules. 相似文献
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120.
老港填埋场渗滤液性质随工艺变化研究 总被引:1,自引:0,他引:1
经老港填埋场渗滤液处理系统的各处理单元处理后的流出液,用不同孔径的系列膜进行了梯度分离。分离前后的渗滤液进行了TOC、TP、TN、氨氮和可溶性P等参数的测定,并建立了各参数与不同孔径膜的关系。结果表明,此工艺对老港填埋场渗滤液的处理具有一定的功效;随着处理工艺的进行,渗滤液的组成发生了较大的改变,其中细胶体部分的百分含量增加,而可溶性部分降低;渗滤液的绝大部分污染物质集中于可溶性部分,而渗滤液中的P主要与大分子的悬浮物和粗胶体结合。 相似文献