南宁市区交通环境空气颗粒物中碳组分的污染特征分析研究

含碳颗粒物是大气颗粒物的重要组成部分,对人体健康产生很大的威胁.分别于2012年夏季及2013年冬季在南宁市选取六条主要交通干道采集了PM10、PM2.5样品,分析测定了其中的碳组分.结果表明,碳组分浓度季节变化明显.碳组分在细颗粒物中占有比重比在可吸入颗粒物中大.存在二次有机碳污染.对8种碳组分丰度分析说明南宁市大气颗粒物中碳组分的主要来源是燃煤、机动车尾气及生物质样品燃烧.     

Multilevel air quality evolution in Shenyang: Impact of elevated point emission reduction

Visibility observed at different altitudes is favorable to understand the causes of air pollution. We conducted 4-years of observations of visibility at 2.8 and 60 m and particulate matter(PM) concentrations from 2015 to 2018 in Shenyang, a provincial city in Northeast China. The results indicated that visibility increased with the increasing height in winter(especially at night), and decreased with height in summer(especially at the daytime). PM concentration exhibited opposite vertical variati...     

杀虫剂环境风险评价工作的进展与探讨

杀虫剂使用量大，使用范围广，对生态环境影响深刻，其种类繁多，特性各异，毒理性质，物化性质及残留降解性能均与健康风险和生态风险密切相关。用一般的风险方法评价难以涵盖其危害的方方面面。因此，杀虫剂环境风险评价是一项重要而紧迫的课题，本文从理论，方法及实际工作等方面介绍了国内外杀虫剂环境风险评价的进展情况，分析了其特点和存在的问题，提出了构建杀虫剂环境风险评价整体框架的设想。以便通过环境风险评价追踪和预测杀虫剂对人群健康和生态系统结构与功能的潜在影响，从根本上预防和控制杀虫剂对人体健康和生态环境造成的危害。     

Environmental behaviors of phoxim with two formulations in bamboo forest under soil surface mulching

Phoxim (emulsifiable concentrate (EC) and granules (G)) has been widely used in bamboo forests. The persistence and magnitude of phoxim residues in the crop and soil must be investigated to ensure human and environmental safety. The environmental behaviors of the two formulations were investigated in a bamboo forest under soil surface mulching conditions (CP) and non-covered cultivation conditions (NCP). The half-lives of phoxim in soil under the two conditions in soil were 4.1–6.2 days (EC) and 31.5–49.5 days (G), respectively. Phoxim in EC could be leached from the topsoil into the subsoil. A minimized leaching effect was observed for G under NCP. Inversely, an enhanced leaching effect was observed for G under CP. The G formulation resulted in more parent compound (in bamboo shoots) and metabolite (in soil) residues of phoxim than in the case of EC, especially under CP conditions. In addition, the intensity and duration of the formulation effect on soil pH adjustment from G were more obvious than that from EC. Results showed that the environmental behaviors (distribution, degradation, residue) of phoxim in the bamboo forest were significantly influenced by the type of formulation. The prolongation effect from phoxim G might cause persistence and long-term environmental risk. However, bamboo shoot consumption could be considered relatively safe after applying the recommended dose of the two phoxim formulations.     

Examining strategic sustainability plans and smart-growth land-use measures in California cities

Given many potential obstacles, what types of strategic plans and measures for climate protection and/or energy sustainability are more likely than others to be adopted by cities? What are the key internal and external obstacles to adopting and implementing these plans and measures? Based on data obtained from a survey conducted from 2010 to 2011 and other sources, this paper develops a framework derived from political contracting theory and strategic orientation literature to examine how public management obstacles, socio-economic factors, and political factors influence a city's likelihood of having strategic energy sustainability plans and measures in place. Moreover, this paper finds that many California cities remain reluctant to require residents and businesses to comply with more challenging sustainability measures, such as smart-growth land-use practices, and that those cities with a strategic energy sustainability plan already in place tend to be more willing to adopt smart-growth land-use measures.     

后疫情时期全国碳市场政策对经济和排放的影响

新冠肺炎疫情暴发一年多以来,国际国内形势仍面临极大不确定性。疫情显著降低了短期排放水平,但是经济恢复政策和疫情发展形势的不确定使得对未来经济发展和碳排放的判断变得复杂,碳排放是否会反弹对实现《巴黎协定》目标造成挑战,已经投入运行的全国碳市场能多大程度发挥政策效果等问题值得关注。本文首先定量评估了疫情对经济和环境的短期和长期的影响,基于此分析疫情后全国碳市场政策的实施效果。结果显示:疫情造成中国经济活动以及碳排放短期显著下降,2020年中国全年的GDP增长较基准情景下降3.84%,能源消费和碳排放分别较基准情景下降4.47%和5.12%。但是,接下来的十年内,GDP会逐渐恢复至基准情景,累计碳排放较基准情景增加0.06%。在没有其他气候政策干预的情况下,疫情带来的短期减排效应不足以保障中国各项气候目标的实现,落实碳市场政策十分必要。疫情之后启动全国碳市场,可以促进投资、减少能源使用和碳排放,到2030年,能源消费将下降7.44%,碳排放下降10.49%,碳价为229.73元/t。国外疫情若在2021年还不能得到控制,将会继续影响中国的对外贸易,使得中国GDP损失略有提高,但不会改变国内疫情之后经济恢复的大趋势。     

柔性管理理念在高校学生管理中的运用

新时期大学生的心理行为特点和高校"以人为本"的学生工作理念的发展都要求高校学生管理必须改变传统的刚性管理模式,引入柔性管理理念,在学生管理中重视学生的主体地位,关注学生的情感需要,注重管理与服务的糅合、融通.     

Enzyme-electrolytic degradation of dichloromethane: Efficiency, kinetics and mechanism

Enzymatic electrolysis cell(EEC) has advantages over microbial electrolysis cell(MEC) due to the needless of microbe inoculation and high-efficiency of enzymatic reaction. In this study, an EEC was first applied to achieve the effective degradation of halogenated organic pollutants and dichloromethane(CH_2Cl_2) was utilized as a model pollutant. The results indicate that the degradation efficiency of CH_2Cl_2 after 2 hr reaction in the EEC was almost100%, which was significantly higher than that with enzyme(51.1%) or current(19.0%). The current induced the continuous regeneration of reduced glutathione(GSH), thus CH_2Cl_2 was degraded under the catalysis of GSH-dependent dehalogenase through stepwise dechlorination, and successively formed monochloromethane(CH_3Cl) and methane(CH_4). The kinetic result shows that with a current of 15 mA, the maximum specific degradation rate of CH_2Cl_2(3.77 × 10~(-3) hr~(-1)) was increased by 5.7 times. The optimum condition for CH_2Cl_2 dechlorination was also obtained with pH, current and temperature of 7.0, 15 mA and 35°C,respectively. Importantly, this study helps to understand the behavior of enzymes and the fate of halogenated organic pollutants with EEC, providing a possible treatment technology for halogenated organic pollutants.     

Microbial response to CaCO3 application in an acid soil in southern China

Calcium carbonate (CaCO₃) application is widely used to ameliorate soil acidification. To counteract soil and bacterial community response to CaCO₃ application in an acidic paddy soil in southern China, a field experiment was conducted with four different dosages of CaCO₃ addition, 0, 2.25, 4.5 and 7.5?tons/ha, respectively. After one seasonal growth of rice, soil physicochemical properties, soil respiration and bacterial communities were investigated. Results showed that soil pH increased accordingly with increasing dose of CaCO₃ addition, and 7.5?tons/ha addition increased soil pH to neutral condition. Moderate dose of CaCO₃ application (4.5?tons/ha) significantly increased soil dissolved organic carbon (DOC) and dissolved organic nitrogen (DON) content, enhanced soil respiration, while the excessive CaCO₃ application (7.5?tons/ha) decreased these soil properties. High-throughput sequencing results illustrated that moderate dose of CaCO₃ application increased the richness and alpha diversity of soil bacterial community. Compared with control, the relative abundance of Anaerolineaceae family belonging to Chloroflexi phylum increased by 38.7%, 35.4% and 24.5% under 2.25, 4.5 and 7.5?tons/ha treatments, respectively. Redundancy analysis (RDA) showed that soil pH was the most important factor shaping soil bacterial community. The results of this study suggest that proper dose of CaCO₃ additions to acid paddy soil in southern China could have positive effects on soil properties and bacterial community.     

From waste hot-pot oil as carbon precursor to development of recyclable attapulgite/carbon composites for wastewater treatment

The utilization of waste products as valuable materials was a technical imperative for waste management. In this study, the cost-effective attapulgite/carbon(APT/C) composite was developed for wastewater treatment using waste hot-pot oil as a carbon precursor through a facile one-step calcination process. The APT/C composite prepared at 300°C exhibited the excellent adsorption capacity and rapid equilibrium rate over a broad p H range for the removal of various pollutants. More importantly, the removal ratios of the composites toward Methyl Violet and tetracycline still remained 77.6% and 60.2% of the initial adsorption capacity after ten adsorption–regeneration cycles via a facile thermal regeneration strategy, respectively.Beyond all doubt, this research provided a feasible and economical way for the sustainable utilization of waste hot-pot oil in wastewater treatment, achieving the concept of disposal waste with waste and recycling.