多酚原位固化茶渣对水中Cr（Ⅵ）的吸附

通过甲醛与茶渣中多酚类组分的反应制备了多酚原位固化茶渣吸附材料,并将其用于对水中Cr（Ⅵ）的吸附。表征结果显示：茶渣多酚的原位固化提高了其热稳定性,同时对茶渣粒料起到了修补增强作用。固化茶渣对Cr（Ⅵ）的吸附量随溶液pH的减小而增大。在吸附温度303 K、初始Cr（Ⅵ）质量浓度60 mg/L、吸附剂投加量1.0 g/L、吸附时间300 min、溶液pH为2的条件下,固化茶渣对Cr（Ⅵ）的吸附量为56.56 mg/g,去除率达94.3%。固化茶渣对Cr（Ⅵ）的吸附符合Langmuir等温吸附模型和准二级动力学方程,吸附是一个自发的、吸热过程,303,318,333 K下的Langmuir饱和吸附量分别为83.26,107.64,129.20 mg/g。     

Effect of biocover equipped with a novel passive air diffusion system on microbial methane oxidation and community of methanotrophs

A novel biocover with passive air diffusion system (PADS) was designed in this study. Its effect on landfill gas components in the macrocosms of simulated biocover systems was also investigated. The results show that O2 concentration increased in the whole profile of the macrocosms equipped with PADS. When simulated landfill gas (SLFG) flow rate was no more than 40 mL min(-1), the methane oxidation rate was 100%. The highest CH4 oxidation capacity reached to 31.34 mol m(-3) day(-1). Molecular microbiology analysis of the soil samples taken from the above macrocosm showed that the growth of type I methanotrophs was enhanced, attributable to enhanced air diffusion and distribution, whereas the microbial diversity and population density of type II methanotrophs were not so affected, as evidenced by the absence of any difference between the biocover equipped with PADS and that of the control. According to a phylogenic analysis, Methylobacter Methylosarcinafor type I, and Methylocystis, Methylosinus for type II, were the most prevalent species in the macrocosm with PADS.     

低碳经济下的秦皇岛休闲农业发展研究

秦皇岛市作为休闲度假旅游胜地,在实施＂旅游立市＂发展战略中把休闲农业作为一个新的经济增长点,在应对低碳时代的发展要求、发展休闲农业方面做出积极实践。通过分析低碳经济下发展休闲农业的必要性和秦皇岛休闲农业的发展现状,提出秦皇岛休闲农业发展的对策和路径选择。     

Fe(Ⅲ)-酒石酸盐配合物体系的光解特性

以Fe(Ⅲ)-酒石酸配合物体系光化学过程中产生的Fe(Ⅱ)和.OH为主要检测对象,探讨了Fe(Ⅲ)-酒石酸配合物体系光化学反应的基本规律及影响因素。结果表明,体系的光化学过程能产生Fe(Ⅱ)和.OH;产生Fe(Ⅱ)的速率远高于产生.OH的速率;Fe(Ⅱ)生成浓度在pH 3.50时最大,.OH则在pH 3.00时最大;配合物的光化学过程中会伴随pH的升高;在照度为3.6×103Lux的日光灯照射下,Fe(Ⅲ)-酒石酸盐配合物初级光解的速率常数为2.1×10-3S-1;Fe(Ⅱ)是高价重金属的主要还原剂,.OH是有机物的主要氧化剂。     

离子色谱在监测土霉素结晶母液废水处理过程中土霉素含量的研究

土霉素结晶母液是一种含高硫高氮的高浓度难生物降解有抽废水,有用前置反硝化法对其进行脱氮处理过程中,残留的土霉素等对反硝化有明显的生物和抑制作用,用离子色谱法（以0mniPac PCX-100为分离柱,0.2mol.l^-1盐酸－27.9%乙腈（V／V）为淋洗液）测定经预酸化处理后废水中的土霉素含量,分析结果表明,预酸化处理可以显著降解废水中的土壤素,提高其可生化性,该法6min内即可完成土霉素含量的测定,土霉素的检出限为10ug.l^-1.     

构建和谐社会与高校共青团工作创新

从高校共青团工作面临的新的机遇和挑战出发,就高校共青团组织在构建和谐社会中的主要任务进行探讨,对构建和谐社会进程中共青团工作所面临的问题进行剖析,从而提出了在构建社会主义和谐社会进程中创新青年工作的几点建议,其中包括共青团思想政治工作中工作思路、工作内容、工作手段、工作机制的创新,培育团队的创新能力和大力加强团员青年群体创新能力的开发等推动共青团工作创新的方法.     

Assessing noxious effects of dietary exposure to methylmercury,PCBs and Se coexisting in environmentally contaminated rice in male mice

Polychlorinated biphenyls and methylmercury are two of the most ubiquitous environmental contaminants in Guizhou province. Rice is eaten with almost every meal and provides more calories than any single food in Guizhou province. The estimated tolerable daily intake of total mercury, MeHg, Se and PCBs from Guizhou contaminated rice by Chinese people showed that MeHg and/or PCBs exceeded the corresponding limits. The aim of this study was to characterize the effects of exposure to environmental contaminated rice on neurobehavioral development and neurobiological disruptions in mice. Animals were treated from postnatal day (PND) 22 to 91. At PND 26–91 days of age, mice were tested for neurobehavioural development and neurochemical level changes. We showed that dietary exposure to environmentally contaminated rice gave rise to different changes in antioxidants. Reduced superoxide dismutase (SOD) activity and excess increased nitric oxide (NO) indicated aggravation of oxidative status after long-term dietary intake of Hg and PCBs. Neurobehavioral derangement in the central nervous system and significant delay in the Morris water maze test response on PND 91 are correlated with the increased of c-fos/c-jun expression levels in the cerebral cortex. These results suggest that MeHg neurotoxicity might be a greater hazard than that associated with PCB, but PCB may augment the neurobehavioral deficits caused by increased levels of mercury exposure. The simultaneous intake of selenium might have a protective effect on Hg accumulation in the body, and vitamin C might protect mice against the toxic effects of PCBs. However, the protective role of Se and vitamin C is very limited for multiple-agent pollution. Immediately early genes in the brain response to contaminated rice might be dependent on interaction among NO, NO synthase (NOS), SOD and reduced glutathione (GSH). We should be alert to mental health problems in human beings when any kind of Hg- and PCB-polluted food is consumed.     

Binding of phthalates with nuclease increases DNA enzymatic degradation and implication for antibiotic resistance

Environmental Chemistry Letters - The overuse of antibiotics has widely induced the development of antibiotic resistance in pathogens and, in turn, has induced the inefficiency of antibiotic drugs,...     

蚯蚓生物反应器污泥减量与稳定效果试验研究

蚯蚓生物反应器以蚯矧等微型动物和各种微生物为主形成生物降解系统.城镇污水经生物预处理后,经该反应器过滤,水质得到澄清和进一步改善,而水中含有的生物膜污泥则被滤床截留.通过蚯蚓的吸收、消化和分解转化为蚯蚓排泄物(蚓粪).中试运行结果表明,当蚯蚓生物反应器水力负荷为5.3～6.6 m3/(m2·d)时,在满足污水处理效果条件下,蚯蚓生物反应器对生物膜污泥挥发性悬浮固体(VSS)降解率为86.67%～96.20%.所产生的蚓粪VSS:SS为29.97%～31.20%,有机物降解率超过了厌氧消化与好氧消化处理污泥的效果.减量化和稳定化效果十分明显.该系统排出的蚓粪含有丰富的肥分,可用作农肥与土壤改良剂.     

COD对生物除磷颗粒污泥稳定性影响研究

颗粒污泥稳定性是影响其应用的主要因素之一.以SBR中成熟的生物除磷颗粒污泥为研究对象,探讨进水COD浓度对系统稳定性的影响.结果表明,当进水COD浓度由300 mg/L逐渐升高到500 mg/L时,磷去除率由93%降低到88%;当进水COD浓度在400 mg/L以下时,污泥的最大比释磷速率和比吸磷速率分别为45.2 m...