地下污油罐腐蚀因素分析及防腐措施

地下污油罐是石油炼化行业中的常用储罐,分析了地下土壤或油罐内部介质等因素对其造成的腐蚀,结合实际案例提出了污油罐防腐措施     

Mesoporous cobalt monoxide-supported platinum nanoparticles: Superior catalysts for the oxidative removal of benzene

Mesoporous Co_3 O_4(meso-Co_3 O_4)-supported Pt(0.53 wt.% Pt/meso-Co304) was synthesized via the KIT-6-templating and polyvinyl alcohol(PVA)-assisted reduction routes.Mesoporous CoO(meso-CoO) was fabricated through in situ reduction of meso-Co304 with glycerol,and the 0.18-0.69 wt.% Pt/meso-CoO samples were generated by the PVA-assisted reduction method.Meso-Co_3 O_4 and meso-CoO were of cubic crystal structure and the Pt nanoparticles(NPs) with a uniform size of ca.2 nm were well distributed on the mesoCo_3 O_4 or meso-CoO surface.The 0.56 wt% Pt/meso-CoO(0.56 Pt/meso-CoO) sample performed the best in benzene combustion(T_(50%)=156℃and T_(90%)=186℃at a space velocity of 80,000 mL/(g h)).Introducing water vapor or C02 with a certain concentration led to partial deactivation of 0.56 Pt/meso-CoO and such a deactivation was reversible.We think that the superior catalytic activity of 0.56 Pt/meso-CoO was intimately related to its good oxygen activation and benzene adsorption ability.     

Studies on relationships between air pollutants and allergenicity of Humulus Scandens pollen collected from different areas of Shanghai

Pollen pollution and allergy are becoming prominent issues in China. However, few studies on pollinosis have been reported. As an allergen in the atmosphere, allergenic Humulus scandens pollen was collected from four districts of Shanghai, including Wusong (WS), Jiading (JD), Xujiahui (XJH) and Songjiang (SJ). The mass concentrations of SO₂, NO₂, O₃, PM_10, and PM_2.5 (particulate matter with air dynamic diameter less than 10 and 2.5 µm, respectively) near the four sampling sites were also recorded during Humulus scandens pollen season. The allergenicity of the Humulus scandens pollen was assessed by using of a rat model and enzyme linked immunosorbent assay (ELISA). Relationships between the allergenicity and air pollutants were correlated. Our results demonstrated that the biological viability of the pollens collected from the four districts exhibited no significant differences. ELISA and dot blotting results further demonstrated that the serum of sensitized rats exhibited much higher immune-reactive response than that of control groups. Western blotting showed that the 15 KD (1KD = 1000 dalton) proteins of Humulus pollen led to the allergic response. The allergenic intensity of Humulus pollen protein from different samples followed the pattern: WS > JD > XJ > SJ. There was a negative relationship between the allergenicity of Humulus pollens and PM₁₀ (R = -0.99) / PM_2.5 (R = -0.73), and a positive relationship with O₃ (R = 0.92). These data clearly showed that PM₁₀ and PM_2.5 could enhance Humulus pollen protein release, and O₃ could aggravate the allergenicity of the Humulus pollen.     

Modeling Change-Pattern-Value Dynamics on Land Use: An Integrated GIS and Artificial Neural Networks Approach

The use of spatial methods to detect and characterize changes in land use has been attracting increasing attention from researchers. The objectives of this article were to formulate the dynamics of land use on the temporal and spatial dimensions from the perspectives of the Change-Pattern-Value (CPV) and driving mechanism, based on multitemporal remote sensing data and socioeconomic data. The Artificial Neural Networks were used to identify the factors driving changes in land use. The Pearl River Delta Region of southeast China, which was experiencing rapid economic growth and widespread land conversion, has been selected as the study region. The results show that from 1985 to 2000 in the study region (1) the most prominent characteristics of change in land use were the expansion of the urban land at the expense of farmland, forests, and grasslands, (2) the land-use pattern was being optimized during this period, (3) in an analysis of value, built-up land can yield a return of more than 30 times that of farmland, water area, and forests lands, and (4) rapid economic development, growth in population, and the development of an infrastructure were major driving factors behind ecological land loss and the nonecological land expansion.     

核电站事故前人因可靠性分析方法

人因可靠性分析 (HRA)已成为概率安全分析 (PSA)必不可少的内容 ,事故前人因事件可靠性分析对有效预防维修、调校工作中的人因失误有着重要作用 ,是人因可靠性分析的重要组成部分 ,对PSA最终计算结果有重要影响。笔者结合核电站人因可靠性分析的实际需求 ,运用了以THERP为主的人因失误概率评价方法 ,创建了事故前人因事件分析的基本程序、方法及分析文档模式 ,表述了程序化的事故前人因事件分析模式 ,为我国核电站事故前人因可靠性分析提供了完整和有效的分析方法 ,并有效用于秦山核电站的PSA。     

核电厂人因及组织行政管理安全审查体系

定期安全审查 (PSR)是国际原子能机构 (IAEA)近年推广的一种新的核电厂安全审查方式 ,它强调系统性、全面性和关键性。人因安全因素 (HF)、组织机构和行政管理安全因素 (OA)是PSR的重要组成部分 ,也是PSR中审查难度较大的部分之一。其难点主要在于如何用有限的评审指标去刻画出最能表征人因、OA对核电厂安全运行最具影响的特征因子 ,建立起科学的、系统化的审查体系 ,且该体系还需具有较强的可操作性。基于上述认识 ,笔者建立了核电厂人因及组织行政管理安全审查体系 ,它包含安全目标与方针、人员配备与资格、组织机构与管理、配置控制、培训、职业健康、运行经验反馈、质量保证、人 -机接口、遵章守法等 10类 19个要素。同时介绍了其评审指标、审查内容、审查方法和程序等。该体系已应用于秦山核电厂。     

光催化氧化法处理甲醛废水的研究

用二氧化钛作催化剂，对较低浓度甲醛废水进行了光催化氧化处理试验。研究了催化剂用量、溶液pH、甲醛初始浓度及外加氧化剂等因素对光催化氧化的影响。试验结果表明，增加催化剂用量可以显著增加反应速度，提高降解效率；增强溶液的酸性和碱性都可以加快甲醛的降解速度，且碱性条件更加有利；在试验浓度范围内，甲醛的起始浓度对其降解反应基本没有影响；外加氧化剂双氧水可以在没有紫外光条件下，很快将甲醛氧化。     

梅子垭旅游资源评价及开发,保护规划研究

在对三梅子垭区的旅游资源现状及其结构和功能进行评价分析的基础上,认为应大力发展该地的旅游业,并建议长江三峡地区统筹安排以形成该区旅游业发展的整体优势。对于区内旅游资源的开发则应以生态旅游为主,但是必须适度,即合理的开发度和保护度相结合而且这种旅游资源的开发应该是可承受性的。这与当地整个社会－经济－自然复合生态系统的总承受能力有关。对于构成总承受能力的各种具体因素,如旅游区生态承受能力。社会心理 承     

软弱夹层地基土钉支护的安全设计计算

本文通过对某基坑失稳实例的工程计算分析，探讨在软弱夹层发育地段设计采用土钉支护时，支护体稳定性验算应注意的问题，并提出了相应的处理措施。     

重庆城市SO2污染与气象条件的关系

本文分析了重庆市城市SO_2地面浓度与风向、风速、逆温、雾以及各种地面流场型式的关系,为研究城市大气污染分布和变化规律提供了科学依据。