高硫高铁土壤全硫提取和测定方法的改进

硫酸钡分光光度比浊法是大批量测定土壤环境样品硫含量的常用方法,但影响测定结果的因素较多,如稳定剂的选择、酸度的控制、BaCl：的形态和用量等均可对测定结果产生影响。在多金属硫化物矿区,由于长期的采矿冶炼活动,造成周边土壤中硫、铁含量增加,用比浊法测定硫含量时,铁的含量也对测定结果产生显著影响。针对这些影响因素,本研究在用硝酸．高氯酸湿法对土壤进行消解后,优化了硫酸钡分光光度比浊法测定高硫高铁样品的实验条件和实验步骤,并对多金属硫化物矿区的土壤样品进行了测定,得到了较好的结果。实验证明,称取0．50g土壤样品,消解后过滤,取滤液7mL,加入1mL研（1＋2）甘油．乙醇]=6％的甘油．乙醇为稳定剂,1mL浓磷酸掩蔽Fe3＋与cl-反应所显的黄色,定容到10mL,加入w（BaCl2）=10％的氯化钡溶液10mL,电磁搅拌1min,静置20-40min,在波长440nm处,比浊法测定土壤全硫含量,相对误差〈10％,取得良好的测定结果。此方法简单、快捷、方便,适合大批量环境样品的测定。     

Antioxidant vitamin E protects embryos of Xenopus tropicalis against lambda-cyhalothrin induced embryotoxicity

Environmental Science and Pollution Research - Pesticides are capable of increasing risks to the early development of nontarget organisms through oxidative stress. The supplementation of...     

Abundance and distribution characteristics of microplastic in plateau cultivated land of Yunnan Province,China

Environmental Science and Pollution Research - Microplastic pollution in cultivated soil has received increasing attention recently. There may be more serious microplastic abundance but little...     

Release characteristics and control of hydrogen sulfide during thermal drying of municipal wastewater sludge

Journal of Material Cycles and Waste Management - Hydrogen sulfide (H2S) is the most predominant malodorous gas released during the thermal drying of municipal wastewater sludge. Experiment using a...     

苏门答腊海域海啸地震及地壳深部结构

近10年来苏门答腊俯冲带大震频发,并引发灾难性海啸,使之成为全球关注的焦点。特别是2004年和2012年的两次大震所带来的科学问题在许多方面超出现有认识。国际上对苏门答腊地区已开展了大量的地质学、地球物理学等多方面的调查研究,应用了许多新方法并取得了许多新认识。解读苏门答腊的构造背景和地质演化史对于认识俯冲型大地震的产生机理是必要的,对此类地震的发生过程和规律的研究,对于理解海啸产生的条件和防灾减灾有十分重要的现实意义。本文对苏门答腊地区的地震活动和深部构造进行了详细分析,对近年关于该地区的世界性研究成果进行了总结,梳理出若干亟待研究的科学问题,进而提出开展苏门答腊俯冲带地震3D层析成像的具体实施路线。     

自助加油站典型事故案例分析及防范措施

分析了自助加油站面临的主要安全风险,针对自助加油站的非静电类典型事故案例进行了分析和讨论。在参考和借鉴国外自助加油站相关法规的基础上,提出了一系列有针对性的防范措施。     

添加剂对碳酸钙溶解度的影响

针对石灰石-石膏湿法烟气脱硫中吸收剂石灰石利用率低、烟气参数超设计、脱硫效率低等问题,开展研究添加剂对碳酸钙溶解度的影响,结果表明:添加剂可以促进碳酸钙的溶解,不同添加剂其作用程度不同。有机添加剂的效果最显著;复合添加剂效果略差,成分间无明显的协同作用;无机添加剂效果较不理想。     

医疗废物处置工艺改进及运行效果研究

随着医疗废物产生量快速增长,造成了大气、水体、土壤的严重污染。医疗废物无害化处理成为我们当前急需解决的迫切问题。通过对垃圾处置厂医疗废物高温蒸汽处置工艺的研究,在现有工艺仅可处理感染性和损伤性废物的基础上,进行技术改进,通过增加蒸汽骤冷环节,从而增加了对病理性废物处置类别,并能确保环保及卫生达标;同时提高了灭菌率,减容率。设备改进后,可有效地处理病例性废物,有效地减少对环境的污染。     

桥头镇声环境污染控制规划及防治措施分析

摘要：城市的声环境质量在现实生活中越来越受到人们重视,因而声环境规划在整个城市的布局规划中占据着重要的地位。本文对桥头镇的环境噪声现状进行监测和分析,在各类环境噪声中以道路交通噪声污染最为严重,并提出了控制噪声污染的对策建议。     

Products of methotrexate during chlorination

Methotrexate(MTX)is a cytotoxic drug widely used in the treatment of tumors,autoimmune diseases and severe asthma. jen00883 This drug has been frequently detected in the aquatic environment with concentrations up to μg/L levels. The MTX present in environmental water might be transformed and removed during chlorination disinfection treatment. In this work,the fate of MTX during aqueous chlorination was investigated in laboratory batch experiments,and the transformation products of MTX were identified. Aqueous solutions of MTX(1 mg/L)were chlorinated by sodium hypochlorite solution at room temperature under neutral p H conditions. Chlorinated products were pre-concentrated with solid-phase extraction(SPE)cartridges and determined by liquid chromatography electrospray ionization tandem mass spectrometry(LC–ESI–MS/MS). The reaction of MTX chlorination exhibited pseudo-first-order kinetics and the half-life time of MTX degradation was calculated to be 1.65 min,when the initial chlorine concentration was 2 mg/L. Two chlorinated MTX congeners,4-amino-3-chlorinated-N10-methylpteroylglutamic(monochloro-MTX)and 4-amino-3,5-dichloro-N10-methylpteroylglutamic(dichloro-MTX)were found in the chlorinated solution. Monochloro-MTX was successfully fractionated by high performance liquid chromatography(HPLC)and its structure was further identified using ~1H nuclear magnetic resonance(NMR)analysis. The presence of the two products in real hospital wastewater was then examined and both compounds were detected. Finally,the effects of MTX and monochloro-MTX on the cell cycle progression in vitro were evaluated using zebrafish liver cell line. It was found that both compounds could inhibit the proliferation of zebrafish liver cells through S phase arrest and their effects on the cell cycle profile had no significant difference.