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741.
Xiaoxia Ou Chong Wang Fengjie Zhang Xie Quan Yan Ma He Liu 《Frontiers of Environmental Science & Engineering》2010,4(2):157-163
The photodegradation of atrazine and the photochemical formation of Fe(II) and H2O2 in aqueous solutions containing salicylic acid and Fe(III) were studied under simulated sunlight irradiation. Atrazine photolysis followed first-order reaction kinetics, and the rate constant (k) corresponding to the solution of Fe(III)-salicylic acid complex (Fe(III)-SA) was only 0.0153 h?1, roughly one eighth of the k observed in the Fe(III) alone solution (0.115 h?1). Compared with Fe(III) solution, the presence of salicylic acid significantly enhanced the formation of Fe(II) but greatly decreased H2O2 generation, and their subsequent product, hydroxyl radical (˙OH), was much less, accounting for the low rate of atrazine photodegradation in Fe(III)-SA solution. The interaction of Fe(III) with salicylic acid was analyzed using Fourier-transform infrared (FTIR) spectroscopy and UV-visible absorption, indicating that Fe(III)-salicylic acid complex could be formed by ligand exchange between the hydrogen ions in salicylic acid and Fe(III) ions. 相似文献
742.
Lu Li Bing Yuan Shi-Wei Liu Shi-Tao Yu Cong-Xia Xie Fu-Sheng Liu Li-Juan Shan 《Journal of Polymers and the Environment》2012,20(2):388-394
Chitosan oligomers because of its water solubility has some special physiological functions, such as binding lipid, affecting the mitogenic response, restraining the growth of tumors, and was widely used in cosmetics and health. H2O2/Gly (Glycine) series ionic liquids system, a new solvable-catalytic system, was an efficient clean process for preparation of chitosan oligomers. The effects of the anions of Gly series ionic liquids on the solubility and degradation for chitosan were investigated, and the results showed that [Gly]Cl aqueous solution was of good solubility and assistant degradation for chitosan. In additional, the mechanism for oxidative degradation of chitosan in ionic liquids (ILs) was studied. The effect on the property of chitosan oligomers catalyzed by H2O2, in two different kinds of solvents (HAc and [Gly]Cl) were compared. It was found that the performance of moisture absorption and retention of chitosan oligomers using ionic liquid aqueous solution as solvent was better than that using HAc aqueous solution as solvent, and even superior to that of hyaluronic acid. Furthermore, [Gly]Cl could be easily separated from the product and reused with only slight loss. It could provide an efficient and environmental friendly method for the preparation of chitosan oligomers in H2O2/ILs system. 相似文献
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以现场注水试验和实验室实验结果为依据,分析并讨论了目前研究甚少而又对注水防尘实施,特别是在软煤层综放工作面实施很重要的工艺问题,提出了适宜的钻孔、封孔、润湿效果考察方法以及表面活性剂应用中的浓度选择、种类选择和应用的必要性评价方法 相似文献
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Haiguang Zhang Lei Du Jiajian Xing Gaoliang Wei Xie Quan 《Frontiers of Environmental Science & Engineering》2023,17(5):59
748.
Mourin Jarin Zeou Dou Haiping Gao Yongsheng Chen Xing Xie 《Frontiers of Environmental Science & Engineering》2023,17(2):16
749.
Xiaoying Wang Haiguang Zhang Xu Wang Shuo Chen Hongtao Yu Xie Quan 《Frontiers of Environmental Science & Engineering》2023,17(1):1
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